Effects of Sintering Condition on the Trapped Magnetic Field Properties for MgB2 Bulks Fabricated by in-situ Capsule Method

AbstractWe have studied the trapped field properties of MgB2 bulks which were fabricated by the in-situ capsule method under various sintering temperatures of 700-900̊C for 1-24h. The trapped field, BT (T), was 1.8-1.9 T for all the bulks approximately at 16K. The BT (T) values on the bulks sintered at 900̊C for 6h and at 800̊C for 24h were slightly lower than those of other bulks because of the decrease of critical current density, Jc, which originates from both the lower connectivity, K, and the promotion of the grain growth. The high temperature and/or the long periods sintering decrease the BT (T) value. From the obtained results, the sintering at 700-800̊C for 1-6h is the optimum condition to fabricate MgB2 bulks by the capsule method

A new concept of a hybrid trapped field magnet lens

In this paper, a new concept of a hybrid trapped field magnet lens (HTFML) is proposed. The HTMFL exploits the “vortex pinning effect” of an outer superconducting bulk cylinder, which is magnetized as a trapped field magnet (TFM) using field-cooled magnetization (FCM), and the “diamagnetic shielding effect” of an inner bulk magnetic lens to generate a concentrated magnetic field higher than the trapped field from the TFM in the bore of the magnetic lens. This requires that, during the FCM process, the outer cylinder is in the normal state (T > superconducting transition temperature, Tc) and the inner lens is in the superconducting state (T < Tc) when the external magnetizing field is applied, followed by cooling to an appropriate operating temperature, then removing the external field. This is explored for two potential cases: 1) exploiting the difference in Tc of two different bulk materials (“case-1”), e.g. MgB2 (Tc = 39 K) and GdBaCuO (Tc = 92 K) or 2) using the same material for the whole HTFML, e.g., GdBaCuO, but utilizing individually-controlled cryostats, the same cryostat with different cooling loops or coolants, or heaters that keep the outer bulk cylinder at a temperature above Tc to achieve the same desired effect. The HTFML is verified using numerical simulations for “case-1” using an MgB2 cylinder and GdBaCuO lens pair and for “case-2” using a GdBaCuO cylinder and GdBaCuO lens pair. As a result, the HTFML could reliably generate a concentrated magnetic field Bc = 4.73 T with the external magnetizing field Bapp = 3 T in the “case-1, and a higher Bc = 13.49 T with higher Bapp = 10 T in the “case-2,” respectively. This could, for example, be used to enhance the magnetic field in the bore of a bulk superconducting NMR/MRI system to improve its resolution

Simulation study for magnetic levitation in pure water exploiting the ultra-high magnetic field gradient product of a hybrid trapped field magnet lens (HTFML)

A hybrid trapped field magnet lens (HTFML) is a promising device that is able to concentrate a magnetic field higher than the applied field continuously, even after removing an external field, which was conceptually proposed by the authors in 2018. In this study, we propose a new additional advantage of the HTFML, which could be applicable for magnetic levitation and separation. The HTFML device consisting of a GdBaCuO bulk cylinder and a GdBaCuO magnetic lens, after the magnetization process from an applied field, Bapp = 10 T, can generate a maximum trapped field, Bc = 11.4 T, as well as an ultra-high magnetic field gradient product, Bz⋅dBz/dz, over ±3000 T2/m at Ts = 20 K, which is higher than that of existing superconducting magnets and large-scale hybrid magnets. Through detailed numerical simulations, the HTFML device is considered for the magnetic separation of a mixture of precious metal particles (Pt, Au, Ag, and Cu) dispersed in pure water, by exploiting the magneto-Archimedes effect. The HTFML can be realized as a compact and mobile desktop-type superconducting bulk magnet system, and there are a wide range of potential industrial applications, such as in the food and medical industries.Adaptable and Seamless Technology Transfer Program through Target-driven R&D (A-STEP), Japan Science and Technology Agency (JST), Grant No. VP30218088419 JSPS KAKENHI Grant No. 19K0524

Trapped field of 1.1T without flux jumps in an MgB<inf>2</inf> bulk during pulsed field magnetization using a split coil with a soft iron yoke

MgB$_{2}$ superconducting bulks have promising potential as trapped field magnets (TFMs). We have achieved a trapped field of B$_{z}$ = 1.1 T on a high-J$_{c}$ MgB$_{2}$ bulk at 13 K without flux jumps by pulsed field magnetization (PFM) using a split-type coil with a soft iron yoke, which is a record-high trapped field by PFM for bulk MgB$_{2}$ to date. The flux jumps, which frequently took place using a solenoid-type coil during PFM, were avoided by using the split-type coil, and the B$_{z}$ value was enhanced by the insertion of soft iron yoke. The flux dynamics and heat generation/propagation were analyzed during PFM using a numerical simulation, in which the magnetic flux intruded and attenuated slowly in the bulk and tended to align along the axial direction due to the presence of soft iron yoke. The advantages of the split-type coil and the simultaneous use of a soft iron yoke are discussed.This work was supported by Open Partnership Joint Projects of Japan Society for the Promotion of Science (JSPS) Bilateral Joint Research Projects, and JSPS KAKENHI grant number 23560002 and 15K04646. Dr Mark Ainslie would like to acknowledge the support of a Royal Academy of Engineering Research Fellowship and a Royal Society International Exchanges Scheme grant, IE131084.This is the author accepted manuscript. It is currently under an indefinite embargo pending publication by the Institute of Physics

Phase transition in Pr0.5Ca0.5CoO3 and related cobaltites

We present an extensive investigation (magnetic, electric and thermal measurements and X-ray absorption spectroscopy) of the Pr0.5Ca0.5CoO3 and (Pr1-yYy)0.7Ca0.3CoO3 (y=0.0625-0.15) perovskites, in which a peculiar metal-insulator (M-I) transition, accompanied with pronounced structural and magnetic anomalies, occurs at 76 K and 40-132 K, respectively. The inspection of the M-I transition using the XANES data of Pr L3-edge and Co K-edge proofs the presence of Pr4+ ions at low temperatures and indicates simultaneously the intermediate spin to low spin crossover of Co species on lowering the temperature. The study thus definitively confirms the synchronicity of the electron transfer between Pr3+ ions and Co^(3+/4+)O3 subsystem and the transition to the low-spin, less electrically conducting phase. The large extent of the transfer is evidenced by the good quantitative agreement of the determined amount of the Pr4+ species, obtained either from the temperature dependence of the XANES spectra or via integration of the magnetic entropy change over the Pr4+ related Schottky peak in the low-temperature specific heat. These results show that the average valence of Pr3+/Pr4+ ions increases (in concomitance with the decrease of the formal Co valence) below TMI for (Pr0.925Y0.075)0.7Ca0.3CoO3 up to 3.16+ (the doping level of the CoO3 subsystem decreases from 3.30+ to 3.20+), for (Pr0.85Y0.15)0.7Ca0.3CoO3 up to 3.28+ (the decrease of doping level from 3.30+ to 3.13+) and for Pr0.5Ca0.5CoO3 up to 3.46+ (the decrease of doping level from 3.50+ to 3.27+).Comment: 19 pages, 11 figure

Physical Properties, Star Formation, and Active Galactic Nucleus Activity in Balmer Break Galaxies at 0 < z < 1

We present a spectroscopic study with the derivation of the physical properties of 37 Balmer break galaxies, which have the necessary lines to locate them in star-forming-AGN diagnostic diagrams. These galaxies span a redshift range from 0.045 to 0.93 and are somewhat less massive than similar samples of previous works. The studied sample has multiwavelength photometric data coverage from the ultraviolet to MIR Spitzer bands. We investigate the connection between star formation and AGN activity via optical, mass-excitation (MEx) and MIR diagnostic diagrams. Through optical diagrams, 31 (84%) star-forming galaxies, 2 (5%) composite galaxies and 3 (8%) AGNs were classified, whereas from the MEx diagram only one galaxy was classified as AGN. A total of 19 galaxies have photometry available in all the IRAC/Spitzer bands. Of these, 3 AGN candidates were not classified as AGN in the optical diagrams, suggesting they are dusty/obscured AGNs, or that nuclear star formation has diluted their contributions. Furthermore, the relationship between SFR surface density (\Sigma_{SFR}) and stellar mass surface density per time unit (\Sigma_{M_{\ast}/\tau}) as a function of redshift was investigated using the [OII] \lambda3727, 3729, H\alpha \lambda6563 luminosities, which revealed that both quantities are larger for higher redshift galaxies. We also studied the SFR and SSFR versus stellar mass and color relations, with the more massive galaxies having higher SFR values but lower SSFR values than less massive galaxies. These results are consistent with previous ones showing that, at a given mass, high-redshift galaxies have on average larger SFR and SSFR values than low-redshift galaxies. Finally, bluer galaxies have larger SSFR values than redder galaxies and for a given color the SSFR is larger for higher redshift galaxies.Comment: preprint version, 36 pages, 17 figures, 3 tables, accepted for publication in the Astrophysical Journa

Pulsed-Field Magnetizing Characteristics of Rectangular-Shaped Gd-Ba-Cu-O Bulk Using Split- and Solenoid-Type Coils

We have investigated the trapped-held characteristics of a rectangular-shaped Gd-Ba-Cu-O bulk (33 × 33 × 15 mm$^3$) magnetized by pulsed-field magnetization (PFM) using split- and solenoid-type coils. A soft iron yoke was set below the bulk for the solenoid coil and two yokes are inserted in the bores of the split coil. The maximum trapped held B$_{Zmax}$ at the center of the bulk surface was 1.73 T at 40 K in the case of the solenoid coil, with a distorted profile. On the other hand B$_{Zmax}$ was enhanced to 3.05 T at 40 K for the split coil with two yokes for which a symmetric trapped-held profile was observed. The behavior of the magnetic flux motion indicated two conditions for the enhancement of the trapped held: that the magnetic flux intrudes easily into the bulk even for lower applied fields and then saturates with minimal flux creep. We have also investigated the electromagnetic and thermal properties of the bulk during PFM using a numerical simulation in which the magnetic flux tended to align along the z-axis due to the presence of the soft iron yoke. The use of the split coil with two yokes is effective in enhancing the trapped held for the rectangular-shaped bulks.This work was supported by Open Partnership Joint Projects of Japan Society for the Promotion of Science (JSPS) Bilateral Joint Research Projects, and JSPS KAKENHI grant number 23560002 and 15K04646. Dr. Mark Ainslie would like to acknowledge the support of a Royal Academy of Engineering Research Fellowship

Trapped Field Enhancement of a Thin, High-Jc MgB2 Bulk without Flux Jumps using Pulsed Field Magnetization with a Split-type Coil with a Soft Iron Yoke

We have investigated the suppression of flux jumps and the enhancement of trapped field on a thin, high-J$_{c}$ MgB₂ bulk (30 mm in diameter and 7 mm in thickness) for the pulsed field magnetization (PFM) using a split-type coil with a soft iron yoke, and compared the results to those magnetized using the split-type coil without a yoke and a solenoid-type coil with a yoke. A maximum-trapped field, B$_{z}$, of 0.71 T at 14 K was achieved on the bulk surface without flux jumps by using the split coil with yoke. On the other hand, low B$_{z}$ values with flux jumps were observed for the cases using the split-type coil without a soft iron yoke, and the solenoid-type coil with a yoke. These results reproduce previous ones for a thick, high-J$_{c}$ MgB₂ bulk (22 mm in diameter and 15 mm in thickness), for which the trapped field was enhanced to a record high value of B$_{z}$=1.10 T at 13 K by PFM using the split-type coil with a yoke

Flux jumps in high-J <inf>c</inf> MgB<inf>2</inf> bulks during pulsed field magnetization

Pulsed field magnetization (PFM) of a high-J_c MgB_2 bulk disk has been investigated at 20 K, in which flux jumps frequently occur for high pulsed fields. Using a numerical simulation of the PFM procedure, we estimated the time dependence of the local magnetic field and temperature during PFM. We analyzed the electromagnetic and thermal instability of the high-J_c MgB_2 bulk to avoid flux jumps using the time dependence of the critical thickness, d_c(t), which shows the upper safety thickness to stabilize the superconductor magnetically, and the minimum propagation zone length, l_m(t), to obtain dynamical stability. The values of d_c(t) and l_m(t) change along the thermally-stabilized direction with increasing temperature below the critical temperature, T_c. However, the flux jump can be qualitatively understood by the local temperature, T(t), which exceeds T_c in the bulk. Finally, possible solutions to avoid flux jumps in high-J_c MgB_2 bulks are discussed.This work was supported by Open Partnership Joint Projects of Japan Society for the Promotion of Science (JSPS) Bilateral Joint Research Projects, and JSPS KAKENHI grant number 23560002 and 15K04646. Dr Mark Ainslie would like to acknowledge the support of a Royal Academy of Engineering Research Fellowship and a Royal Society International Exchanges Scheme grant, IE131084.This is the author accepted manuscript. The final version is available from IOP Publishing via http://dx.doi.org/10.1088/0953-2048/29/3/03400