Raman spectroscopic study of the magnesium-carbonate minerals - artinite and dypingite

Magnesium minerals are important in the understanding of the concept of geosequestration. The two hydrated hydroxy magnesium carbonate minerals artinite and dypingite have been studied by Raman spectroscopy. Intense bands are observed at 1092 cm-1 for artinite and at 1120 cm-1 for dypingite attributed CO32- ν1 symmetric stretching mode. The CO32- ν3 antisymmetric stretching vibrations are extremely weak and are observed at1412 and 1465 cm-1 for artinite and at 1366, 1447 and 1524 cm-1 for dypingite. Very weak Raman bands at 790 cm-1 for artinite and 800 cm-1 for dypingite are assigned to the CO32- ν2 out-of-plane bend. The Raman band at 700 cm-1 of artinite and at 725 and 760 cm-1 of dypingite are ascribed to CO32- ν2 in-plane bending mode. The Raman spectrum of artinite in the OH stretching region is characterised by two sets of bands: (a) an intense band at 3593 cm-1 assigned to the MgOH stretching vibrations and (b) the broad profile of overlapping bands at 3030 and 3229 cm-1 attributed to water stretching vibrations. X-ray diffraction studies show the minerals are disordered. This is reflected in the difficulty of obtaining Raman spectra of reasonable quality and explains why the Raman spectra of these minerals have not been previously or sufficiently described

Manipulating Data and Moving Forward: Transitioning to a Shared Cataloging Environment

In May of 2017, the University System of Georgia (USG) finished migrating to Alma, a single, shared catalog for all its colleges and universities. Prior to migration, all the University System’s colleges and universities maintained an Integrated Library System (ILS) from Ex Libris, Voyager, which provided a virtual catalog comprising a union catalog, while each institution managed its own database. The current migration took nearly four years from early planning stages to go live. Migrating to a cloud-based shared bibliographic environment where master bibliographic records were not “owned” by anyone was a new concept for USG libraries. Valdosta State University was involved with the migration process from the beginning. In addition, Valdosta was a key player in new collaborative initiatives for cataloging in the University System. The following case study attempts to shed light on the University’s experience migrating to a new Library Management System (LMS)

Exploring Body Comparison Tendencies: Women Are Self-Critical Whereas Men Are Self-Hopeful

Our study examined similarities and differences in women’s and men’s comparison tendencies and perfection beliefs when evaluating their face, body shape, and physical abilities, as well as how these tendencies and beliefs relate to their body esteem. College students (90 women and 88 men) completed the Body Esteem Scale (Franzoi & Shields, 1984) and answered questions concerning their social comparison and temporal comparison tendencies related to face, body shape, and physical abilities evaluations as well as personal perfection body beliefs. As predicted, women were more likely than men to compare their face and bodies to other same-sex persons whom they perceived as having either similar or better physical qualities than themselves in those body domains, with their most likely comparison tendency being upward social comparison. More men than women held body-perfection beliefs for all three body domains, and men were most likely to rely on future temporal comparison when evaluating their body shape. Comparison tendencies and perfection beliefs also were differentially related to women\u27s and men\u27s body esteem; whereas women rely on self-critical social comparison strategies associated with negative body esteem, men’s comparison strategies and perfection beliefs are more self-hopeful. Implications for practitioners treating body-image issues are discussed

Mid-infrared and near-infrared spectroscopic study of selected magnesium carbonate minerals containing ferric iron-Implications for the geosequestration of greenhouse gases

The proposal to remove greenhouse gases by pumping CO2 several kilometres below the ground implies that many carbonate containing minerals will be formed. Among these minerals brugnatellite and coalingite are probable. Two ferric ion bearing minerals brugnatellite and coalingite with a hydrotalcite -like structure have been characterised by a combination of infrared and near-infrared spectroscopy. The infrared spectra of the OH stretching region are characterised by OH and water stretching vibrations. Both the first and second fundamental overtones of these bands are observed in the NIR spectra in the 7030 to 7235 cm-1 and 10490 to 10570 cm-1. Intense (CO3)2- symmetric and antisymmetric stretching vibrations support the concept that the carbonate ion is distorted. The position of the water bending vibration indicates the water is strongly hydrogen bonded in the mineral structure. Split NIR bands at around 8675 and 11100 cm-1 indicates that some replacement of magnesium ions by ferrous ions in the mineral structure has occurred. Near-infrared spectroscopy is ideal for the assessment of the formation of carbonate minerals

Don’t Want to Get Caught? Don’t Say It: The Use of EMOJIS in Online Human Sex Trafficking Ads

Technology has dramatically changed the way criminals conduct their illicit activities. Specifically, the Internet has become a major facilitator of online human sex trafficking. Traffickers are using these technologies to market their victims which presents new challenges for efforts to combat sex trafficking. This study used knowledge management principles and natural language processing methods to develop an improved ontology of online sex trafficking ads. The language of these ads is constantly evolving; therefore, this study explored the role of a new type of indicator, emoticons, to the ontology of human trafficking indicators

Cigarette Smoking and Minority Stress Across Age Cohorts in a National Sample of Sexual Minorities:Results From the Generations Study

BACKGROUND: Sexual minority populations in the United States have persistently higher rates of cigarette use than heterosexuals, partially driven by exposure to minority stressors (e.g., discrimination and victimization). Little is known about cigarette use across cohorts of sexual minority adults who came of age in distinctly different sociopolitical environments. PURPOSE: To examine cigarette use and minority stressors across three age cohorts of U.S. sexual minority adults. METHODS: We used data from the Generations Study, a nationally representative sample (N = 1,500) of White, Black, and Latino/a sexual minority adults in three age cohorts (younger: 18–25 years; middle: 34–41 years; and older: 52–59 years). Survey data were collected from March 2016 to March 2017. We used sex-stratified logistic regression models to estimate adjusted odds ratios (aORs) and 95% confidence intervals (CIs) for associations between age cohort, minority stressors (discrimination and victimization), and two indicators of cigarette smoking (lifetime use and current use). RESULTS: Prevalence of current cigarette use in each age cohort was high (younger: 20%; middle: 33%; and older: 29%). Relative to the younger cohort, men and women in the middle- and older-age cohorts had significantly higher odds of lifetime and current smoking (e.g., men, current, aOR [95% CI]: middle = 2.47 [1.34, 4.52], older = 2.85 [1.66, 4.93]). Minority stressors were independently associated with higher odds of current smoking; when victimization was included, the magnitude of the association between age cohort and current smoking was diminished but remained significant. CONCLUSIONS: Smoking cessation interventions must consider the role of minority stress and the unique needs of sexual minority people across the life course

Waitlist-Controlled Trial of Cognitive Behavior Therapy for Hoarding Disorder

Objective: This study investigated a multicomponent cognitive behavioral treatment (CBT) for hoarding based on a model proposed by Frost and colleagues and manualized in Steketee and Frost (2007). Method: Participants with clinically significant hoarding were recruited from the community and a university-based anxiety clinic. Of the 46 patients randomly assigned to CBT or waitlist (WL), 40 completed the 12-week assessment and 36 completed 26 sessions. Treatment included education and case formulation, motivational interviewing, skills training for organizing and problem solving, direct exposure to nonacquiring and discarding, and cognitive therapy. Measures included the Saving Inventory-Revised (self-report), Hoarding Rating Scale-Interview, and measures of clinical global improvement. Between group repeated measures analyses using general linear modeling examined the effect of CBT versus WL on hoarding symptoms and moodstate after 12 weeks. Within group analyses examined pre-post effects for all CBT participants combined after 26 sessions. Results: After 12 weeks, CBT participants benefited significantly more than WL patients on hoarding severity and mood with moderate effect sizes. After 26 sessions of CBT, participants showed significant reductions in hoarding symptoms with large effect sizes for most measures. At session 26, 71% of patients were considered improved on therapist clinical global improvement ratings and 81% of patients rated themselves improved; 41% of completers were clinically significantly improved. Conclusions: Multicomponent CBT was effective in treating hoarding. However, treatment refusal and compliance remain a concern, and further research with independent assessors is needed to establish treatment benefits and durability of gains

Chitosan adhesives with sub-micron structures for photochemical tissue bonding

We describe a method for fabricating biocompatible chitosan-based adhesives with sub-micron structures to enhance tissue bonding. This procedure avoids coating and chemical modification of structures and requires a simple drop-casting step for the adhesive film formation. Chitosan thin films (27±3 μm) were fabricated with sub-micron pillars (rectangular cuboid with height ∼150 nm, square dimension ∼1 μm and pitch ∼2 μm) or holes (diameter ~500 nm or ~1 μm, depth ~100 or 400 nm, pitch of 1 or 2 μm). Polydimethylsiloxane moulds were used as negative templates for the adhesive solution that was cast and then allowed to dry to form thin films. These were applied on bisected rectangular strips of small sheep intestine and photochemically bonded by a green laser (λ= 532 nm, irradiance ∼110 J/cm2 ). The tissue repair was subsequently measured using a computer-interfaced tensiometer. The mould sub-micron structures were reproduced in the chitosan adhesive with high fidelity. The adhesive with pillars achieved the highest bonding strength (17.1±1.2 kPa) when compared to the adhesive with holes (13.0±1.3 kPa, p<0.0001, one-way ANOVA, n=15). The production of chitosan films with patterned pillars or holes in the sub-micron range was demonstrated, using a polydimethylsiloxane mould and a single drop-casting step. This technique is potentially scalable to produce adhesives of larger surface areas

A Pilot Search for Population III Supernova Candidates in the Spitzer/IRAC Dark Field

We have undertaken a systematic search for candidate supernovae from high-redshift Population III stars in a field that has been observed with repeated imaging on a cadence of 2-3 weeks over a 2.2 year baseline, the Spitzer/IRAC Dark Field. The individual epochs reach a typical 5-sigma depth of 1 uJy in IRAC Channel 1 (3.6 um). Requiring a minimum of four epochs coverage, the total effective area searched is 214 sq arcminutes. The unprecedented depth and multi-epochal nature of these data make it ideal for a first foray to detect transient objects which may be candidate luminous Pair Instability Supernovae from the primordial-metallicity first stars. The search was conducted over a broad range of timescales, allowing for different durations of the putative candidates' light curve plateau phases. All candidates were vetted by inspection of the Spitzer imaging data, as well as deep HST/ACS F814W imaging available over the full field. While many resolved-source objects were found with Spitzer variability, no transient objects could plausibly be identified as high-redshift supernovae candidates. The resulting 95% confidence level upper limit is 23/sq deg/yr, for sources with plateau timescales under 400/(1+z) days and brightnesses above ~1 uJy.Comment: ApJL, in pres