Gas Chromatography-Mass Spectrometry Study of the Essential Oils of Schinus longifolia (Lindl.) Speg., Schinus fasciculata (Griseb.) I. M. Johnst., and Schinus areira L.

The essential oil composition from the aerial parts of three Anacardiaceae growing in Bah¨ªa Blanca, Argentina was studied by gas chromatography and gas chromatography-mass spectrometry. The essential oils of S. longifolia and S. fasciculata have been studied for the first time. The major constituents were ¦Á-pinene (46.5%), ¦Â-pinene (15.1%) and ¦Á-phellandrene (10.1%) for S. longifolia and limonene (10.9%), ¦Â-phellandrene (6.16%) and ¦Á-phellandrene (5.6%) for S. fasciculata. The major components of the essential oil of S. areira were limonene (28.6%), ¦Á-phellandrene (10.1%), sabinene (9.2%) and camphene (9.2%) differing from the literature data. The essential oils from S. areira and S. longifolia exhibited a high biotoxicity in a brine shrimp assay with Artemia persimilis.Fil: Murray, Ana Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur. Departamento de Química. Instituto de Investigaciones en Química Orgánica; ArgentinaFil: Frontera, Maria Eugenia. Universidad Nacional del Sur. Departamento de Química. Instituto de Investigaciones en Química Orgánica; ArgentinaFil: Tomas, María A.. Universidad Nacional del Sur. Departamento de Química. Instituto de Investigaciones en Química Orgánica; ArgentinaFil: Mulet, María Cristina. Universidad Nacional del Sur. Departamento de Química. Instituto de Investigaciones en Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentin

A common stochastic process rules gamma-ray burst prompt emission and X-ray flares

Prompt gamma-ray and early X-ray afterglow emission in gamma-ray bursts (GRBs) are characterized by a bursty behavior and are often interspersed with long quiescent times. There is compelling evidence that X-ray flares are linked to prompt gamma-rays. However, the physical mechanism that leads to the complex temporal distribution of gamma-ray pulses and X-ray flares is not understood. Here we show that the waiting time distribution (WTD) of pulses and flares exhibits a power-law tail extending over 4 decades with index ~2 and can be the manifestation of a common time-dependent Poisson process. This result is robust and is obtained on different catalogs. Surprisingly, GRBs with many (>=8) gamma-ray pulses are very unlikely to be accompanied by X-ray flares after the end of the prompt emission (3.1 sigma Gaussian confidence). These results are consistent with a simple interpretation: an hyperaccreting disk breaks up into one or a few groups of fragments, each of which is independently accreted with the same probability per unit time. Prompt gamma-rays and late X-ray flares are nothing but different fragments being accreted at the beginning and at the end, respectively, following the very same stochastic process and likely the same mechanism.Comment: 11 pages, 7 figures, accepted by Ap

BeppoSAX observations of the X-ray binary pulsar 4U1626-67

We report on observations of the low-mass X-ray binary 4U1626-67 performed during the BeppoSAX Science Verification Phase. We present the broad-band 0.1-100 keV pulse averaged spectrum, that is well fit by a two-component function: a 0.27 +/- 0.02 keV blackbody and an absorbed power law with a photon index of 0.89 +/- 0.02. A very deep and narrow absorption feature at 38 keV, attributable to electron cyclotron resonance, is clearly visible in the broad-band spectrum. It corresponds to a neutron star magnetic field strength of 3.3 x 10^{12} G. The 4U1626-67 pulse profiles show a dramatic dependance on energy: the transition between the low energy (E<10 keV) "bi-horned" shape to the high-energy (E>10 keV) sinusoidal profile is clearly visible in our data. The modulation index shows a monotonic increase with energy.Comment: 4 pages, 2 figures. Uses espcrc2.sty (included). To appear in Proceedings of "The Active X-ray Sky: Results from BeppoSAX and Rossi-XTE

GRB 970228 Revisited: Evidence for a Supernova in the Light Curve and La te Spectral Energy Distribution of the Afterglow

At the time of its discovery, the optical and X-ray afterglow of GRB 970228 appeared to be a ringing endorsement of the previously untried relativistic fireball model of gamma-ray burst (GRB) afterglows, but now that nearly a dozen optical afterglows to GRBs have been observed, the wavering light curve and reddening spectrum of this afterglow make it perhaps the most difficult of the observed afterglows to reconcile with the fireball model. In this Letter, we argue that this afterglow's unusual temporal and spectral properties can be attributed to a supernova that overtook the light curve nearly two weeks after the GRB. This is the strongest case yet for a GRB/supernova connection. It strengthens the case that a supernova also dominated the late afterglow of GRB 980326, and the case that GRB 980425 is related to SN 1998bw.Comment: Accepted to The Astrophysical Journal (Letters), 14 pages, LaTe

A Robust Filter for the BeppoSAX Gamma Ray Burst Monitor Triggers

The BeppoSAX Gamma Ray Burst Monitor (GRBM) is triggered any time a statistically significant counting excess is simultaneously revealed by at least two of its four independent detectors. Several spurious effects, including highly ionizing particles crossing two detectors, are recorded as onboard triggers. In fact, a large number of false triggers is detected, in the order of 10/day. A software code, based on an heuristic algorithm, was written to discriminate between real and false triggers. We present the results of the analysis on an homogeneous sample of GRBM triggers, thus providing an estimate of the efficiency of the GRB detection system consisting of the GRBM and the software.Comment: Proc. 5th Huntsville GRB Symposiu

Electronic Structure of N₂P₂ Four-Membered Rings

The biradicaloid character of the ground-state structures of N2P2 rings is studied by using the high-level ab initio multiconfigurational CASPT2/CASSCF method. In order to obtain accurate descriptors, we combine two criteria: 1) singlet–triplet energy gaps and 2) relative values of the occupation numbers for bonding and antibonding orbitals associated with the radical sites. The singlet–triplet energy gaps, the occupation numbers of antibonding-like orbitals, and the weights of the main configuration state functions (CSFs) of the ground-state wavefunctions, that is, Ψ(1A1), are used to derive the biradicaloid character that ranges from 10–15 %