Rapid, Specific Determination of Iodine and Iodide by Combined Solid-Phase Extraction/Diffuse Reflectance Spectroscopy

A new, rapid methodology for trace analysis using solid-phase extraction is described. The two-step methodology is based on the concentration of an analyte onto a membrane disk and on the determination by diffuse reflectance spectroscopy of the amount of analyte extracted on the disk surface. This method, which is adaptable to a wide range of analytes, has been used for monitoring ppm levels of iodine and iodide in spacecraft water. Iodine is used as a biocide in spacecraft water. For these determinations, a water sample is passed through a membrane disk by means of a 10-mL syringe that is attached to a disk holder assembly. The disk, which is a polystyrene−divinylbenzene composite, is impregnated with poly(vinylpyrrolidone) (PVP), which exhaustively concentrates iodine as a yellow iodine−PVP complex. The amount of concentrated iodine is then determined in only 2 s by using a hand-held diffuse reflectance spectrometer by comparing the result with a calibration curve based on the Kubelka−Munk function. The same general procedure can be used to determine iodide levels after its facile and exhaustive oxidation to iodine by peroxymonosulfate (i.e., Oxone reagent). For samples containing both analytes, a two-step procedure can be used in which the iodide concentration is calculated from the difference in iodine levels before and after treatment of the sample with peroxymonosulfate. With this methodology, iodine and iodide levels in the 0.1−5.0 ppm range can be determined with a total workup time of ∼60 s with a RSD of ∼6%

Diurnal and latitude effects observed for 10 key electrons at low satellite altitudes

Observing diurnal and latitude effects for 10 keV electrons on low altitude, high latitude satellite Injun III using low energy electron detecto

On the existence of quantum representations for two dichotomic measurements

Under which conditions do outcome probabilities of measurements possess a quantum-mechanical model? This kind of problem is solved here for the case of two dichotomic von Neumann measurements which can be applied repeatedly to a quantum system with trivial dynamics. The solution uses methods from the theory of operator algebras and the theory of moment problems. The ensuing conditions reveal surprisingly simple relations between certain quantum-mechanical probabilities. It also shown that generally, none of these relations holds in general probabilistic models. This result might facilitate further experimental discrimination between quantum mechanics and other general probabilistic theories.Comment: 16+7 pages, presentation improved and minor errors correcte

Rapid, Low Level Determination of Silver(I) in Drinking Water by Colorimetric–solid-phase Extraction

A rapid, highly sensitive two-step procedure for the trace analysis of silver(I) is described. The method is based on: (1) the solid-phase extraction (SPE) of silver(I) from a water sample onto a disk impregnated with a silver-selective colorimetric reagent, and (2) the determination of the amount of complexed analyte extracted by the disk by diffuse reflectance spectroscopy (DRS). This method, called colorimetric–solid-phase extraction (C–SPE), was recently shown effective in determining low concentrations (0.1–5.0 mg/ml) of iodine and iodide in drinking water. This report extends C–SPE to the trace (∼4 μg/l) level monitoring of silver(I) which is a biocide used on the International Space Station (ISS). The determination relies on the manually driven passage of a water sample through a polystyrene–divinylbenzene disk that has been impregnated with the colorimetric reagent 5-(p-dimethylaminobenzylidene) rhodanine (DMABR) and with an additive such as a semi-volatile alcohol (1,2-decanediol) or nonionic surfactant (Brij 30). The amount of concentrated silver(I) is then determined in a few seconds by using a hand-held diffuse reflectance spectrometer, with a total sample workup and readout time of ∼60 s. Importantly, the additive induces the uptake of water by the disk, which creates a local environment conducive to silver(I) complexation at an extremely high concentration factor (∼800). There is no detectable reaction between silver(I) and impregnated DMABR in the absence of the additive. This strategy represents an intriguing new dimension for C–SPE in which additives, directly loaded in the disk material, provide a means to manipulate the reactivity of the impregnated reagent

Method of fabricating a photovoltaic module of a substantially transparent construction

A method characterized by the steps of positioning a plurality of uniformly dimensioned photovoltaic cells in registered relation with a plurality of openings formed in a planar tool is disclosed. The method allows acess to the P contact surface of each of the cells. The steps of the method are: (1) connecting the N contact surface of alternate cells to the P contact surface of the cells interposed therebetween, (2) removing therefrom residue of solder flux, (3) applying to the N contact surfaces of the cells a transparent adhesive, (4) placing a common transparent cover plate in engaged relation with the adhesive, (5) placing a film over the circular openings for hermetically sealing the openings, and (6) establishing a vacuum between the film and the cover plate

Optimization of Al/AlOx/AlAl/AlO_x/Al-Layer Systems for Josephson Junctions from a Microstructure Point of View

$Al/AlO_x/Al$-layer systems are frequently used for Josephson junction-based superconducting devices. Although much work has been devoted to the optimization of the superconducting properties of these devices, systematic studies on influence of deposition conditions combined with structural analyses on the nanoscale are rare up to now. We have focused on the optimization of the structural properties of $Al/AlO_x/Al$-layer systems deposited on Si(111) substrates with a particular focus on the thickness homogeneity of the $AlO_x$-tunnel barrier. A standard high-vacuum electron-beam deposition system was used and the effect of substrate pretreatment, different Al-deposition temperatures and Al-deposition rates was studied. Transmission electron microscopy was applied to analyze the structural properties of the $Al/AlO_x/Al$-layer systems to determine the thickness homogeneity of the $AlO_x$ layer, grain size distribution in the Al layers, Al-grain boundary types and the morphology of the $Al/AlO_x$ interface. We show that the structural properties of the lower Al layer are decisive for the structural quality of the whole $Al/AlO_x/Al$-layer system. Optimum conditions yield an epitaxial Al(111) layer on a Si(111) substrate with an Al-layer thickness variation of only 1.6 nm over more than 10 $\mu m$ and large lateral grain sizes up to 1 $\mu m$. Thickness fluctuations of the $AlO_x$-tunnel barrier are minimized on such an Al layer which is essential for the homogeneity of the tunnel current. Systematic variation of the Al-deposition rate and deposition temperature allows to develop an understanding of the growth mechanisms

NGC 4314. III. Inflowing Molecular Gas Feeding a Nuclear Ring of Star Formation

NGC 4314 is an early-type barred galaxy containing a nuclear ring of recent star formation. We present CO(1-0) interferometer data of the bar and circumnuclear region with 2.3 x 2.2 arcsec spatial resolution and 13 km/s velocity resolution acquired at the Owens Valley Radio Observatory . These data reveal a clumpy circumnuclear ring of molecular gas. We also find a peak of CO inside the ring within 2 arcsec of the optical center that is not associated with massive star formation. We construct a rotation curve from these CO kinematic data and the mass model of Combes et al. (1992). Using this rotation curve, we have identified the location of orbital resonances in the galaxy. Assuming that the bar ends at corotation, the circumnuclear ring of star formation lies between two Inner Lindblad Resonances, while the nuclear stellar bar ends near the IILR. Deviations from circular motion are detected just beyond the CO and H-alpha ring, where the dust lanes along the leading edge of the bar intersect the nuclear ring. These non-circular motions along the minor axis correspond to radially inward streaming motions at speeds of 20 - 90 km/s and clearly show inflowing gas feeding an ILR ring. There are bright HII regions near the ends of this inflow region, perhaps indicating triggering of star formation by the inflow.Comment: 25 pages, uses aasms.sty. 7 Postscript figures, 12 JPEG figures. Figures may be retrieved from ftp://clyde.as.utexas.edu/pub/N4314COfigs.tar.g

Labor Cost and Value of Citrus Operations with Alternative Technology: Enterprise DCF Approach

The prospect of immigration policy reform has renewed growers’ concerns of serious labor shortages and cost increases given that a large portion of the workforce is unauthorized for U.S. employment. This concern of labor shortages and cost increases is more serious for specialty crop agriculture which is highly labor intensive. Specialty crop growers may address the problem in various ways, but likely options include adoption of mechanical harvesting. In the current paper we study the citrus industry case and estimate the value for two operational modes (hand and mechanical harvesting) using the enterprise discounted cash flow (DCF) approach. Further we implement a simulation to forecast how the value for each operational mode would change with a change in cost scenario.Value, Enterprise DCF approach, Labor cost, Citrus operations, Mechanization, Agricultural Finance, Labor and Human Capital, Q14, J43,