Extraction of soil solution by drainage centrifugation-effects of centrifugal force and time of centrifugation on soil moisture recovery and solute concentration in soil moisture of loess subsoils.

The solute concentration in the subsoil beneath the root zone is an important parameter for leaching assessment. Drainage centrifugation is considered a simple and straightforward method of determining soil solution chemistry. Although several studies have been carried out to determine whether this method is robust, hardly any results are available for loess subsoils. To study the effect of centrifugation conditions on soil moisture recovery and solute concentration, we sampled the subsoil (1.5-3.0 m depth) at commercial farms in the loess region of the Netherlands. The effect of time (20, 35, 60, 120 and 240 min) on recovery was studied at two levels of the relative centrifugal force (733 and 6597g). The effect of force on recovery was studied by centrifugation for 35 min at 117, 264, 733, 2932, 6597 and 14,191g. All soil moisture samples were chemically analysed. This study shows that drainage centrifugation offers a robust, reproducible and standardised way for determining solute concentrations in mobile soil moisture in silt loam subsoils. The centrifugal force, rather than centrifugation time, has a major effect on recovery. The maximum recovery for silt loams at field capacity is about 40%. Concentrations of most solutes are fairly constant with an increasing recovery, as most solutes, including nitrate, did not show a change in concentration with an increasing recovery

Monitoring Nitrogen Leaching for the Evaluation of the Dutch Minerals Policy for Agriculture in Clay Regions

This paper presents the results of the Dutch monitoring program for agriculture in the clay regions for the period 1996–2000 and evaluates the monitoring strategy. A wide range of farms (25 to 85%) had a NO3–-N concentration in tile drainwater higher than the EU standard of 11.3 mg/l. The low figure is related to wet winters; the high, to dry winters. Arable farms are more prone to NO3– leaching than dairy farms. On arable farms, about 25% of the N surplus leached to groundwater and tile drainwater, on dairy farms this was about 15%. N in tile drainwater has shown to be the best indicator for monitoring the effects of farming practice changes in the clay regions. The average NO3–-N concentration in tile drainwater was 18.8 and 3.2 mg/l in borehole water on farms where both were monitored. It is known that N use has a relationship with NO3– in tile drainwater and not with NH4+ and organic N. The presented results indicate that crop rotation and precipitation strongly influence NO3– concentration in tile drainwater

Mapping nitrate leaching to upper groundwater in the sandy regions of The Netherlands, using conceptual knowledge

The European Community asks its Member States to provide a comprehensive and coherent overview of their groundwater chemical status. It is stated that simple conceptual models are necessary to allow assessments of the risks of failing to meet quality objectives. In The Netherlands two monitoring networks (one for agriculture and one for nature) are operational, providing results which can be used for an overview. Two regression models, based upon simple conceptual models, link measured nitrate concentrations to data from remote sensing images of land use, national forest inventory, national cattle inventory, fertiliser use statistics, atmospheric N deposition, soil maps and weather monitoring. The models are used to draw a nitrate leaching map and to estimate the size of the area exceeding the EU limit value in the early 1990s. The 95% confidence interval for the fraction nature and agricultural areas where the EU limit value for nitrate (50 mg/l) was exceeded amounted to 0.77–0.85 while the lower 97.5% confidence limit for the fraction agricultural area where the EU limit value was exceeded amounted to 0.94. Although the two conceptual models can be regarded as simple, the use of the models to give an overview was experienced as complex

Use of long-term monitoring data to derive a relationship between nitrogen surplus and nitrate leaching for grassland and arable land on well-drained sandy soils in the Netherlands

The decrease in nitrogen (N) use in agriculture led to improvement of upper groundwater quality in the Sand region of the Netherlands in the 1991–2009 period. However, still half of the farms exceeded the European nitrate standard for groundwater of 50 mg/l in the 2008–2011 period. To assure that farms will comply with the quality standard, an empirical model is used to derive environmentally sound N use standards for sandy soils for different crops and soil drainage conditions. Key parameters in this model are the nitrate-N leaching fractions (NLFs) for arable land and grassland on deep, well-drained sandy soils. NLFs quantify the fraction of the N surplus on the soil balance that leaches from the root zone to groundwater and this fraction represents N available for leaching and denitrification. The aim of this study was to develop a method for calculating these NLFs by using data from a random sample of commercial arable farms and dairy farms that were monitored in the 1991–2009 period. Only mean data per farm were available, which blocked a direct derivation of NLFs for unique combinations of crop type, soil type and natural soil drainage conditions. Results showed that N surplus leached almost completely from the root zone of arable land on the most vulnerable soils, that is, deep, well-drained sandy soils (95% confidence interval of NLF 0.80–0.99), while for grassland only half of the N surplus leached from the root zone of grassland (0.39–0.49). The NLF for grassland decreased with 0.015 units/year, which is postulated to be due to a decreased grazing and increased year-round housing of dairy cows. NLFs are positively correlated with precipitation surplus (0.05 units/100 mm for dairy farms and 0.10 units/100 mm for arable farms). Therefore, an increase in precipitation due to climate change may lead to an increase in leaching of nitrate