Markets, Trust, and a Culture of Responsibility: Implications for a Family-Friendly Health Care Policy.

This paper explores the way in which a family-centered community should approach markets and market interactions and the role of markets in promoting a culture of responsibility. After making a case for the compatibility of markets and families, the paper then looks at one particular family-centered community, the Amish. The Amish are a useful example not only because of their success in creating self-reliant, family-centered communities, but also because they provide a focal point for theoretical attacks on strong, independent families and communities by those proposing alternative regimes. In particular, this paper looks at the attack against the Amish in the political theory of students of John Rawls and demonstrates the incompatibility of family-centered societies and Rawlsian ideas. It then draws parallels to the thought of Habermas and the case of Germany. The paper concludes by drawing some implications for a health care policy designed to nurture a family-centered culture of responsibility.Hayek, Rawls, Amish, Markets, Trust, Responsibility

Monolayer- and crystal-type MoO3 catalysts: Their catalytic properties in relation to their surface structures

Various MoO3 catalysts have been prepared by means of adsorption of molybdenum on supports from molybdate solutions or from the gas phase. Complete monomolecular layers of Mo6+ oxide can be prepared on the carriers Al2O3, Cr2O3, TiO2, CeO2, and ZrO2, whereas on SiO2 crystallites of MoO3 are formed. Reduction experiments show that the higher valencies of Mo are stabilized in the case of a monomolecular layer. Alcohol dehydration, pentene hydrogenation, and poisoning of these reactions with pyridine reveal that MoO2 present as a monolayer is less acidic than crystalline MoO2. On the complete monolayer catalysts investigated, mostly more than 70% of the dehydration and hydrogenation activities can be correlated with sites showing a relatively high acidity which are equivalent to 10–20% of the Mo content. The CO oxidation rates on the oxidized catalysts are antiparallel to those of the reactions on the reduced ones mentioned above; relatively basic sites preferentially chemisorb CO. The conclusion is that the activity pattern of the catalysts is a function of the acidity of the supports. It is suggested that Mo5+ ions contribute to the formation of the active acid sites after reduction with hydrogen

FTIR and XPS studies on corrosion resistant SiO2 coatings as a function of the humidity during deposition

The degradation of SiO2 coatings deposited on alloys by metal organic chemical vapour deposition (MOCVD) in sulphidizing high-temperature environments is determined by delamination and crack formation. With increasing water concentration during deposition, the crack density in silica decreases and the critical thickness for delamination of SiO2 coatings increases. This improvement is supposed to be caused by compositional changes in the SiO2 coating. In this study presence of water and silanol groups as measured by Fourier transform infrared spectroscopy(FTIR) and the Si:O ratio as measured by XPS are discussed in relation to the protective properties. The FTIRmeasurements show that the coatings deposited in more humid environments contain more silanol groups and have lower stress levels. The coatings obtained under all deposition conditions consisted of stoichiometric SiO2.0 as determined by XPS. The presence of silanol groups reduces the viscosity of the coating, and stress relaxation by viscous flow becomes enhanced, thereby improving the coating performance

Protection of stainless-steels against corrosion in sulphidizing environments by Ce oxide coatings: X-ray absorption and thermogravimetric studies

In this paper a study is reported concerning ceramic coatings containing cerium oxide, prepared by the sol-gel method, used to protect Incoloy 800H against sulphidation. When the coating is sintered in air at 850°C good protection is obtained. In an X-ray absorption spectroscopic study of the coatings it was observed that the best protective coating contains all cerium as CeIV after pretreatment. After sulphidizing cerium was reduced to CeIII. Possible mechanisms to explain the protective properties are discussed

A Radiation Imaging Detector Made by Postprocessing a Standard CMOS Chip

An unpackaged microchip is used as the sensing element in a miniaturized gaseous proportional chamber. Thisletter reports on the fabrication and performance of a complete radiation imaging detector based on this principle. Our fabrication schemes are based on wafer-scale and chip-scale postprocessing.\ud Compared to hybrid-assembled gaseous detectors, our microsystem shows superior alignment precision and energy resolution, and offers the capability to unambiguously reconstruct 3-D radiation tracks on the spot.\u

The value of non-sport-specific characteristics for talent orientation in young male judo, karate and taekwondo athletes

Background & Study Aim: The present study aims to discriminate young male taekwondo, judo, and karate athletes from two age groups. It is hypothesized that a generic test battery (i.e. consisting of non-sport specific items) can allocate athletes in their respective sports. It is also expected that due to training and experience, differences between sports would be larger in the oldest age group. Material & Methods: Fifty-six highly trained taekwondo, judo, and karate athletes U13 (11.596 ± 0.578 years; n = 30) and U18 (16.097 ± 0.844 years; n = 26) completed five anthropometrical, six physical performance and three motor coordination tests. Discriminant analyses were used to investigate relevant performance measures while MANOVAs were conducted to elucidate the differences between taekwondo, judo and karate. Results: The classification results for both discriminant analyses U13 and U18 showed a perfect classification (100%) of the athletes in their respective sports. U18 showed higher multivariate differences between the three martial arts i.e. for anthropometrical measures (F2.148, P =0.044, ES =0.36), physical performance characteristics (F2.216, P =0.033, ES =0.43) and motor coordination (F6.697, P <0.001, ES =0.49) when compared to their younger counterparts. Judo athletes had the highest scores for sit and reach, handgrip, counter movement jump and balance beam. While taekwondo athletes had the highest scores for sit-ups, sprint 5m and 30m and jumping sideways. Conclusions: Generic talent characteristics allow for a successful discrimination between judo, taekwondo and karate athletes, while the differences between the martial arts profiles are more pronounced in older athletes. © Archives of Budo

An exploratory study on the effect of a four-week stroboscopic vision training program on soccer dribbling performance

BACKGROUND: Perceptual-cognitive skill is a crucial component of expert performance in sport as expert athletes rely on the integration and processing of sensory information to execute complex actions. One of the topics of interest to skill acquisition researchers is therefore how the perceptual-cognitive system can be trained, and how that affects sport skill performance. One of the methods suggested to be able to aid in the training of perceptual-cognitive skill is restricted visual feedback training.  Recently, stroboscopic vision glasses have been proposed as a tool that can restrict visual feedback during sport training and may therefore provide a useful tool for training sport-specific skills.However, despite its use in practice, evidence for the beneficial effect of stroboscopic vision on sport-specific performance across youth athletes with a range of performance levels is currently lacking. AIM: Therefore, this study aimed to investigate the effect of a four-week soccer training program with (experimental group) or without (control group) stroboscopic vision on the dribbling performance of relatively fast and slow dribblers. METHOD: To measure dribbling performance, this study used the Ugent Soccer dribbling task. RESULTS: A Repeated Measures MANOVA revealed that four weeks of stroboscopic vision training did not improve soccer dribbling skill measured through the time taken to complete the dribbling task as well as the number of touches of the ball while dribbling. CONCLUSION: While stroboscopic vision can likely lead to short term changes in perceptual-cognitive skill, it is likely not related to persistent changes in soccer dribbling performance in youth soccer players

Functional consequences of sphingomyelinase-induced changes in erythrocyte membrane structure.

Inflammation enhances the secretion of sphingomyelinases (SMases). SMases catalyze the hydrolysis of sphingomyelin into phosphocholine and ceramide. In erythrocytes, ceramide formation leads to exposure of the removal signal phosphatidylserine (PS), creating a potential link between SMase activity and anemia of inflammation. Therefore, we studied the effects of SMase on various pathophysiologically relevant parameters of erythrocyte homeostasis. Time-lapse confocal microscopy revealed a SMase-induced transition from the discoid to a spherical shape, followed by PS exposure, and finally loss of cytoplasmic content. Also, SMase treatment resulted in ceramide-associated alterations in membrane-cytoskeleton interactions and membrane organization, including microdomain formation. Furthermore, we observed increases in membrane fragility, vesiculation and invagination, and large protein clusters. These changes were associated with enhanced erythrocyte retention in a spleen-mimicking model. Erythrocyte storage under blood bank conditions and during physiological aging increased the sensitivity to SMase. A low SMase activity already induced morphological and structural changes, demonstrating the potential of SMase to disturb erythrocyte homeostasis. Our analyses provide a comprehensive picture in which ceramide-induced changes in membrane microdomain organization disrupt the membrane-cytoskeleton interaction and membrane integrity, leading to vesiculation, reduced deformability, and finally loss of erythrocyte content. Understanding these processes is highly relevant for understanding anemia during chronic inflammation, especially in critically ill patients receiving blood transfusions