Sunscreens’ uv filters risk for coastal marine environment biodiversity: A review

Considering the rapid growth of tourism in recent years and the acknowledgement that exposure to solar UV radiation may cause skin cancer, sunscreens have been widely used by beach-goers in recent decades. UV filters contained in sunscreens, however, were recently identified as emerging pollutants in coastal waters since they accumulate in the marine environment with different adverse effects. In fact, exposure to these components was proven to be toxic to most invertebrate and vertebrate marine species. Some UV filters are linked to the production of significant amounts of reactive oxygen species (ROS), such as hydrogen peroxide, and the release of inorganic micronutrients that may alter the status of coastal habitats. Bioaccumulation and biomagnification have not yet been fully addressed. This review highlights recent progress in research and provides a comprehensive overview of the toxicological and ecotoxicological effects of the most used UV filters both on the abiotic and biotic compartments in different types of coastal areas, to gain a better understanding of the impacts on coastal biodiversity

Fast Acceleration of Transrelativistic Electrons in Astrophysical Turbulence

Highly energetic, relativistic electrons are commonly present in many astrophysical systems, from solar flares to the intra-cluster medium, as indicated by observed electromagnetic radiation. However, open questions remain about the mechanisms responsible for their acceleration, and possible re-acceleration. Ubiquitous plasma turbulence is one of the possible universal mechanisms. We study the energization of transrelativistic electrons in turbulence using hybrid particle-in-cell, which provide a realistic model of Alfv\'{e}nic turbulence from MHD to sub-ion scales, and test particle simulations for electrons. We find that, depending on the electron initial energy and turbulence strength, electrons may undergo a fast and efficient phase of energization due to the magnetic curvature drift during the time they are trapped in dynamic magnetic structures. In addition, electrons are accelerated stochastically which is a slower process that yields lower maximum energies. The combined effect of these two processes determines the overall electron acceleration. With appropriate turbulence parameters, we find that superthermal electrons can be accelerated up to relativistic energies. For example, with heliospheric parameters and a relatively high turbulence level, rapid energization to MeV energies is possible.Comment: Accepted for publication in The Astrophysical Journa

Seasonal effect on the technological and chemical traits of sheep "ricotta Pistoiese" cheese

The "ricotta di pecora pistoiese" is comprised in the list of the traditional agrofood products of Tuscany and the relative PDO (Protected Designation of Origin) has be required. This research, analysing the making process, aimed to evaluate its chemical and nutritive traits as influenced by some factors, with particular attention to the season. During the four seasons of two consecutive years, the making process of ricotta cheese was monitored in four farms for a total of 32 control-days. Yields, chemical composition and fatty acid profile of fat were determined. The amount of milk added to whey influenced the fat and protein content and the yields at 0 and 24 hours. Season affected only the protein content, higher in winter and spring. Fatty acid composition was influenced strongly by the season being the ricotta cheese of summer richer of monounsaturated and polyunsaturated FA than that of autumn and winter, probably due to the feeding regimen based mainly on fresh grass

Plasma turbulence and kinetic instabilities at ion scales in the expanding solar wind

The relationship between a decaying strong turbulence and kinetic instabilities in a slowly expanding plasma is investigated using two-dimensional (2D) hybrid expanding box simulations. We impose an initial ambient magnetic field perpendicular to the simulation box, and we start with a spectrum of large-scale, linearly polarized, random-phase Alfvénic fluctuations that have energy equipartition between kinetic and magnetic fluctuations and vanishing correlation between the two fields. A turbulent cascade rapidly develops; magnetic field fluctuations exhibit a power-law spectrum at large scales and a steeper spectrum at ion scales. The turbulent cascade leads to an overall anisotropic proton heating, protons are heated in the perpendicular direction, and, initially, also in the parallel direction. The imposed expansion leads to generation of a large parallel proton temperature anisotropy which is at later stages partly reduced by turbulence. The turbulent heating is not sufficient to overcome the expansion-driven perpendicular cooling and the system eventually drives the oblique firehose instability in a form of localized nonlinear wave packets which efficiently reduce the parallel temperature anisotropy. This work demonstrates that kinetic instabilities may coexist with strong plasma turbulence even in a constrained 2D regime

A comparison of 0.375% ropivacaine psoas compartment block and 2% prilocaine spinal anaesthesia in dogs undergoing tibial plateau levelling osteotomy

BACKGROUND: In dogs undergoing routine elective orthopaedic surgeries carried out as same-day surgeries regional anaesthetic techniques (RATs) should aim to produce analgesia but minimising the postoperative motor dysfunction. Our objective was to compare the perioperative analgesic effects and the time to motor recovery between spinal anaesthesia (SA) with hyperbaric solution of prilocaine 2% (mg = 4 x [0.3 × BW (kg) + 0.05 × SCL (cm)]) and morphine (0.03 mg/kg) and combined ultrasound (US) and electro stimulator-guided psoas compartment and ischiatic nerve block (PB) with ropivacaine 0.375% (0.45 mL/kg). Dogs undergoing tibial plateau levelling osteotomy (TPLO) were randomly assigned to receive either SA or PB. Procedural failure, perioperative rescue analgesia, motor block recovery and complications were recorded. RESULTS: Procedural failure rate (PFR) was 19% (7 out of 36) for SA and 9% (3 out of 32) for PB (p = 0.31). Intraoperative rescue analgesia was administered to 6/29 (21%) SA group dogs and in 15/29 (52%) PB group dogs, respectively (p = 0.03). At 3 h after RAT, percentage of dogs with complete block recovery was 25/29 (86%) and 25/29 (86%) in group SA and PB, respectively (p = 1). Two cases of pruritus and one case of urinary retention were recorded in the SA group. Residual ischiatic nerve block was noted at 12 h after RAT in 2/15 (13%) of dogs in group PB; it completely resolved 24 h after RAT. CONCLUSIONS: SA with prilocaine 2% and PB with ropivacaine 0.37% were found suitable for dogs undergoing same-day TPLO surgery. Pruritus and urinary retention in SA and residual block in both groups might occasionally delay the time of discharge. SUPPLEMENTARY INFORMATION: The online version contains supplementary material available at 10.1186/s12917-022-03277-6