Food consumption and civil society: Mediterranean diet as a sustainable resource for the Mediterranean area

Objective: To define the Mediterranean diet model inside a Mediterranean social and cultural food framework and from the perspective of a local model of consumption. Design: Reflexion and review of literature available in relation to the Mediterranean diet, locality and proximity. Setting and subjects: Mediterranean region and its populations. Results: The Mediterranean local food system under the term Mediterranean diet encourages local production and local consumption. From this perspective, this model takes part of every local Mediterranean lifestyles and encourages sustainability. Conclusions: From a local Mediterranean point of view and as a proximity model of consumption, Mediterranean food and diet can be a sustainable resource for the Mediterranean area

Implementation of connected and autonomous vehicles in cities could have neutral effects on the total travel time costs: modeling and analysis for a circular city

Autonomous vehicles promise to revolutionize the automobile market, although their implementation could take several decades in which both types of cars will coexist on the streets. We formulate a model for a circular city based on continuous approximations, considering demand surfaces over the city. Numerical results from our model predict direct and indirect effects of connected and autonomous vehicles. Direct effects will be positive for our cities: (a) less street supply is needed to accommodate the traffic; (b) congestion levels decrease: travel costs may decrease by 30%. Some indirect effects will counterbalance these positive effects: (c) a decrease of 20% in the value of travel time can reduce the total cost by a third; (d) induced demand could be as high as 50%, bringing equivalent total costs in the future scenario; (e) the vehicle-kilometers traveled could also affect the future scenario; and (f) increases in city size and urban sprawl. As a conclusion, the implementation of autonomous vehicles could be neutral for the cities regarding travel time costs. City planning agencies still have to promote complementary modes such as active mobility (walking and bicycle), transit (public transportation), and shared mobility (shared autonomous vehicles and mobility as a service).Peer ReviewedPostprint (published version

Role of the synthesis route on the properties of hybrid LDH-graphene as basic catalysts

Layered double hydroxides (LDH or HT) or their derived mixed oxides present marked acid-base properties useful in catalysis, but they lead to agglomerate inducing a weak accessibility to the active sites. In this study we report the preparation and characterization of HT/Graphene (HT/rGO) nanocomposites as active and selective basic catalysts for the acetone condensation reaction. The graphene high specific surface area and structural compatibility with the HT allowed increasing the number and accessibility of the active sites and activity of this later. Two series of HT/rGO nanocomposites with 0.5 = HT/rGO = 10 mass ratio were prepared by: i) direct HT coprecipitation in the presence of GO; ii) self-assembly of preformed HT with GO. The prepared HT/rGO nanocomposites were dried either in air at 80 °C or freeze-dried. A series of characterizations showed the great influence of the preparation method and HT/rGO mass ratio on both the nanocomposite structure and catalytic activity. An optimum activity was observed for a HT/rGO = 10 catalyst. Particularly, the highest catalytic activity was found in those nanocomposites obtained by coprecipitation and freeze dried (3 times more active than bulk HT) which can be connected to their structure with a better accessibility to the basic sites.Postprint (author's final draft