The effect of (Ti + Al): V ratio on the structure and oxidation behaviour of TiAlN/VN nano-scale multilayer coatings

Nano-scaled multilayered TiAlN/VN coatings have been grown on stainless steel and M2 high speed steel substrates at U-B = - 85 V in an industrial, four target, Hauzer HTC 1000 coater using combined cathodic steered arc etching/unbalanced magnetron sputtering. X-ray diffraction (XRD) has been used to investigate the effects of process parameters (Target Power) on texture evolution (using texture parameter T*), development of residual stress (sin(2) psi method) and nano-scale multilayer period. The composition of the coating was determined using energy dispersive X-ray analysis. The thermal behaviour of the coatings in air was studied using thermo-gravimetric analysis, XRD and scanning electron microscopy. The bi-layer period varied between 2.8 and 3.1 nm and in all cases a {1 1 0} texture developed with a maximum value T* = 4.9. The residual stress varied between -5.2 and -7.4 GPa. The onset of rapid oxidation occurred between 628 and 645 degreesC depending on the (Ti+Al):V ratio. After oxidation in air at 550 degreesC AlVO4, TiO2 and V2O5 Phases were identified by XRD with the AlVO4, TiO2 being the major phases. The formation of AlVO4 appears to disrupt the formation of Al2O3 which imparts oxidation resistance to TiAlN based coatings. Increasing the temperature to 600 and 640 degreesC led to a dramatic increase in the formation of V2O5 which was highly oriented (0 0 1) with a plate-like morphology. At 640 degreesC there was no evidence of the coating on XRD. Increasing the temperature to 670 degreesC led to further formation of AlVO4 and a dramatic reduction in V2O5. (C) 2003 Elsevier B.V. All rights reserved

A rapid assessment of the invasive status of Eucalyptus species in two South African provinces

Gum trees, or eucalypts (Eucalyptus species), have been targeted for invasive alien plant clearing programmes in many parts of South Africa. This has caused some dissatisfaction where the species concerned also have useful characteristics, and stakeholders contend that some of these useful species are not invasive. A rapid assessment of the invasive status of Eucalyptus species at 82 sites in South Africa (54 in the Western Cape and 28 in Mpumalanga) indicated that only Red River gum (E. camaldulensis) and flooded gum (E. grandis) are clearly invasive. Surveys were not undertaken in parts of the Western Cape known to be invaded by spider gum (E. lehmannii); the invasive status of this species is well known and is not contested. Red River gum has transformed long stretches of rivers and its importance as a major weed has been underestimated in previous reviews of alien plant invasions in South Africa. Most other species were naturalized. We recommend that projects aimed at clearing eucalypts should focus on riparian areas and nature reserves (where all eucalypts have deleterious effects), but that clearing projects outside these areas should only target species known to be invasive until such time as the invasive status of the other eucalypts (notably sugar gum, E. cladocalyx, and karri, E. diversicolor) can be ascertained with a greater degree of confidence

Strange Decays of Nonstrange Baryons

The strong decays of excited nonstrange baryons into the final states Lambda K, Sigma K, and for the first time into Lambda(1405) K, Lambda(1520) K, Sigma(1385) K, Lambda K*, and Sigma K*, are examined in a relativized quark pair creation model. The wave functions and parameters of the model are fixed by previous calculations of N pi and N pi pi, etc., decays. Our results show that it should be possible to discover several new negative parity excited baryons and confirm the discovery of several others by analyzing these final states in kaon production experiments. We also establish clear predictions for the relative strengths of certain states to decay to Lambda(1405) K and Lambda(1520) K, which can be tested to determine if a three-quark model of the Lambda(1405) K is valid. Our results compare favorably with the results of partial wave analyses of the limited existing data for the Lambda K and Sigma K channels. We do not find large Sigma K decay amplitudes for a substantial group of predicted and weakly established negative-parity states, in contrast to the only previous work to consider decays of these states into the strange final states Lambda K and Sigma K.Comment: 25 pages, 8 figures, RevTe

Recent Advances in Model-Assisted Probability of Detection

The increased role played by probability of detection (POD) in structural integrity programs, combined with the significant time and cost associated with the purely empirical determination of POD, provides motivation for alternate means to estimate this important metric of NDE techniques. One approach to make the process of POD estimation more efficient is to complement limited empirical experiments with information from physics-based models of the inspection process or controlled laboratory experiments. The Model-Assisted Probability of Detection (MAPOD) Working Group was formed by the Air Force Research Laboratory, the FAA Technical Center, and NASA to explore these possibilities. Since the 2004 inception of the MAPOD Working Group, 11 meetings have been held in conjunction with major NDE conferences. This paper will review the accomplishments of this group, which includes over 90 members from around the world. Included will be a discussion of strategies developed to combine physics-based and empirical understanding, draft protocols that have been developed to guide application of the strategies, and demonstrations that have been or are being carried out in a number of countries. The talk will conclude with a discussion of future directions, which will include documentation of benefits via case studies, development of formal protocols for engineering practice, as well as a number of specific technical issues

Hierarchy of Conservation Laws of Diffusion--Convection Equations

We introduce notions of equivalence of conservation laws with respect to Lie symmetry groups for fixed systems of differential equations and with respect to equivalence groups or sets of admissible transformations for classes of such systems. We also revise the notion of linear dependence of conservation laws and define the notion of local dependence of potentials. To construct conservation laws, we develop and apply the most direct method which is effective to use in the case of two independent variables. Admitting possibility of dependence of conserved vectors on a number of potentials, we generalize the iteration procedure proposed by Bluman and Doran-Wu for finding nonlocal (potential) conservation laws. As an example, we completely classify potential conservation laws (including arbitrary order local ones) of diffusion--convection equations with respect to the equivalence group and construct an exhaustive list of locally inequivalent potential systems corresponding to these equations.Comment: 24 page

New Baryons in the Delta eta and Delta omega Channels

The decays of excited nonstrange baryons into the final states Delta eta and Delta omega are examined in a relativized quark pair creation model. The wavefunctions and parameters of the model are fixed by previous calculations of N pi and N pi pi, etc., decays through various quasi-two body channels including N eta and N omega. Our results show that the combination of thresholds just below the region of interest and the isospin selectivity of these channels should allow the discovery of several new baryons in such experiments.Comment: 10 pages, RevTe