New Integrated High-Resolution Dinoflagellate Cyst Stratigraphy and Litho- and Chemostratigraphy from the Paris and Dieppe–Hampshire Basins for the “Sparnacian”

The Paris Basin represents an historical cradle of Palaeogene stratigraphy, where during the nineteenth century the Palaeocene Series and the “Sparnacian Stage” were established. As highlighted by Aubry et al. (2005), whereas the chronostratigraphic connotation of the “Sparnacian Stage” has been controversial since its definition, modern studies of the late Palaeocene–early Eocene interval have revealed that the so-called “Sparnacian” deposits encompass a remarkable and short (~170 kyr) episode of the Cenozoic, the Palaeocene–Eocene Thermal Maximum (PETM, ~55.8–55.6 Ma). Dinoflagellate assemblages from the “Sparnacian” of the Dieppe–Hampshire and Paris basins do not contain the key species Apectodinium augustum, whereas it is present in the northern Belgian Basin Tienen Formation and is coeval there with the CIE and the Apectodinium acme interval. However, our calibration of the Apectodinium acme to the CIE in the Dieppe–Hampshire and Paris basins suggests its attribution to the A. augustum zone. The absence of species A. augustum in the Anglo–Paris Basin may be explained by its restriction to more offshore conditions

U-Th vs. AMS 14C dating of shells from the Achenheim loess (Rhine Graben)

Shells extracted from loess deposits at Achenheim (Rhine Graben) have been investigated for AMS 14C and for U-Th dating by the isochron method on single shells. The two chronometers provide results that are not in agreement: the obtained 14C date is 38 ka B.P. In contrast, U-Th results provide much older ages. The 238U/232Th - 230Th/ 232Th isochron diagram gives an age of 69 kyr, whereas a slightly younger age of 64 kyr is derived from the other, 234U/232Th - 230Th/232Th, diagram. 234U/238U ratios have not been found to vary from a shell to another: the average value is 1.199, slightly higher than radioactive equilibrium. For both isochrons, the Y-axis intercept is slightly negative, which indicates that there is no evidence for a significant detrital component. Thorium 232 that is present in the shells is probably incorporated in the material. The negative intercepts suggest that the two ages have been probably "aged" resulting from a slight mobilisation of uranium. By constraining the Y-axis intercepts at 0, ages that are in good agreement from one to another, can be calculated at 60.9 kyr and 60.4 kyr, respectively. In both cases, the statistical quality of the alignment is only slightly deteriorated. Since U-Th ages are in agreement with strat igraphic data, in contrast to the 14C date, one may believe that they date the end of early diagenesis, with uranium trapping. In contrast, the AMS 14C date is either thought to reflect analytical limitations of AMS 14C dating for such type of material, or to date a younger geologic event. In this latter case, a possible hypothesis is that this event has triggered the slight opening of the 238U - 234U system. In any case, this study demonstrates once again that surface formations often tell such complex stories that only one single dating method cannot usually be sufficient to describe precisely these histories. Instead, informations derived from different independent chronometers have to be compared

Mantle-derived helium and carbon in groundwaters and gases of Mount Etna, Italy

International audienc

Mineralogical and isotopic record of diagenesis from the Opalinus Clay formation at Benken, Switzerland: Implications for the modeling of pore-water chemistry in a clay formation

Argillaceous rocks are considered to be a suitable geological barrier for the long-term containment of wastes. Their efficiency at retarding contaminant migration is assessed using reactive-transport experiments and modeling, the latter requiring a sound understanding of pore-water chemistry. The building of a pore-water model, which is mandatory for laboratory experiments mimicking in situ conditions, requires a detailed knowledge of the rock mineralogy and of minerals at equilibrium with present-day pore waters. Using a combination of petrological, mineralogical, and isotopic studies, the present study focused on the reduced Opalinus Clay formation (Fm) of the Benken borehole (30 km north of Zurich) which is intended for nuclear-waste disposal in Switzerland. A diagenetic sequence is proposed, which serves as a basis for determining the minerals stable in the formation and their textural relationships. Early cementation of dominant calcite, rare dolomite, and pyrite formed by bacterial sulfate reduction, was followed by formation of iron-rich calcite, ankerite, siderite, glauconite, (Ba, Sr) sulfates, and traces of sphalerite and galena. The distribution and abundance of siderite depends heavily on the depositional environment (and consequently on the water column). Benken sediment deposition during Aalenian times corresponds to an offshore environment with the early formation of siderite concretions at the water/sediment interface at the fluctuating boundary between the suboxic iron reduction and the sulfate reduction zones. Diagenetic minerals (carbonates except dolomite, sulfates, silicates) remained stable from their formation to the present. Based on these mineralogical and geochemical data, the mineral assemblage previously used for the geochemical model of the pore waters at Mont Terri may be applied to Benken without significant changes. These further investigations demonstrate the need for detailed mineralogical and geochemical study to refine the model of pore-water chemistry in a clay formation

Dissolved CO2 and Alkane Gas in Clay Formations

Characterization of dissolved CO2 and alkane gas in clayrocks may help assessing the confinement properties of geological barriers considered as potential host rocks for a deep geological disposal as well as for caprocks of gas storages. A monitoring of alkanes with CO2, combined with carbon isotopes was performed on core samples coming from Underground Research Laboratories (Bure, Mont Terri, Tournemire) and the Schlattingen borehole in France and Switzerland. Composition of hydrocarbon gas and delta C-13 of methane strongly suggest a dominant thermogenic origin of methane which is mixed with a bacterial origin for the Toarcian shales, Pliensbachien and Callovian-Oxfordian clayrocks. Results also evidence the contrasted behavior of CO2, which is controlled by chemical equilibrium between pore water and carbonate mineralogy, compared to the alkanes which are present in the porosity as a stock of dissolved gases which can be depleted during degassing experiments. (C) 2015 The Authors. Published by Elsevier B.V