The Angular Resolved Photoelectron Spectroscopy of Various Polyatomic Molecular Systems

This thesis describes the study of the angular resolved photoelectron spectroscopy of a series of polyatomic molecules. The spectrometer consists of a He I radiation source, a scattering chamber, and a rotatable detection system which includes a set of electrostatic lenses, a hemispherical electrostatic kinetic energy analyzer and an electron multiplier. Angular distributions are determined from the variation in intensity as the detection system is rotated about the center of the scattering chamber. The theory of photoionization is discussed semiclassically, as the interaction of an atom or molecule treated quantum mechanically with a classical radiation field. Some recent calculations of the asymmetry parameter for valence electrons are briefly reviewed. Photoelectron angular distributions were measured for acetylene, propyne, 1-butyne, and 2-butyne. The asymmetry parameters of propyne, 1-butyne, and 2-butyne have been determined for the first time. Trends in the asymmetry parameter, ionization potentials and band shapes were studied. It was determined that the parity favoredness rules of Chang failed to account for the behavior of the asymmetry parameter of the molecule despite the symmetry of the molecule. Instead, acetylene and its alkylated analogs follow the trends in β observed in studies of the methylated ethenes. Additionally, the semi-empirical rule that the β values of π orbitals are higher than for σ orbitals was violated in this series. Acetylene and propyne possess σ orbital with β values significantly higher than the π orbitals. Two principal substituent effects were observed: 1) a systematic decrease in the first ionization potential and 2) a similar decrease in the asymmetry parameter of the X&#771; band with increasing alkylation. The photoelectron angular distributions were measured for formaldehyde, acetaldehyde, and acetone. The asymmetry parameter has been determined for the first time for acetaldehyde, and, with the exception of the first band, for acetone. This study has shown that the beta values of the X&#771; nO bands of these molecules are, within experimental error, invariant with respect to methyl substitution, results that are consistent with the nonbonding characteristics of the molecular orbitals. The A&#771; πC = O bands, however, show a strong decrease in the asymmetry parameter of approximately 0.2 per methylation in a manner similar to that observed previously in the methylated ethenes and ethynes. The expected systematic decrease in first ionization potential with substitution was also observed. Lastly, HAM/3 calculations were performed to determine the ionization potentials of some substituted carbonyls and to examine the excitation energies of ethylene and its methyl and fluoro derivatives to evaluate the method's usefulness to studies in electron impact spectroscopy. There was generally good agreement between the ionization potential calculated by this method and experimentally determined values. Agreement between the calculated values of the excitation energies and the experimental were reasonable but the method was not sensitive enough to reproduce the trends observed with increasing substitution of the chromophore.</p

Observations sur le projet final de Constitution de la République Tunisienne

Avis juridique du Conseil de l'Europe (Commission de Venise, en collaboration avec le Congrès des pouvoirs locaux et régionaux) du 17 juillet 2013 sur le projet final de la Constitution tunisienne du 1er juillet 201

Rapid onset of collectivity in the vicinity of 78Ni

gamma-rays following the B and B-n decay of the very neutron rich 84Ga produced by photo-fission of 238U have been studied at the newly built ISOL facility of IPN Orsay: ALTO. Two activities were observed and assigned to two B-decaying states: 84gGa, I = (0\^-) and 84mGa, I = (3\^-, 4\^-). Excitation energies of the 2+1 and 4+1 excited states of 84Ge were measured at E(2+1) = 624.3 keV and E(4+1) = 1670.1 keV. Comparison with HFB+GCM calculations allows to establish the collective character of this nucleus indicating a substantial N=50 core polarization. The excitation energy of the 1/2+1 state in 83Ga known to carry a large part of the neutron 3s1/2 strength was measured at 247.8keV. Altogether these data allow to confirm the new single particle state ordering which appears immediately after the double Z=28 and N=50 shell closure and to designate 78Ni as a fragile and easily polarized doubly-magic core.Comment: 4 pages, ReVTe

Localisation of massive fermions on the brane

We construct an explicit model to describe fermions confined on a four dimensional brane embedded in a five dimensional anti-de Sitter spacetime. We extend previous works to accommodate massive bound states on the brane and exhibit the transverse structure of the fermionic fields. We estimate analytically and calculate numerically the fermion mass spectrum on the brane, which we show to be discrete. The confinement life-time of the bound states is evaluated, and it is shown that existing constraints can be made compatible with the existence of massive fermions trapped on the brane for durations much longer than the age of the Universe.Comment: 20 pages, LaTeX-RevTex, 15 figures, submitted to PR

Inferring Loop Invariants using Postconditions

One of the obstacles in automatic program proving is to obtain suitable loop invariants. The invariant of a loop is a weakened form of its postcondition (the loop's goal, also known as its contract); the present work takes advantage of this observation by using the postcondition as the basis for invariant inference, using various heuristics such as "uncoupling" which prove useful in many important algorithms. Thanks to these heuristics, the technique is able to infer invariants for a large variety of loop examples. We present the theory behind the technique, its implementation (freely available for download and currently relying on Microsoft Research's Boogie tool), and the results obtained.Comment: Slightly revised versio

Estimating summary measures of health: a structured workbook approach

BACKGROUND: Summary measures of health that combine mortality and morbidity into a single indicator are being estimated in the Canadian context for approximately 200 diseases and conditions. To manage the large amount of data and calculations for this many diseases, we have developed a structured workbook system with easy to use tools. We expect this system will be attractive to researchers from other countries or regions of Canada who are interested in estimating the health-adjusted life years (HALYs) lost to premature mortality and year-equivalents lost to reduced functioning, as well as population attributable fractions (PAFs) associated with risk factors. This paper describes the workbook system using cancers as an example, and includes the entire system as a free, downloadable package. METHODS: The workbook system was developed in Excel and runs on a personal computer. It is a database system that stores data on population structure, mortality, incidence, distributions of cases entering a multitude of health states, durations of time spent in health states, preference scores that weight for severity, life table estimates of life expectancies, and risk factor prevalence and relative risks. The tools are Excel files with embedded macro programs. The main tool generates workbooks that estimate HALY, one per disease, by copying data from the database into a pre-defined template. Other tools summarize the HALY results across diseases for easy analysis. RESULTS: The downloadable zip file contains the database files initialized with Canadian data for cancers, the tools, templates and workbooks that estimate PAF and a user guide. The workbooks that estimate HALY are generated from the system at a rate of approximately one minute per disease. The resulting workbooks are self-contained and can be used directly to explore the details of a particular disease. Results can be discounted at different rates through simple parameter modification. CONCLUSION: The structured workbook approach offers researchers an efficient, easy to use, and easy to understand set of tools for estimating HALY and PAF summary measures for their country or region of interest

The central role of Wnt signaling and organoid technology in personalizing anticancer therapy

The Wnt pathway is at the heart of organoid technology, which is set to revolutionize the cancer field. We can now predetermine a patient's response to any given anticancer therapy by exposing tumor organoids established from the patient's own tumor. This cutting-edge biomedical platform translates to patients being treated with the correct drug at the correct dose from the outset, a truly personalized and precise medical approach. A high throughput drug screen on organoids also allows drugs to be tested in limitless combinations. More recently, the tumor cells that are resistant to the therapy given to a patient were selected in culture using the patient's organoids. The resistant tumor organoids were then screened empirically to identify drugs that will kill the resistant cells. This information allows diagnosis in real-time to either prevent tumor recurrence or effectively treat the recurring tumor. Furthermore, the ability to culture stem cell-derived epithelium as organoids has enabled us to begin to understand how a stem cell becomes a cancer cell or to pin-point the genetic alteration that underlies a given genetic syndrome. Here we summarize these advances and the central role of Wnt signaling, and identify the next challenges for organoid technology

X-ray polarimetry on-board HXMT

The development of micropixel gas detectors, capable to image tracks produced in a gas by photoelectrons, makes possible to perform polarimetry of X-ray celestial sources in the focus of grazing incidence X-ray telescopes. HXMT is a mission by the Chinese Space Agency aimed to survey the Hard X-ray Sky with Phoswich detectors, by exploitation of the direct demodulation technique. Since a fraction of the HXMT time will be spent on dedicated pointing of particular sources, it could host, with moderate additional resources a pair of X-ray telescopes, each with a photoelectric X-ray polarimeter (EXP2, Efficient X-ray Photoelectric Polarimeter) in the focal plane. We present the design of the telescopes and the focal plane instrumentation and discuss the performance of this instrument to detect the degree and angle of linear polarization of some representative sources. Notwithstanding the limited resources, the proposed instrument can represent a breakthrough in X-ray Polarimetry.Comment: 10 pages, 7 figure

Quasiequilibrium sequences of synchronized and irrotational binary neutron stars in general relativity. I. Method and tests

We present a numerical method to compute quasiequilibrium configurations of close binary neutron stars in the pre-coalescing stage. A hydrodynamical treatment is performed under the assumption that the flow is either rigidly rotating or irrotational. The latter state is technically more complicated to treat than the former one (synchronized binary), but is expected to represent fairly well the late evolutionary stages of a binary neutron star system. As regards the gravitational field, an approximation of general relativity is used, which amounts to solving five of the ten Einstein equations (conformally flat spatial metric). The obtained system of partial differential equations is solved by means of a multi-domain spectral method. Two spherical coordinate systems are introduced, one centered on each star; this results in a precise description of the stellar interiors. Thanks to the multi-domain approach, this high precision is extended to the strong field regions. The computational domain covers the whole space so that exact boundary conditions are set to infinity. Extensive tests of the numerical code are performed, including comparisons with recent analytical solutions. Finally a constant baryon number sequence (evolutionary sequence) is presented in details for a polytropic equation of state with gamma=2.Comment: Minor corrections, references updated, 42 pages, 25 PostScript figures, accepted for publication in Phys. Rev.