Assessment of element-specific recycling efficiency in WEEE pre-processing

Pre-processing is a crucial step to ensure the efficiency of subsequent processes and the quality of recyclates. The efficiency of pre-processing can be affected by high losses to undesignated output fractions. Standard batch tests usually provide mass balances and are a good proxy for bulk materials balances (iron/steel, aluminum, plastics). This article aims at harmonizing methodologies and recommends a strategy for further study in pre-processing on a plant scale. We have developed an “extended batch test” method, which should help to • describe the fates of materials and elements, • assess the quality of output fractions, • identify access points for critical metals and other valuable elements to enable their recovery. A methodical approach was compiled with common material flow analysis methods and an extended set of methods, which improve the reliability via the assessment of uncertainties. This applies to systematic effects and random effects. This extended batch test was performed with a 40 Mg Waste Electrical & Electronic Equipment (WEEE) batch to trace the flows of industrial base metals, precious metals and critical metals in a WEEE pre-processing plant. Results show that one-third of the input was separated and sorted manually, while the remaining material was subsequently crushed and automatically sorted. Copper and precious metals are distributed to various output fractions but are most concentrated in the sorting residues. Critical metals like cobalt and rare earth elements are mainly concentrated in the manually sorted materials but also appear in the ferrous metals scrap and the shredder light fraction

QUOVADIS Project - Organization of Validation Exercises

Waste-to-energy Solid Recovered Fuels (SRF) are prepared from non-hazardous waste. Their use is regulated under EU legislation and requires specifications for commercial or regulatory purposes. SRFs are seen as important contributors to a sustainable EU waste management. Directive 2001/77/EC includes in its scope the production of electricity from biomass, being defined as the biodegradable fraction of products, waste and residues from agriculture, forestry and related industries, as well as the biodegradable fraction of industrial and municipal waste. In this context the European Commission (EC) gave a mandate to the European Committee for Standardisation (CEN) to develop and validate Technical Specification (TS) concerning SRF for energy recovery and to transform these TS into European Standards. To meet these requests, a holistic validation programme covering quality management and the validation exercises for the pre-standards of CEN¿s Technical Committee on Solid Recovered Fuels (CEN TC 343) was designed and carried out by various members of CEN TC 343, interested Non-Governmental Organisations (NGOs) and the European Commission¿s Joint Research Centre (JRC). This report gives an overview about the validation programm called QUOVADIS (from QUality Management Organisation, VAlidation of Standards, Developments and Inquiries for Solid-Recovered Fuels). In particular the results stemming from the validation intercomparisons, which were carried out according to the requirements of the ISO Standard 5725 are shown. Upon statistical treatment the respective performance characteristics in terms of repeatability and reproducibility could be obtained.JRC.H.5-Rural, water and ecosystem resource

The ResourcePlan—An Instrument for Resource-Efficient Development of Urban Neighborhoods

In Germany, the current sectoral urban planning often leads to inefficient use of resources, partly because municipalities lack integrated planning instruments and argumentation strength toward politics, investors, or citizens. The paper develops the ResourcePlan as (i) legal and (ii) a planning instrument to support the efficient use of resources in urban neighborhoods. The integrative, multi-methodological approach addresses the use of natural resources in the building and infrastructural sectors of (i) water (storm- and wastewater) management, (ii) construction and maintenance of buildings and infrastructure, (iii) urban energy system planning, and (iv) land-use planning. First, the development as legal instrument is carried out, providing (i) premises for integrating resource protection at all legal levels and (ii) options for implementing the ResourcePlan within German municipal structures. Second, the evaluation framework for resource efficiency of the urban neighborhoods is set up for usage as a planning instrument. The framework provides a two-stage process that runs through the phases of setting up and implementing the ResourcePlan. (Eco)system services are evaluated as well as life cycle assessment and economic aspects. As a legal instrument, the ResourcePlan integrates resource protection into municipal planning and decision-making processes. The multi-methodological evaluation framework helps to assess inter-disciplinary resource efficiency, supports the spatial identification of synergies and conflicting goals, and contributes to transparent, resource-optimized planning decisions.BMBF, 033W102E, RESZ - Verbundvorhaben: R2Q - RessourcenPlan im Quartier - Teilprojekt 5: Ganzheitliche Bewertung der Ressourceneffizienz von Stadtquartiere

Deguelin Attenuates Reperfusion Injury and Improves Outcome after Orthotopic Lung Transplantation in the Rat

The main goal of adequate organ preservation is to avoid further cellular metabolism during the phase of ischemia. However, modern preservation solutions do rarely achieve this target. In donor organs hypoxia and ischemia induce a broad spectrum of pathologic molecular mechanisms favoring primary graft dysfunction (PGD) after transplantation. Increased hypoxia-induced transcriptional activity leads to increased vascular permeability which in turn is the soil of a reperfusion edema and the enhancement of a pro-inflammatory response in the graft after reperfusion. We hypothesize that inhibition of the respiration chain in mitochondria and thus inhibition of the hypoxia induced mechanisms might reduce reperfusion edema and consecutively improve survival in vivo. In this study we demonstrate that the rotenoid Deguelin reduces the expression of hypoxia induced target genes, and especially VEGF-A, dose-dependently in hypoxic human lung derived cells. Furthermore, Deguelin significantly suppresses the mRNA expression of the HIF target genes VEGF-A, the pro-inflammatory CXCR4 and ICAM-1 in ischemic lungs vs. control lungs. After lung transplantation, the VEGF-A induced reperfusion-edema is significantly lower in Deguelin-treated animals than in controls. Deguelin-treated rats exhibit a significantly increased survival-rate after transplantation. Additionally, a downregulation of the pro-inflammatory molecules ICAM-1 and CXCR4 and an increase in the recruitment of immunomodulatory monocytes (CD163+ and CD68+) to the transplanted organ involving the IL4 pathway was observed. Therefore, we conclude that ischemic periods preceding reperfusion are mainly responsible for the increased vascular permeability via upregulation of VEGF. Together with this, the resulting endothelial dysfunction also enhances inflammation and consequently lung dysfunction. Deguelin significantly decreases a VEGF-A induced reperfusion edema, induces the recruitment of immunomodulatory monocytes and thus improves organ function and survival after lung transplantation by interfering with hypoxia induced signaling

Recycling Strategies for Spent Consumer Lithium-Ion Batteries

Introduction: In the quest for sustainable energy solutions and environmental protection, the management of end-of-life (EoL) batteries has emerged as a critical issue. Batteries, especially lithium-ion batteries (LIBs), power a wide range of devices and are central to modern life. As society’s reliance on batteries grows, there is an urgent need for sustainable battery recycling methods that can efficiently recover valuable materials, minimize environmental impact, and support the circular economy. Methods: A literature review was conducted to analyze the LIB market, the estimated return volumes and state-of-the-art sorting and recycling processes. Furthermore, a manual dismantling and input analysis was done for consumer LIB. Results: The current recycling processes operate for individual cathode active material input only. However, there is no sorting process or application in place to provide pre-sorted LIBs. This is why they need to be developed. X-ray transmission, X-ray fluorescence and optical sorting in theory can be applied to differentiate LIBs by their cathode active material. To support this hypothesis, further investigations need to be performed

Status of waste-to-energy in Germany, Part I - Waste treatment facilities

This study gives a detailed overview over the German waste-to-energy sector in 2015. The aim is to quantify the available treatment capacities and the energetic potential of waste in Germany. The work is based on an extensive data collection and evaluation, both from literature sources as well as from a survey among operators of waste treatment plants. The present Part I, gives an overview of all treatment facilities in Germany that convert waste into energy. It was found that in total, almost 320 PJ of end energy are produced in German waste treatment plants: 225 PJ a−1 of heat; and 90 PJ a−1 of electricity. This is a share of about 3.7% of the German end energy consumption.publishedVersio