An evaluation of Te Rau Puawai workforce 100: Stakeholder perspectives

To evaluate the Te Rau Puawai programme, the Ministry of Health commissioned the Maori and Psychology Research Unit of the University of Waikato in July 2001. The overall aim of the evaluation was to provide the Ministry with a clearer understanding of the programme including: the perceived critical success factors, the barriers if any regarding Te Rau Puawai, the impact of the programme, the extent to which the programme may be transferable, gaps in the programme, and suggested improvements. There are a number of stakeholders who do not have a direct role in the provision of Te Rau Puawai. These people are not involved in the day to day running of Te Rau Puawai (as do, for example, the coordinator, support team or academic mentors), nevertheless they play an important role, contributing in a variety of ways to the programme

Bis(3-benzoyl-1,1-di-sec-butyl­thio­ureato-κ2 O,S)palladium(II)

The complex mol­ecule of the title complex, [Pd(C16H23N2OS)2], is completed by crystallographic twofold symmetry with the metal atom lying on the rotation axis. The PdII atom exists within a slightly distorted square-planar geometry defined by a cis-O2S2 donor set. The dihedral angle formed between the mean planes of the symmetry-related six-membered chelate rings is 12.88 (7)° and the bond lengths within the rings are indicative of significant electron delocalization. In the crystal, mol­ecules aggregate into dimers linked by four C—H⋯O inter­actions

2-(4-Chloro­phen­yl)acetic acid–2-{(E)-[(E)-2-(2-pyridyl­methyl­idene)hydrazin-1-yl­idene]meth­yl}pyridine (1/1)

In the crystal of the title 1:1 adduct, C8H7ClO2·C12H10N4, the components are linked by an O—H⋯N hydrogen bond between the carb­oxy­lic acid and one of the pyridine N atoms. In the acid, the carb­oxy­lic acid group is approximately normal to [dihedral angle = 72.9 (2)°] but twisted with respect to the plane through the benzene ring [C—C—C—O torsion angle = 25.4 (5)°]. The base is roughly planar [dihedral angle between rings = 12.66 (15)°; r.m.s. deviation of the 16 non-H atoms = 0.107 Å] and the conformations about both imine bonds are E. The dimeric aggregates are linked into a supra­molecular layer in the ab plane by C—H⋯O inter­actions

Ethyl [1-(4-bromo­phen­yl)-1-hydr­oxy-3-oxobut­yl](phen­yl)phosphinate monohydrate1

In the title hydrate, C18H20BrO4P·H2O, a staggered conformation is found when the organic mol­ecule is viewed down the central P—C bond, with the oxo and hydroxyl groups being diagonally opposite; each of the central P and C atoms has an S-configuration. The crystal structure features supra­molecular double chains along the b axis mediated by Ohydrox­yl–H⋯Ooxo, Owater–H⋯Ooxo, and Owater–H⋯Owater hydrogen bonds

Bis(propan-2-yl) [(2S,3S)-2-hydr­oxy-3-nitro­butan-2-yl]phospho­nate

In the title compound, C10H22NO6P, a staggered conformation is found when the mol­ecule is viewed down the central P—C bond, with the oxo and hydr­oxy groups gauche to each other. The crystal structure features supra­molecular chains of helical topology propagating along the b axis, mediated by O—H⋯O hydrogen bonds

2,2′-(Disulfanedi­yl)dibenzoic acid–2,9-dimethyl­phenanthroline–tetra­hydro­furan (1/2/1)

The asymmetric unit of the title co-crystal solvate, C14H10O4S2·2C14H12N2·C4H8O, comprises a 2,2′-(disulfanedi­yl)dibenzoic acid mol­ecule, two mol­ecules of 2,9-dimethyl­phenanthroline and a tetra­hydro­furan (THF) solvent mol­ecule. Each end of the twisted diacid [dihedral angle between the benzene rings = 74.33 (17)°] forms a strong O—H⋯N hydrogen bond with a 2,9-dimethyl­phenanthroline mol­ecule, forming a trimeric aggregate. The crystal structure comprises layers of acid and THF mol­ecules, and layers of 2,9-dimethyl­phenanthroline mol­ecules that alternate along the a axis, the main connections between them being of the type C—H⋯O

3-Benzoyl-1,1-dibenzyl­thio­urea

Two independent thio­urea mol­ecules comprise the asymmetric unit of the title compound, C22H20N2OS. The central N–C(=S)N(H)C(=O) atoms in each mol­ecule are virtually superimposable and each is twisted [C—N—C—S torsion angles = 121.3 (3) and −62.3 (4)°]. The mol­ecules differ only in terms of the relative orientations of the benzyl benzene rings [major difference between the C—N—C—C torsion angles of −146.6 (3) and −132.9 (3)°]. The presence of N—H⋯S hydrogen bonding leads to the formation of supra­molecular chains along the a axis. These are consolidated in the crystal packing by C—H⋯O inter­actions. The crystal was found to be a combined non-merohedral and racemic twin (twin law 00/00/001), with the fractional contribution of the minor components being approximately 9 and 28%

Aqua­(2,2′-bipyridine-κ2 N,N′)(3,5-dinitro­benzoato-κO 1)copper(II) tetra­hydro­furan monosolvate

The title complex, [Cu(C7H3N2O6)2(C10H8N2)(H2O)]·C4H8O, features a penta­coordinate CuII atom bound by two monodentate carboxyl­ate ligands, a bidentate 2,2′-bipyridine mol­ecule [dihedral angle between pyridine rings = 5.0 (2)°] and a water mol­ecule. The resulting N2O3 donor set defines a distorted square-pyramidal geometry with the coordinated water mol­ecule in the apical position. In the crystal, the presence of O—Hw⋯Oc (w = water and c = carbon­yl) hydrogen bonding leads to the formation of a supra­molecular chain propagating along the c axis, which associates into a double chain via C—H⋯ O and π–π contacts between pyridyl rings [centroid–centroid distance = 3.527 (3) Å]. The solvent mol­ecules, which are disordered over two orientations in a 0.678 (11):0.322 (11) ratio, occupy voids defined by the complex mol­ecules and are held in place via C—H⋯O inter­actions

A cocrystal of 3α-hy­droxy­tirucalla-8,24-dien-21-oic acid and 3β-fluoro­tirucalla-7,24-dien-21-oic acid (0.897:0.103)

The title compound, 0.897C30H48O3.0.103C30H47O2F is a co-crystal of two triterpenes isolated from the resin of Canarium schweinfurthiiand Engl. Both triterpenes consists of four trans-fused rings having chair/half-chair/half-chair and envelope conformations. The mol­ecular conformations are stabilized by intra­molecular C—H⋯O hydrogen bonds, forming rings of S(7) graph-set motif. In the crystal, mol­ecules are linked by inter­molecular O—H⋯O and C—H⋯O inter­actions, forming sheets parallel to (001). All atoms. excepting the axially-oriented hydroxyl group in the major component and the equatorially-oriented fluorine atom in the minor component, are overlapping