Investigation of sodium insertion in hard carbon with operando small angle neutron scattering

Sodium-ion battery technology is a promising and more sustainable alternative to its more conventional lithium-ion based counterpart. The most common anode material for these systems is a disordered form of graphite known as hard carbon. The inherent disorder in these carbons results in multiple possible pathways for sodium storage making the characterisation of sodiation mechanisms during cycling highly challenging. Here, we report an operando small angle neutron scattering (SANS) investigation of sodiation in a commercial hard carbon using a custom electrochemical cell. We demonstrate that it is possible to discern different sodiation mechanisms throughout cycling and provide supporting evidence for a three-stage model in which sodium ions are first adsorbed onto the surface of particles, then intercalated into the graphene layers, and finally inserted into the nanopores during the electrochemical stage known as the plateau region. This study showcases the unique capabilities of operando SANS for the characterisation of sodiation mechanisms of carbon-based, disordered, porous materials

Towards Jetography

As the LHC prepares to start taking data, this review is intended to provide a QCD theorist's understanding and views on jet finding at hadron colliders, including recent developments. My hope is that it will serve both as a primer for the newcomer to jets and as a quick reference for those with some experience of the subject. It is devoted to the questions of how one defines jets, how jets relate to partons, and to the emerging subject of how best to use jets at the LHC.Comment: 95 pages, 28 figures, an extended version of lectures given at the CTEQ/MCNET school, Debrecen, Hungary, August 2008; v2 includes additional discussion in several places, as well as other clarifications and additional references

An experimental test of the contributions and condition dependence of microstructure and carotenoids in yellow plumage coloration

A combination of structural and pigmentary components is responsible for many of the colour displays of animals. Despite the ubiquity of this type of coloration, neither the relative contribution of structures and pigments to variation in such colour displays nor the relative effects of extrinsic factors on the structural and pigment-based components of such colour has been determined. Understanding the sources of colour variation is important because structures and pigments may convey different information to conspecifics. In an experiment on captive American goldfinches Carduelis tristis, we manipulated two parameters, carotenoid availability and food availability, known to affect the expression of carotenoid pigments in a full-factorial design. Yellow feathers from these birds were then analysed in two ways. First, we used full-spectrum spectrometry and high-performance liquid chromatography to examine the extent to which variation in white structural colour and total carotenoid content was associated with variation in colour properties of feathers. The carotenoid content of yellow feathers predicted two colour parameters (principal component 1—representing high values of ultraviolet and yellow chroma and low values of violet–blue chroma—and hue). Two different colour parameters (violet–blue and yellow chroma) from white de-pigmented feathers, as well as carotenoid content, predicted reflectance measurements from yellow feathers. Second, we determined the relative effects of our experimental manipulations on white structural colour and yellow colour. Carotenoid availability directly affected yellow colour, while food availability affected it only in combination with carotenoid availability. None of our manipulations had significant effects on the expression of white structural colour. Our results suggest that the contribution of microstructures to variation in the expression of yellow coloration is less than the contribution of carotenoid content, and that carotenoid deposition is more dependent on extrinsic variability than is the production of white structural colour