Landau Expansion for the Kugel-Khomskii t2gt_{2g} Hamiltonian

The Kugel-Khomskii (KK) Hamiltonian for the titanates describes spin and orbital superexchange interactions between $d^1$ ions in an ideal perovskite structure in which the three $t_{2g}$ orbitals are degenerate in energy and electron hopping is constrained by cubic site symmetry. In this paper we implement a variational approach to mean-field theory in which each site, $i$, has its own $n \times n$ single-site density matrix \rhov(i), where $n$, the number of allowed single-particle states, is 6 (3 orbital times 2 spin states). The variational free energy from this 35 parameter density matrix is shown to exhibit the unusual symmetries noted previously which lead to a wavevector-dependent susceptibility for spins in $\alpha$ orbitals which is dispersionless in the $q_\alpha$-direction. Thus, for the cubic KK model itself, mean-field theory does not provide wavevector `selection', in agreement with rigorous symmetry arguments. We consider the effect of including various perturbations. When spin-orbit interactions are introduced, the susceptibility has dispersion in all directions in ${\bf q}$-space, but the resulting antiferromagnetic mean-field state is degenerate with respect to global rotation of the staggered spin, implying that the spin-wave spectrum is gapless. This possibly surprising conclusion is also consistent with rigorous symmetry arguments. When next-nearest-neighbor hopping is included, staggered moments of all orbitals appear, but the sum of these moments is zero, yielding an exotic state with long-range order without long-range spin order. The effect of a Hund's rule coupling of sufficient strength is to produce a state with orbital order.Comment: 20 pages, 5 figures, submitted to Phys. Rev. B (2003

Ensemble dependence in the Random transverse-field Ising chain

In a disordered system one can either consider a microcanonical ensemble, where there is a precise constraint on the random variables, or a canonical ensemble where the variables are chosen according to a distribution without constraints. We address the question as to whether critical exponents in these two cases can differ through a detailed study of the random transverse-field Ising chain. We find that the exponents are the same in both ensembles, though some critical amplitudes vanish in the microcanonical ensemble for correlations which span the whole system and are particularly sensitive to the constraint. This can \textit{appear} as a different exponent. We expect that this apparent dependence of exponents on ensemble is related to the integrability of the model, and would not occur in non-integrable models.Comment: 8 pages, 12 figure

Crossover and scaling in a two-dimensional field-tuned superconductor

Using an analysis similar to that of Imry and Wortis, it is shown that the apparent first order superconductor to metal transition, which has been claimed to exist at low values of the magnetic field in a two-dimensional field-tuned system at zero temperature,can be consistentlyinterpreted as a sharp crossover from a strong superconductor to an inhomogeneous state, which is a weak superconductor. The true zero-temperature superconductor to insulator transition within the inhomogenous state is conjectured to be that of randomly diluted XY model. An explaination of the observed finite temperature approximate scaling of resistivity close to the critical point is speculated within this model.Comment: 5 pages, 2 figures, corrected and modified according to referee Report

Electron transport in the dye sensitized nanocrystalline cell

Dye sensitised nanocrystalline solar cells (Gr\"{a}tzel cells) have achieved solar-to-electrical energy conversion efficiencies of 12% in diffuse daylight. The cell is based on a thin film of dye-sensitised nanocrystalline TiO$_2$ interpenetrated by a redox electrolyte. The high surface area of the TiO$_2$ and the spectral characteristics of the dye allow the device to harvest 46% of the solar energy flux. One of the puzzling features of dye-sensitised nano-crystalline solar cells is the slow electron transport in the titanium dioxide phase. The available experimental evidence as well as theoretical considerations suggest that the driving force for electron collection at the substrate contact arises primarily from the concentration gradient, ie the contribution of drift is negligible. The transport of electrons has been characterised by small amplitude pulse or intensity modulated illumination. Here, we show how the transport of electrons in the Gr\"{a}tzel cell can be described quantitatively using trap distributions obtained from a novel charge extraction method with a one-dimensional model based on solving the continuity equation for the electron density. For the first time in such a model, a back reaction with the I$_3^-$ ions in the electrolyte that is second order in the electron density has been included.Comment: 6 pages, 5 figures, invited talk at the workshop 'Nanostructures in Photovoltaics' to appear in Physica

Percolation in random environment

We consider bond percolation on the square lattice with perfectly correlated random probabilities. According to scaling considerations, mapping to a random walk problem and the results of Monte Carlo simulations the critical behavior of the system with varying degree of disorder is governed by new, random fixed points with anisotropic scaling properties. For weaker disorder both the magnetization and the anisotropy exponents are non-universal, whereas for strong enough disorder the system scales into an {\it infinite randomness fixed point} in which the critical exponents are exactly known.Comment: 8 pages, 7 figure

Two-component Bose gas in an optical lattice at single-particle filling

The Bose-Hubbard model of a two-fold degenerate Bose gas is studied in an optical lattice with one particle per site and virtual tunneling to empty and doubly-occupied sites. An effective Hamiltonian for this system is derived within a continued-fraction approach. The ground state of the effective model is studied in mean-field approximation for a modulated optical lattice. A dimerized mean-field state gives a Mott insulator whereas the lattice without modulations develops long-range correlated phase fluctuations due to a Goldstone mode. This result is discussed in comparison with the superfluid and the Mott-insulating state of a single-component hard-core Bose.Comment: 11 page

Thermal Effects in the dynamics of disordered elastic systems

Many seemingly different macroscopic systems (magnets, ferroelectrics, CDW, vortices,..) can be described as generic disordered elastic systems. Understanding their static and dynamics thus poses challenging problems both from the point of view of fundamental physics and of practical applications. Despite important progress many questions remain open. In particular the temperature has drastic effects on the way these systems respond to an external force. We address here the important question of the thermal effect close to depinning, and whether these effects can be understood in the analogy with standard critical phenomena, analogy so useful to understand the zero temperature case. We show that close to the depinning force temperature leads to a rounding of the depinning transition and compute the corresponding exponent. In addition, using a novel algorithm it is possible to study precisely the behavior close to depinning, and to show that the commonly accepted analogy of the depinning with a critical phenomenon does not fully hold, since no divergent lengthscale exists in the steady state properties of the line below the depinning threshold.Comment: Proceedings of the International Workshop on Electronic Crystals, Cargese(2008

Correlated disordered interactions on Potts models

Using a weak-disorder scheme and real-space renormalization-group techniques, we obtain analytical results for the critical behavior of various q-state Potts models with correlated disordered exchange interactions along d1 of d spatial dimensions on hierarchical (Migdal-Kadanoff) lattices. Our results indicate qualitative differences between the cases d-d1=1 (for which we find nonphysical random fixed points, suggesting the existence of nonperturbative fixed distributions) and d-d1>1 (for which we do find acceptable perturbartive random fixed points), in agreement with previous numerical calculations by Andelman and Aharony. We also rederive a criterion for relevance of correlated disorder, which generalizes the usual Harris criterion.Comment: 8 pages, 4 figures, to be published in Physical Review

Direct Mott Insulator-to-Superfluid Transition in the Presence of Disorder

We introduce a new renormalization group theory to examine the quantum phase transitions upon exiting the insulating phase of a disordered, strongly interacting boson system. For weak disorder we find a direct transition from this Mott insulator to the Superfluid phase. In d > 4 a finite region around the particle-hole symmetric point supports this direct transition, whereas for 2=< d <4 perturbative arguments suggest that the direct transition survives only precisely at commensurate filling. For strong disorder the renormalization trajectories pass next to two fixed points, describing a pair of distinct transitions; first from the Mott insulator to the Bose glass, and then from the Bose glass to the Superfluid. The latter fixed point possesses statistical particle-hole symmetry and a dynamical exponent z, equal to the dimension d.Comment: 4 pages, Latex, submitted to Physical Review Letter