Identification of Pyroxene-Akimotoite Phase Transformation in NWA 5011 L6 Chondrite: Confirmation of the Preliminary Optical Observations

第2回極域科学シンポジウム/第34回南極隕石シンポジウム 11月17日（木） 国立国語研究所 2階講

Lava - substrate interaction: Constraints on flow emplacement and basal sintering, Lebuj rhyolitic flow, Tokaj Mountains, Carpathian-Pannonian region

The surface extrusion of rhyolite lava is linked with a complex edifice morphology and texturally diverse internal structure. The rarely exposed basal flow/dome zones provide a textural record of the mechanical and thermal stress between the overlying lava and existing topography. The Lebuj flow (Tokaj Mountains, Hungary) developed in a Miocene caldera setting, where the erosion exposed its basal zone, including various textures due to the lava substrate interaction. The flow margin is contacted with underlying volcaniclastics along a steeply inclined (50-75 degrees) plane. The lithology describes a complex ductile-brittle transition in the flow and lithification process in the substrate. The relict obsidian grains (marekanite, 0.1% H2O) in the perlite (2-3% H2O) are proof of an incomplete hydration process below the glass transition temperature. The dynamic loading of the lava caused irregular fragmentation developing a brittle basal shear zone with lens-like glass deformation. The substrate has suffered syn-emplacement lithification and the primary glass structure is completely re-crystallized. FTIR and Raman measurements identified low-temperature phyllosilicate minerals and SiO2 polymorphs, which caused additional porosity loss and densification. Using cooling time-temperature-porosity information given by this reconstruction, we suggest parallel-acting processes at elevated (groundmass crystallization-devitrification) and lower temperature (hydration-secondary mineralization) range. These define a relative timescale for the textural development in the lithologically heterogeneous contact zone

Shock heterogeneity and shock history of the recently found ordinary Csátalja chondrite in Hungary

Shock impact-produced mineral alterations in two thin sections of the recently found Csátalja H4 ordinary chondrite meteorite are compared. Peak positions of Raman and infrared spectra of mineral clasts show peaks shifted in wavenumber relative to unshocked reference minerals, and both peak shifts and FWHM values seem to correlate to each other. In the less shocked thin section (Csátalja-1) a more monomineralic and homogeneous composition indicate shock pressures of <15 GPa, while the more shocked Csátalja-2 indicates shock pressure in the 15–17 GPa range. The highest identified infrared peak position shifts range between –48 and +28 cm–1 with peak broadening between 60–84 cm–1 in the case of the feldspars, which, together with sulphide globules, were produced by the shock itself. Feldspar spectra could be detected only by FTIR spectroscopy, but in most cases (above the S3 shock level) the mixed type of the pyroxene-feldspar spectra (both peaks in the same spectra) is in agreement with the shock-produced secondary feldspars. These grains are located around crystalline borders, and probably formed by selective melting, due to shock annealing. In reconstruction of the shock history, an early fragmentation by a lower shock effect and a later increased shock level-related vein and melt pocket formation occurred, with subsequent shock annealing; temporal reconstruction of the shock event is possible only in part. The joint usage of Raman and infrared spectroscopy provided useful insights into the shock-produced changes and their spatial inhomogeneity, while shocked feldspar could be better detected by infrared than by the Raman method

Shock heterogeneity and shock history of the recently found ordinary Csátalja chondrite in Hungary

Shock impact-produced mineral alterations in two thin sections of the recently found Csátalja H4 ordinary chondrite meteorite are compared. Peak positions of Raman and infrared spectra of mineral clasts show peaks shifted in wavenumber relative to unshocked reference minerals, and both peak shifts and FWHM values seem to correlate to each other. In the less shocked thin section (Csátalja-1) a more monomineralic and homogeneous composition indicate shock pressures of <15 GPa, while the more shocked Csátalja-2 indicates shock pressure in the 15–17 GPa range. The highest identified infrared peak position shifts range between –48 and +28 cm–1 with peak broadening between 60–84 cm–1 in the case of the feldspars, which, together with sulphide globules, were produced by the shock itself. Feldspar spectra could be detected only by FTIR spectroscopy, but in most cases (above the S3 shock level) the mixed type of the pyroxene-feldspar spectra (both peaks in the same spectra) is in agreement with the shock-produced secondary feldspars. These grains are located around crystalline borders, and probably formed by selective melting, due to shock annealing. In reconstruction of the shock history, an early fragmentation by a lower shock effect and a later increased shock level-related vein and melt pocket formation occurred, with subsequent shock annealing; temporal reconstruction of the shock event is possible only in part. The joint usage of Raman and infrared spectroscopy provided useful insights into the shock-produced changes and their spatial inhomogeneity, while shocked feldspar could be better detected by infrared than by the Raman method

Characterization and 10Be content of iron carbonate concretions for genetic aspects - Weathering, desert varnish or burning: Rim effects in iron carbonate concretions

The research investigated three iron carbonate (siderite) sedimentary concretions from Nagykovácsi, Úri and Délegyháza, Hungary. To identify possible source rocks and effects of the glaze-like exposed surface of the concretions, we carried on comparative petrological, mineralogical, geochemical and isotopic studies. The samples were microbially mediated siderite concretions with embedded metamorphous and igneous mineral clasts, and had specific rim belts characterized by semi-concentric outer Fe-oxide layers, fluffy pyrite-rich outer belts and siderite inner parts. We investigated the cross section of the Fe-carbonate concretions by independent methodologies in order to identify their rim effects. Their surficial oxide layers showed evidence of degassing of the exposed surface caused most probably by elevated temperatures. The inner rim pyrite belt in the concretions excluded the possibility of a prolonged wet surface environment. Microtextural and mineralogical features did not support desert varnish formation. 10Be nuclide values of the Nagykovácsi and Uri concretions were far above the level of terrestrial in-situ cosmogenic nuclides, but they were consistent with the lowest levels for meteorites. Though the data were not conclusive to confirm any kind of known origin, they are contradictary, and open possibilities for a scenario of terrestrial meteorite origin. © 2016 Elsevier Lt