Structural design for ponding of rainwater on roof structures

Ponding of rainwater is a special load case that can lead to roof collapse. In Dutch building practice the most frequently occurring damage cases are failures of flat roof structures caused by ponding of rainwater. In the Dutch code for loadings and deformations NEN6702 [1] and the Dutch guidelines for practice regarding ponding NPR 6703 [2], principles and guidelines for the determination of rainwater loads are given. The Dutch code [1] prescribes a complex iterative procedure for ponding of rainwater. Today, there are a number of computer software programs available to support the structural designer in this iteration method. However, to keep insight in the process of rainwater ponding, a simple design method for ponding of slightly sloping flat (steel) roof structures was developed. The method is described in the first part of this article. In the second part a sensitivity analysis for design and construction inaccuracies is presented. It is shown that roofs, that are seemingly stiff enough to withstand ponding, need partial safety factors substantially greater than normally used to account for construction inaccuracies. A proposal for the partial safety factor related to roof stiffness and construction inaccuracies is given

Hierarchical micro-/mesoporous zeolite microspheres prepared by colloidal assembly of zeolite nanoparticles

A novel template-free colloidal assembly method that combines colloidal zeolite (silicalite-1) suspensions in a water-in-oil emulsion with an evaporation-induced assembly process has been developed for preparing hierarchical micro-/mesoporous zeolite microspheres (MZMs). Such particles have an interconnected mesoporosity and large mesopore diameters (25-40 nm) combined with 5.5 \uc5 diameter micropores of the zeolite nanoparticles. The method developed has the advantages of employing mild synthesis conditions, a short preparation time, and not requiring the use of a mesoporogen template or post-treatment methods. The method provides a new range of micro-/mesoporous zeolites with tunable mesoporosity dictated by the size of the zeolite nanoparticles. It also offers the possibility of combining several zeolite particle sizes or optionally adding amorphous silica nanoparticles to tune the mesopore size distribution further. It should be generally applicable to other types of colloidal zeolite suspensions (e.g. ZSM-5, zeolite A, beta) and represents a new route amenable for cost-effective scale-up

Het anorganisch bromide gehalte in boerenkaas : produktieperiode januari - april 1983

Inventarisatie van het anorganisch bromidegehalte in boerenkaas naar aanleiding van soms hogere bromidegehalten gemeten in boerenmelk