Comparative study of NiTi orthodontic wires

In this study, two superelastic NiTi orthodontic wires (0.46 x 0.64 mm(2)) were analyzed. The determination of phase transformation temperatures along with the identification of the predominant phase at room and intraoral temperatures were accomplished by DSC analysis. Superelastic behavior was analyzed through tensile tests. 3-point bending tests were performed on a model design which included brackets to compare wires' behavior: lower forces corresponding to Ormco wires' reverse phase transformation plateau when compared to Dentaurum were exhibited. Wire slippage inside the brackets and friction caused by wire-bracket-ligature combinations on bending and pulling tests, respectively, are also discussed. (C) 2014 The Authors. Published by Elsevier Ltd.publishersversionpublishe

Microstructure characterization of aluminium syntactic functionally graded composites containing hollow ceramic microspheres manufactured by radial centrifugal casting

Syntactic functionally graded metal matrix composites (SFGMMC) are a class of metallic foams in which closed porosity results from the presence of hollow ceramic microspheres (microballoons), whose spatial distribution varies continuously between the inner and the outer section of the part, thus resulting in a continuous variation in properties. In this work, aluminium-based SFGMMC rings were fabricated by radial centrifugal casting. The graded composition along the radial direction is controlled mainly by the difference in the centrifugal forces which act on the molten metal matrix and the ceramic particles, due to their dissimilar densities. In this case where the density of the SiO2/Al2O3 microballoons is lower than that of molten aluminium, the particles show a tendency to remain closer to the inner periphery of the ring. Thus the microballoon volume fraction increases along the radial direction of the ring from the outer to the inner periphery; in other words, the particle-rich zone is limited to an inner layer of the ring. Precursor conventional MMCs were prepared by stir-casting from the constituent materials, by homogeneously dispersing commercial SiO2/Al2O3 microballoons (particle size: 50 m; particle volume fraction: 5 and 10%) within a molten commercial Al-7Si-0.3Mg (A356) alloy. The resulting MMCs were then re-melt and centrifugally cast in order to produce the functionally graded composites. Particle gradients in the centrifugally cast composites were investigated by quantitative image analysis of optical micrographs (for the estimation of the particle volume fraction, mean particle diameter and porosity volume fraction)Fundação para a Ciência e a Tecnologia (FCT

X-Ray Diffraction Study of the Reverse Martensitic Transformation In Cu-Al-Ni Shape Memory Alloy

The paper presents an X ray diffraction study for a cooper based shape memory alloy. The behavior of CuAl13Ni4 alloy, which exhibits a peculiar property, is evaluated by structural changes. On cooling, the martensitic transformation takes place from the ordered structures to the long period two layered structure. The crystalline phase transformations of those alloys are very sensitive to the heat treatments, deformation degrees and also to the undesired aging effects. In particular, the study has been made on the CuAl13Ni4 shape memory alloy samples after being hot extruded, quenched and aged in martensitic state

In situ experiments with synchrotron high-energy x-rays of Ni-Ti alloys produced by powder metallurgy

The structural evolution that takes place during the homogenization heat treatments of powder metallurgical Ni-Ti- alloys was studied by in situ synchrotron diffraction. It is proposed to get a deeper understanding of this phenomenon by using different types of thermal/mechanical cycles

Characterization of smart MARFOS NiTi shape memory alloys

In the present study, structural characterization of NiTi smart shape memory al-loys (SMAs), produced by an alternative powder metallurgy approach named mechanically ac-tivated reactive forging (MARFOS), was carried out by means of transmission electron micros-copy (TEM), scanning electron microscopy (SEM) and X-ray diffraction (XRD). It was observed that MARFOS materials had a multiphase nanocrystalline structure. In addition, the transformation behaviour associated with the shape memory effect of the MARFOS aged mate-rials was studied with differential scanning calorimetry (DSC). Multiple-step martensitic trans-formations could be observed in aged materials

Nonconventional production technologies for NiTi shape memory alloys

The development of new production technologies for NiTi Shape Memory Alloys (SMAs) is always challenging. Recently, we introduced two powder metallurgical (PM) processing routes involving mechanical activation of elemental powder mixtures and densification through extrusion or forging. Those processes were named Mechanically Activated Reactive Extrusion Synthesis (MARES) and Mechanically Activated Reactive FOrging Synthesis (MARFOS). Heat treatments were performed in order to adjust the B2-NiTi matrix composition, yielding a microstructure consisting of a homogeneous dispersion of Ni4Ti3 precipitates embedded in nanocrystalline B2-NiTi matrix. In the present study, we demonstrate the viability of those PM processes for producing NiTi SMAs. With insitu X-ray diffraction and differential scanning calorimetry it is shown that B2-NiTi matrix undergo a B2« R«B19 two-step phase transformatio

Evaluation of SiC-particle connectivity in functionally graded Al/SiCp composites by synchrotron radiation holographic microtomography

Reliability of functionally graded metal matrix composites (FGMMCs) for automotive components is still dependent on the detailed knowledge of the mechanisms of the microstructural build-up, for instance on the mechanisms leading to the distribution and relative positions of the reinforcing particles. In order to assess the influence of the SiC particle size on the 3-D inter-particle connectivity in functionally graded Al/SiCp composites produced by centrifugal casting, X-ray microtomography experiments were performed at the ID19 beamline in ESRF (European Synchrotron Radiation Facility). The FGMMCs consisted of an Al-10Si-2Mg alloy matrix, reinforced by an average SiC particle volume fraction of 0.10; two different average sizes were used: 37 μm and 12 μm. The holographic modification of the X-ray CMT (Computer Micro- Tomography) method allowed to obtain neatly contrasted images, as opposed to classical CMT.Good agreement was found between the particle size evaluated by CMT and by laser interferometry. Particle clustering has been evaluated in number and volume, showing that a lower mean particle size is related to more clustering. Such an adverse effect relies on the importance of particle/liquid alloy surface tension. Also, the mean particle size has been evaluated as a function of particle number within a cluster: as expected, the larger a cluster, the larger the particles inside it.(undefined

Mechanical activation of pre-alloyed NiTi2 and elemental Ni for the synthesis of NiTi alloys

ABSTRACT: This work reports on an efficient powder metallurgy method for the synthesis of NiTi alloys, involving mechanical activation of pre-alloyed NiTi2 and elemental Ni powders (NiTi2-Ni) followed by a press-and-sinter step. The idea is to take advantage of the brittle nature of NiTi2 to promote a better efficiency of the mechanical activation process. The conventional mechanical activation route using elemental Ti and Ni powders (Ti-Ni) was also used for comparative purposes. Starting with (NiTi2-Ni) powder mixtures resulted in the formation of a predominant amorphous structure after mechanical activation at 300 rpm for 2 h. A sintered specimen consisting mainly of NiTi phase was obtained after vacuum sintering at 1050 degrees C for 0.5 h. The produced NiTi phase exhibited the martensitic transformation behavior. Using elemental Ti powders instead of pre-alloyed NiTi2 powders, the structural homogenization of the synthesized NiTi alloys was delayed. Performing the mechanical activation at 300 rpm for the (Ti-Ni) powder mixtures gave rise to the formation of composite particles consisting in dense areas of alternate fine layers of Ni and Ti. However, no significant structural modification was observed even after 16 h of mechanical activation. Only after vacuum sintering at 1050 degrees C for 6 h, the NiTi phase was observed to be the predominant phase. The higher reactivity of the mechanically activated (NiTi2-Ni) powder particles can explain the different sintering behavior of those powders compared with the mechanically activated (Ti-Ni) powders. It is demonstrated that this innovative approach allows an effective time reduction in the mechanical activation and of the vacuum sintering step.info:eu-repo/semantics/publishedVersio

The Temperature Effect on Severely Deformed Aluminium by High Pressure Torsion

The process of deforming materials started to attract the interest of the researchers after the development of the severe plastic deformation techniques. A number of aluminium samples were severe deformed by HPT method with different deformation degree. The researches follow to determine SPD effect on this material and temperature influence on fine aluminium structure. The paper present XRD and DSC results

Gas tungsten arc welding of as-rolled CrMnFeCoNi high entropy alloy

Fundacao para a Ciencia e Tecnologia (FCT)- project UID/EMS/00667/2019 (UNIDEMI). FMBF acknowledges funding of CENIMAT by FEDER through the program COMPETE 2020 and National Funds through FCT-Portuguese Foundation for Science and Technology, under the project UID/CTM/50025/2019 and FCT/MCTES. This work was supported by the Future Material Discovery Project of the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT of Korea (NRF-2016M3D1A1023383). NFFA-Europe Transnational Access Activity (project reference Nf-20010136 EC and ID-806).High entropy alloys have emerged as novel engineering alloys with remarkable mechanical properties in a wide range of temperatures. Among the several high entropy alloys that were already described, the equiatomic CrMnFeCoNi alloy is the most studied one. In this work, gas tungsten arc welding of as-rolled CrMnFeCoNi high entropy alloy sheets was performed. The microstructural characterization encompassed the use of electron microscopy, including electron backscattered diffraction, synchrotron X-ray diffraction analysis, microhardness testing and mechanical evaluation. A comprehensive description of the microstructural evolution, including texture and microstrain determination, of the joint is presented and discussed. Upon mechanical testing, the joints systematically failed in the fusion zone due. The large grain size and low hardness of this region justifies the failure location. The joints' mechanical behaviour is correlated with the material microstructure.publishersversionpublishe