Metal hydrides for hydrogen storage at low charging pressures

LaNi5 alloys are been extensively study as hydrogen storage material due their easy activation and good kinetics. LaNi5 alloys, containing substitutional elements such as Al or Ce, allow adjustments of the equilibrium pressure and absorption kinetics of the metallic hydrides making them storage candidate materials susceptible to be used in fuel cells systems. In this work, the thermodynamic properties of LaNi5-yAly and LaNi5, La1-xCexNi5 alloys were evaluated using a purpose built Sievert-type apparatus

Resolving the kinematics of the discs around Galactic B[e] supergiants

B[e] supergiants are luminous evolved massive stars. The mass-loss during this phase creates a complex circumstellar environment with atomic, molecular, and dusty regions usually found in rings or disc-like structures. For a better comprehension of the mechanisms behind the formation of these rings, detailed knowledge about their structure and dynamics is essential. To address that, we obtained high-resolution optical and near-infrared (near-IR) spectra for eight selected Galactic B[e] supergiants, for which CO emission has been detected. Assuming Keplerian rotation for the disc, we combine the kinematics obtained from the CO bands in the near-IR with those obtained by fitting the forbidden emission [OI] λ5577, [O I] λλ6300,6363, and [Ca II] λλ7291,7323 lines in the optical to probe the disc structure. We find that the emission originates from multiple ring structures around all B[e] supergiants, with each one of them displaying a unique combination of rings regardless of whether the object is part of a binary system. The confirmed binaries display spectroscopic variations of their line intensities and profiles as well as photometric variability, whereas the ring structures around the single stars are stable.Fil: Maravelias, G.. Universidad de Valparaíso; Chile. Academia de la República de Checa; República ChecaFil: Kraus, Michaela. Academia de la República de Checa; República Checa. Universidad de Tartu; EstoniaFil: Cidale, Lydia Sonia. Universidad de Valparaíso; Chile. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Astrofísica La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Astronómicas y Geofísicas. Instituto de Astrofísica La Plata; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Astronómicas y Geofísicas; ArgentinaFil: Borges Fernades, M.. Ministério de Ciencia, Tecnologia e Innovacao. Observatorio Nacional; BrasilFil: Arias, María Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Astrofísica La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Astronómicas y Geofísicas. Instituto de Astrofísica La Plata; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Astronómicas y Geofísicas; ArgentinaFil: Curé, Michel. Universidad de Valparaíso; ChileFil: Vasilopoulos, G.. Max-planck-institut Extraterrestrische Physik; Alemani

SEMICONDUCTOR DEVICE FOR DETECTION OF FRET SIGNALS

The transducer consists on a semiconductor device based on two stacked-i-n  heterostructures, that were designed to detect the emissions of the fluorescence resonance energy transfer between fluorophores in the cyan (470 nm) and yellow (588 nm) range of the spectrum. This research represents a preliminary study on the use of such wavelength sensitive devices as photodetectors for this kind of application. The device was characterized through optoelectronic measurements concerning spectral response measurements under different electrical and optical biasing conditions. To simulate the FRET pairs a chromatic time dependent combination of cyan and yellow wavelengths was applied to the device. The generated photocurrent was measured under reverse and forward bias to readout the output photocurrent signal. Different wavelength biasing light was also superimposed. Results show that under reverse bias the photocurrent signal presents four separate levels each one assigned to the different wavelength combinations of the FRET pairs. If a blue background is superimposed the yellow channel is enhanced and the cyan suppressed while under red irradiation the opposite behavior occurs. So under suitable biasing light the transducer is able to detect separately the cyan and yellow fluorescence pairs. An electrical model, supported by a numerical simulation supports the transduction mechanism of the device

Atividade da reductase do nitrato em milho (Zea mays L.) var. Piranão em níveis crescentes de nitrogênio.

O objetivo deste trabalho foi estudar a atividade da reductase do nitrato em milho (Zea mays L. var. "Piranao") cultivado em solucao nutritiva e sob doses crescentes de nitrogenio, na forma de NO3. A atividade da enzima foi analisada aos 56 dias de idade, em rodelas de folhas do terco medio da folha +4, seguindo-se a metodologia proposta por MULDER et alii (15), adaptada por MALAVOLTA (13). Os resultados permitiram concluir que o aumento do teor de NO3 no meio favoreceu a atividade da reductase do nitrato ate o nivel maximo de 40,51 ug de N-NO-2/g de materia verde, correspondente a um nivel de 296,19 mg de N/litro de solucao nutritiva. Os resultados obtidos nas condicoes experimentais em que foi realizado o trabalho correspondem, provavelmente, ao maximo da capacidade genetica da variedade estudada. Os teores de N encontrados nas folhas inferiores foram mais baixos do que os das folhas superiores, em funcao da alta mobilizacao do elemento para as partes mais novas da planta. Houve tambem correlacao positiva entre a atividade da reductase do nitrato, o teor de N total da folha e a producao de materia seca

Resolving the kinematics of the discs around Galactic B[e] supergiants

B[e] supergiants are luminous evolved massive stars. The mass-loss during this phase creates a complex circumstellar environment with atomic, molecular, and dusty regions usually found in rings or disc-like structures. For a better comprehension of the mechanisms behind the formation of these rings, detailed knowledge about their structure and dynamics is essential. To address that, we obtained high-resolution optical and near-infrared (near-IR) spectra for eight selected Galactic B[e] supergiants, for which CO emission has been detected. Assuming Keplerian rotation for the disc, we combine the kinematics obtained from the CO bands in the near-IR with those obtained by fitting the forbidden emission [OI] λ5577, [O I] λλ6300,6363, and [Ca II] λλ7291,7323 lines in the optical to probe the disc structure. We find that the emission originates from multiple ring structures around all B[e] supergiants, with each one of them displaying a unique combination of rings regardless of whether the object is part of a binary system. The confirmed binaries display spectroscopic variations of their line intensities and profiles as well as photometric variability, whereas the ring structures around the single stars are stable.Instituto de Astrofísica de La PlataFacultad de Ciencias Astronómicas y Geofísica

Resolving the kinematics of the discs around Galactic B[e] supergiants

B[e] supergiants are luminous evolved massive stars. The mass-loss during this phase creates a complex circumstellar environment with atomic, molecular, and dusty regions usually found in rings or disc-like structures. For a better comprehension of the mechanisms behind the formation of these rings, detailed knowledge about their structure and dynamics is essential. To address that, we obtained high-resolution optical and near-infrared (near-IR) spectra for eight selected Galactic B[e] supergiants, for which CO emission has been detected. Assuming Keplerian rotation for the disc, we combine the kinematics obtained from the CO bands in the near-IR with those obtained by fitting the forbidden emission [OI] λ5577, [O I] λλ6300,6363, and [Ca II] λλ7291,7323 lines in the optical to probe the disc structure. We find that the emission originates from multiple ring structures around all B[e] supergiants, with each one of them displaying a unique combination of rings regardless of whether the object is part of a binary system. The confirmed binaries display spectroscopic variations of their line intensities and profiles as well as photometric variability, whereas the ring structures around the single stars are stable.Instituto de Astrofísica de La PlataFacultad de Ciencias Astronómicas y Geofísica

SEMICONDUCTOR DEVICE FOR DETECTION OF FRET SIGNALS

The transducer consists on a semiconductor device based on two stacked-i-n  heterostructures, that were designed to detect the emissions of the fluorescence resonance energy transfer between fluorophores in the cyan (470 nm) and yellow (588 nm) range of the spectrum. This research represents a preliminary study on the use of such wavelength sensitive devices as photodetectors for this kind of application. The device was characterized through optoelectronic measurements concerning spectral response measurements under different electrical and optical biasing conditions. To simulate the FRET pairs a chromatic time dependent combination of cyan and yellow wavelengths was applied to the device. The generated photocurrent was measured under reverse and forward bias to readout the output photocurrent signal. Different wavelength biasing light was also superimposed. Results show that under reverse bias the photocurrent signal presents four separate levels each one assigned to the different wavelength combinations of the FRET pairs. If a blue background is superimposed the yellow channel is enhanced and the cyan suppressed while under red irradiation the opposite behavior occurs. So under suitable biasing light the transducer is able to detect separately the cyan and yellow fluorescence pairs. An electrical model, supported by a numerical simulation supports the transduction mechanism of the device