Analysis of ZDDP content and thermal decomposition in motor oils using NAA and NMR

Zinc dialkyldithiophosphates (ZDDPs) are one of the most common anti-wear additives present in commercially-available motor oils. The ZDDP concentrations of motor oils are most commonly determined using inductively coupled plasma atomic emission spectroscopy (ICP-AES). As part of an undergraduate research project, we have determined the Zn concentrations of eight commercially-available motor oils and one oil additive using neutron activation analysis (NAA), which has potential for greater accuracy and less sensitivity to matrix effects as compared to ICP-AES. The 31P nuclear magnetic resonance (31P-NMR) spectra were also obtained for several oil additive samples which have been heated to various temperatures in order to study the thermal decomposition of ZDDPs.Comment: Manuscript has been accepted for publication in Physics Procedia as part of the proceedings of the 23rd International Conference on Application of Accelerators in Research and Industry (CAARI 2014

Supporting arts and science communities on-line

This paper examines the use of the Web to support continuing professional development (CPD). It outlines the factors driving the adoption of CPD and highlights areas where the Web can aid in the development of successful professional communities. A survey examining the use of the Internet to support professionals working in the domains of the Arts and Science is presented. The study reviews twenty four sites for the presence and degree of adoption of several key features including: - community building, range and value of content, user friendliness and guidance, sophistication of employed Web technology

MGGPOD: a Monte Carlo Suite for Modeling Instrumental Line and Continuum Backgrounds in Gamma-Ray Astronomy

Intense and complex instrumental backgrounds, against which the much smaller signals from celestial sources have to be discerned, are a notorious problem for low and intermediate energy gamma-ray astronomy (~50 keV - 10 MeV). Therefore a detailed qualitative and quantitative understanding of instrumental line and continuum backgrounds is crucial for most stages of gamma-ray astronomy missions, ranging from the design and development of new instrumentation through performance prediction to data reduction. We have developed MGGPOD, a user-friendly suite of Monte Carlo codes built around the widely used GEANT (Version 3.21) package, to simulate ab initio the physical processes relevant for the production of instrumental backgrounds. These include the build-up and delayed decay of radioactive isotopes as well as the prompt de-excitation of excited nuclei, both of which give rise to a plethora of instrumental gamma-ray background lines in addition to continuum backgrounds. The MGGPOD package and documentation are publicly available for download from http://sigma-2.cesr.fr/spi/MGGPOD/. We demonstrate the capabilities of the MGGPOD suite by modeling high resolution gamma-ray spectra recorded by the Transient Gamma-Ray Spectrometer (TGRS) on board Wind during 1995. The TGRS is a Ge spectrometer operating in the 40 keV to 8 MeV range. Due to its fine energy resolution, these spectra reveal the complex instrumental background in formidable detail, particularly the many prompt and delayed gamma-ray lines. We evaluate the successes and failures of the MGGPOD package in reproducing TGRS data, and provide identifications for the numerous instrumental lines.Comment: 60 pages, 13 figures, 7 tables, accepted for publication in ApJ

Distributed resource discovery using a context sensitive infrastructure

Distributed Resource Discovery in a World Wide Web environment using full-text indices will never scale. The distinct properties of WWW information (volume, rate of change, topical diversity) limits the scaleability of traditional approaches to distributed Resource Discovery. An approach combining metadata clustering and query routing can, on the other hand, be proven to scale much better. This paper presents the Content-Sensitive Infrastructure, which is a design building on these results. We also present an analytical framework for comparing scaleability of different distribution strategies

Unique case of inverted papilloma of septum with nasopharyngeal carcinoma:Is it a metachronous tumour?

Inverted papilloma is a rare and benign tumour. It affects the nasal cavity and paranasal sinuses, has a high rate of recurrence and is associated with malignant transformation. Only few cases of a poorly differentiated carcinoma arising from inverted papilloma have been reported, none of which in the nasopharynx. We report a case of a 37-year-old female, who presented originally in 2012 with inverted papilloma of the nasal septum which was surgically resected. Nasopharyngeal biopsy from 2014 was reported as carcinoma in situ and treated with local endoscopic resection. Three years later she presented with a solitary lesion of the right Eustachian tube opening, confirmed as invasive poorly differentiated carcinoma. Imaging revealed T4 N2b M0 malignancy with skull base and prevertebral space invasion, likely extension into right temporal lobe and malignant adenopathy. Although rare, malignant transformation of inverted papilloma in unusual places should be considered during workup and monitoring of patients

The Spectacular Ionized Interstellar Medium of NGC55

We present deep Halpha+[NII], [SII] (6716,6731A) and [OII] (3726,3729A) images of the highly inclined, actively star--forming SBm galaxy NGC 55, located in the nearby Sculptor Group. Due to its proximity, NGC 55 provides a unique opportunity to study the disk--halo interface in a late--type galaxy with unprecedented spatial resolution. Our images reveal a spectacular variety of ionized gas features, ranging from giant HII region complexes, to supergiant filamentary and shell features, to patches of very faint diffuse emission. Many of these features protrude well above the plane of the galaxy, including a very faint fragmented shell of emission which is visible at 2.6 kpc above the disk. We identify candidate `chimneys' extending out of the disk, which could be the conduits into the halo for hot gas around disk star-forming regions, and could also provide low-density paths for the passage of UV photons from the disk to the halo. Several of the identified chimneys are `capped' with clumps of ionized gas, one of which, located at 1.5 kpc above the disk plane, appears to be the site of recent star formation. Emission--line ratios ([OII]/Halpha+[NII], [SII]/Halpha+[NII]) constrain the ionization mechanism of the gas, and our images allow the first measurement of [OII]/Halpha+[NII] in extra-planar diffuse ionized gas. The diffuse gas is characterized by emission--line ratios which are enhanced on average by a factor of two compared to those of bright HII regions. Each line ratio increases in value smoothly from the cores of HII regions, through the haloes of HII regions, into the diffuse ionized gas. Such a continuous trend is predicted by models in which the diffuse gas is ionized by photons produced by massive stars in HII regions.Comment: 19 pages, including 4 figures, plus 2 external tables. Accepted for publication in the Astronomical Journal. Compressed, postscript versions of the plates are available at ftp://skysrv.pha.jhu.edu/ferguson

Structural templating as a route to improved photovoltaic performance in copper phthalocyanine/fullerene (C60) heterojunctions

We have developed a method to improve the short circuit current density in copper phthalocyanine (CuPc)/fullerene (C60) organic solar cells by ~60% by modifying the CuPc crystal orientation through use of a molecular interlayer to maximize charge transport in the direction between the two electrodes. Powder x-ray diffraction and electronic absorption spectroscopy show that a thin 3,4,9,10-perylenetetracarboxylic dianhydride interlayer before CuPc growth templates the CuPc film structure, forcing the molecules to lie flat with respect to the substrate surface, although the intrastack orientation is unaffected. This modified stacking configuration facilitates charge transport and improves charge collection