下地壳及壳慢过渡带化学不均一性 -- 河北汉诺坝地区深源捕虏体元素地球化学证据

河北汉诺坝玄武岩中长英质麻粒岩、镁铁质麻粒岩和辉石岩捕虏体的主量元素和微量元素特征, 反映了下地壳及壳鳗过渡带组成具有高度化学不均一性。不相容元素原始地慢标准化曲线特征的差异表明捕虏体成因复杂。MgO 与不相容元素无或仅有很弱的相关性, 与相容元素的相关性则相对较明显。这些特征反映了下地壳及壳慢过渡带存在较强和多元的混合作用。捕虏体的加权平均值比基于麻粒岩地体资料估算的下地壳平均组成偏基性, 揭示了二者可能的成因差异。The major and trace element data of granulite and pyroxenite xenoliths, which are entrained in Hannuoba basalt Hebei Province, North China, suggest the highly chemical heterogeneity in the lower crust and crust-mantle transitional zone. There is no or only POor linear correlation between MgO and incompatible elements. Whereas a bit remarked correlations are observed between MgO and most compatible elements.The geochemical characteristics suggest that the strong and multiple mixing processes may have Occurred universally both in the lower crust and crust-mantle transitional zone. The weighed average composition of xenoliths shows a more mafic composition of the lower crust than that estimated from granulite data, which may imply the difference in the genesis.published_or_final_versio

Sr, Nd Pb isotopic characteristics of granulite and pyroxenite xenoliths in Hannuoba basalts, Hebei Province, and their implications for geologic processes

Rb-Sr, Sm-Nd and Pb isotopic systematics are reported for granulite and pyroxenite xenoliths in Hannuoba basalts, Hebei Province. The isotopic characteristics of xenoliths suggest t hat they might have formed recently , although there is no strict constraint on the precise age. The decoupling of low Rb/Sr and high [87]Sr/[86]Sr ratios implies the multi-stage evolution history and strong mixing processes. There are close ties between granulite and pyroxenites with different mineral assemblages on the Sr-Nd, Pb-Sr and Pb-Nd correlation figures. The granulite is the common end-member o f the three kinds o f pyroxenite. Combined with the distribution of the xenoliths in space and their isotopic relationships, It is proposed that delamination can be well used to explain the ties.系统研究了河北汉诺坝玄武岩中二辉麻粒岩和辉石岩捕虏体的Sr、Nd、Pb 同位素特征。虽然未确定捕虏体的形成时代, 但同位素特征显示它们可能为较近期( 中生代以来) 形成。低的Rb/Sr 与高 的[87]Sr/[86]Sr 比值的解耦表明捕虏体的形成经历了较强的混合作用。在二元同位素相关图上, 三类具不同矿物组成的辉石岩与二辉麻粒岩有密切关系, 即二辉麻粒岩投点位置是三类辉石岩的共同端点。综合考虑捕虏体的空间分布及其在Sr 、Nd、Pb 同位素协变图上的关系, 可以认为层离作用可较好地解释这些现象。published_or_final_versio

Synthesis and characterization of interspecific trigenomic hybrids and allohexaploids between three cultivated Brassica allotetraploids and wild species Brassica fruticulosa

Interspecific reciprocal crosses between three cultivated Brassica allotetraploids and one wild species Brassica fruticulosa (FF, 2n =16) were made and the trigenomic hybrids were produced only with embryo rescue. From the crosses with Brassica juncea (AABB, 2n = 36) and Brassica napus (AACC, 2n = 38), hybrids (F.AB, 2n = 26; F.AC, 2n = 27) were obtained only with B. fruticulosa as female, but the reciprocal crosses with Brassica carinata (BBCC, 2n = 34) gave rise to hybrids (F.BC/BC.F, 2n = 25). These hybrids showed an intermediate morphology and were sterile for male and female except those with B. carinata. All the triploids showed high frequency of bivalents during diakinesis and metaphase I (MI) of meiosis. The allohexaploids (FF.AABB, 2n = 52; FF.AACC, 2n = 54; BBCC.FF, 2n = 50) were synthesized by colchicine treatments of respective hybrids in vitro, which showed growth vigor and had larger stature than the hybrids, but were male sterile except one (FF.AABB). They produced progenies with the expected chromosome complements (F.AABB, 2n = 44; F.AACC, 2n = 46; BBCC.F, 2n = 42) after pollination by respective Brassica allotetraploids. In these allohexaploids, chromosomes were mainly paired as bivalents at diakinesis and segregated equally at anaphase I (AI) during meiosis of pollen mother cells (PMCs). These allohexaploids and progenies were valuable for the breeding of Brassica crops.Key words: Brassica allotetraploids, Brassica fruticulosa, interspecific hybrids, crossability, morphology, genomic affinity

Cassiterite oxygen isotopes in magmatic-hydrothermal systems: in situ microanalysis, fractionation factor, and applications

Tin and tungsten are important metals for the industrializing society. Deciphering the origin and evolution of hydrothermal fluids responsible for their formation is critical to underpin genetic models of ore formation. Traditional approaches obtain isotopic information mainly from bulk analysis of both ore and gangue minerals, or less frequently from in situ analysis of gangue minerals, which either bear inherited complexities and uncertainties or are indirect constraints. Hence, directly obtaining isotopic information from ore minerals such as cassiterite by in situ techniques is warranted. However, this has been hampered by challenges from both analytical and applicational aspects. In this study, we first demonstrate a lack of crystallographic orientation effects during cassiterite ion microprobe oxygen isotope analysis. Along with our newly developed matrix-matched reference material, the Yongde-Cst, which has a recommended δ18O value of 1.36 ± 0.16‰ (VSMOW) as defined by gas source isotope ratio mass spectrometry, in situ oxygen isotope analysis of cassiterite now is possible. We further refine the oxygen isotope fractionation (1000 ln α) for quartz-cassiterite by first-principles calculations, which is given by the equation of 1.259 × 106/T2 + 8.15 × 103/T − 4.72 (T is temperature in Kelvin). The 1000 ln α for quartz-cassiterite has a sensitive response to temperature, and makes cassiterite-quartz an excellent mineral pair in oxygen isotope thermometry, as described by the equation of T (℃) = 2427 × (δ18Oqtz − δ18Ocst)−0.4326 − 492.4. Using the well-established 1000 ln α of quartz-water, 1000 ln α of cassiterite-water is derived as 2.941 × 106/T2 − 11.45 × 103/T + 4.72 (T in Kelvin), which shows a weak response to temperature. This makes cassiterite an ideal mineral from which to derive δ18O of fluids as robust temperature estimates are no longer a prerequisite. We have applied oxygen isotope analysis to cassiterite samples from six Sn(-W) deposits in China. The results show considerable variability in δ18O values both within a single deposit and among studied deposits. Combining the δ18O of cassiterite samples and the equilibrium oxygen isotope fractionation, we find that the δ18O values of ore-forming fluids show a strong magmatic affinity with variable but mostly no to low degree involvements (~0-10%) of meteoric water, hence our results invite a reassessment on the extent and role of meteoric water in Sn-W mineralization. This study demonstrates that in situ oxygen isotope analysis of cassiterite is a promising tool to refine sources of ore-forming fluids, and to decode hydrothermal dynamics controlling tin and tungsten mineralization

Effect of ZnCdTe-Alloyed Nanocrystals on Polymer–Fullerene Bulk Heterojunction Solar Cells

The photovoltaic properties of solar cell based on the blends of poly[2-methoxy-5-(2-ethylhexoxy-1,4-phenylenevinylene) (MEH-PPV), fullerene (C60), and ZnCdTe-alloyed nanocrystals were investigated. Comparing the spectral response of photocurrent of the MEH-PPV:C60(+ZnCdTe) nanocomposite device with that of the devices based on MEH-PPV:C60and pristine MEH-PPV, one can find that the nanocomposite device exhibits an enhanced photocurrent. In comparing the composite devices with different ZnCdTe:[MEH-PPV + C60] weight ratios of 10 wt% (D1–1), 20 wt% (D1–2), 40 wt% (D1–3), and 70 wt% (D1–4), it was found that the device D1–3exhibits the best performance. The power conversion efficiency (η) is improved doubly compared with that of the MEH-PPV:C60device

Rhabdastrellic Acid-A Induced Autophagy-Associated Cell Death through Blocking Akt Pathway in Human Cancer Cells

BACKGROUND: Autophagy is an evolutionarily conserved protein degradation pathway. A defect in autophagy may contribute to tumorigenesis. Autophagy inducers could have a potential function in tumor prevention and treatment. METHODOLOGY/PRINCIPAL FINDINGS: Our results showed that Rhabdastrellic acid-A, an isomalabaricane triterpenoid isolated from the sponge Rhabdastrella globostellata, inhibited proliferation of human cancer cell lines Hep3B and A549 and induced caspase-independent cell death in both the cell lines. Further investigation showed that Rhabdastrellic acid-A induced autophagy of cancer cells determined by YFP-LC3 punctation and increased LC3-II. The pretreatment with autophagy inhibitor 3-MA inhibited Rhabdastrellic acid-A-induced cell death. Knockdown of autophagy-related gene Atg5 inhibited Rhabdastrellic acid-A-induced cell death in A549 cells. Also, phospho-Akt and its downstream targets significantly decreased after treatment with Rhabdastrellic acid-A in both cancer cell lines. Transfection of constitutive active Akt plasmid abrogated autophagy and cell death induced by Rhabdastrellic acid-A. CONCLUSIONS/SIGNIFICANCE: These results suggest that Rhabdastrellic acid-A could induce autophagy-associated cell death through blocking Akt pathway in cancer cells. It also provides the evidence that Rhabdastrellic acid-A deserves further investigation as a potential anticancer or cancer preventive agent

Experimental simulation of quantum tunneling in small systems

It is well known that quantum computers are superior to classical computers in efficiently simulating quantum systems. Here we report the first experimental simulation of quantum tunneling through potential barriers, a widespread phenomenon of a unique quantum nature, via NMR techniques. Our experiment is based on a digital particle simulation algorithm and requires very few spin-1/2 nuclei without the need of ancillary qubits. The occurrence of quantum tunneling through a barrier, together with the oscillation of the state in potential wells, are clearly observed through the experimental results. This experiment has clearly demonstrated the possibility to observe and study profound physical phenomena within even the reach of small quantum computers.Comment: 17 pages and 8 figure

Fabrication of one-dimensional Ag/multiwalled carbon nanotube nano-composite

Composite made of multiwalled carbon nanotubes coated with silver was fabricated by an electroless deposition process. The thickness of silver layer is about 40 to 60 nm, characterized as nano-crystalline with (111) crystal orientation along the nanotube's axial direction. The characterization of silver/carbon nanotube [Ag/CNT] nanowire has shown the large current carrying capability, and the electric conductivity is similar to the pure silver nanowires that Ag/CNT would be promising as building blocks for integrated circuits

Heavily electron-doped electronic structure and isotropic superconducting gap in AxFe2Se2 (A=K,Cs)

The low energy band structure and Fermi surface of the newly discovered superconductor, AxFe2Se2 (A=K,Cs), have been studied by angle-resolved photoemission spectroscopy. Compared with iron pnictide superconductors, AxFe2Se2 (A=K,Cs) is the most heavily electron-doped with Tc~30 K. Only electron pockets are observed with an almost isotropic superconducting gap of ~10.3 meV, while there is no hole Fermi surface near the zone center, which indicates the inter-pocket hopping or Fermi surface nesting is not a necessary ingredient for the unconventional superconductivity in iron-based superconductors. Thus, the sign changed s$_\pm$ pairing symmetry, a leading candidate proposed for iron-based superconductors, becomes conceptually irrelevant in describing the superconducting state here. A more conventional s-wave pairing is a better description.Comment: 4 pages, 4 figures, published online in Nature Materials 201

Observation of CR Anisotropy with ARGO-YBJ

The measurement of the anisotropies of cosmic ray arrival direction provides important informations on the propagation mechanisms and on the identification of their sources. In this paper we report the observation of anisotropy regions at different angular scales. In particular, the observation of a possible anisotropy on scales between $\sim$ 10 $^{\circ}$ and $\sim$ 30 $^{\circ}$ suggests the presence of unknown features of the magnetic fields the charged cosmic rays propagate through, as well as potential contributions of nearby sources to the total flux of cosmic rays. Evidence of new weaker few-degree excesses throughout the sky region $195^{\circ}\leq$ R.A. $\leq 315^{\circ}$ is reported for the first time.Comment: Talk given at 12th TAUP Conference 2011, 5-9 September 2011, Munich, German