Study of the pyrolysis mechanism of SiBCN polymer precursor

The pyrolysis mechanisms occurring during the conversion of polyborosilazane (PBSZ) into amorphous SiBCN cerasmic have been investigated. TGA–TDG experiment have been applied to investigate the mass loss behaviour during ceramization. Solid-state 11B, 13C and 29Si NMR spectroscopy has been applied to probe the local environment of all NMR active nuclei in the precursor, the thermolysis intermediates and the ceramic residue. IR spectroscopy has been performed to receive valuable information on the chemical bonding in all materials. At temperature below 400oC, Si-N bonds are formed via condensation reaction involving N-H and Si-H units with hydrogen released. It is followed by evolution of hydrocarbons due to the cleavage of bonds and formation of methane and hydrogen at 600 oC. After heating to 1000 oC, ceramization complete and free carbon, BN3 domains as well as Si–C–N units coexist SiCxN4-x,x=0,1,2,3. And BN3 keep unchanged during the whole ceramization stage

Characterization of 35 novel microsatellite DNA markers from the duck (Anas platyrhynchos) genome and cross-amplification in other birds

In order to study duck microsatellites, we constructed a library enriched for (CA)n, (CAG)n, (GCC)n and (TTTC)n. A total of 35 pairs of primers from these microsatellites were developed and used to detect polymorphisms in 31 unrelated Peking ducks. Twenty-eight loci were polymorphic and seven loci were monomorphic. A total of 117 alleles were observed from these polymorphic microsatellite markers, which ranged from 2 to 14 with an average of 4.18 per locus. The frequencies of the 117 alleles ranged from 0.02 to 0.98. The highest heterozygosity (0.97) was observed at the CAUD019 microsatellite locus and the lowest heterozygosity (0.04) at the CAUD008 locus, and 11 loci had heterozygosities greater than 0.50 (46.43%). The polymorphism information content (PIC) of 28 loci ranged from 0.04 to 0.88 with an average of 0.42. All the above markers were used to screen the polymorphism in other bird species. Two markers produced specific monomorphic products with the chicken DNA. Fourteen markers generated specific fragments with the goose DNA: 5 were polymorphic and 9 were monomorphic. But no specific product was detected with the peacock DNA. Based on sequence comparisons of the flanking sequence and repeat, we conclude that 2 chicken loci and 14 goose loci were true homologous loci of the duck loci. The microsatellite markers identified and characterized in the present study will contribute to the genetic map, quantitative traits mapping, and phylogenetic analysis in the duck and goose

Integrated molecular diode as 10 MHz half-wave rectifier based on an organic nanostructure heterojunction

Considerable efforts have been made to realize nanoscale diodes based on single molecules or molecular ensembles for implementing the concept of molecular electronics. However, so far, functional molecular diodes have only been demonstrated in the very low alternating current frequency regime, which is partially due to their extremely low conductance and the poor degree of device integration. Here, we report about fully integrated rectifiers with microtubular soft-contacts, which are based on a molecularly thin organic heterojunction and are able to convert alternating current with a frequency of up to 10 MHz. The unidirectional current behavior of our devices originates mainly from the intrinsically different surfaces of the bottom planar and top microtubular Au electrodes while the excellent high frequency response benefits from the charge accumulation in the phthalocyanine molecular heterojunction, which not only improves the charge injection but also increases the carrier density

An Improved ip − iq Harmonic Detection Method Based on Time-Varying Integral Duration

By analyzing harmonic related to instantaneous active current and instantaneous reactive current, we propose an improved harmonic detection method to remedy long response delay and low detection accuracy corresponding to harmonic of power system. This method introduces a series connection scheme composed of Low-Pass Filter (LPF) and a current average module firstly. Then, detection accuracy of harmonic current is enhanced by adaptive tuning cut-off frequency of LPF and integration time which was obtained by proposed algorithm of the current average module. Moreover, feedback loop is introduced to compensated delay caused by LPF. Simulations including uncontrollable rectifier and three-phase voltage type inverter show proposed method has many advantages such as high detection accuracy, low response delay and good generality. Our method provides reliable harmonic current detection for later harmonic suppression and harmonic compensation

A Numerical Model of Vapour Transfer and Phase Change in Unsaturated Freezing Soils

In recent studies, vapour transfer is reported to lead to remarkable frost heave in unsaturated soils, but how to better model this process has not been answered. In order to avoid the great uncertainty caused by the phase change term of vapour-water-ice in the numerical iteration process, a new numerical model is developed based on the coupled thermal and hydrological processes. The new model avoids using the local equilibrium assumption and the hydraulic relations that accounts for liquid water flow, which provides a new way for the water-heat coupling movement problem. The model is established by using COMSOL Multiphysics, which is a multiphysics simulation software through finite element analysis. The model is evaluated by comparing simulated results with data from column freezing experiments for unsaturated coarse-grained soils. Simulated values of the total water content compare well with experimental values. The model is proved to be applicable and numerically stable for a high-speed railway subgrade involving simultaneous heat and moisture transport. An agreement can be found between the predicted and measured frost/thawed depth and soil moisture profiles, demonstrating that the model is able to simulate rapidly changing boundary conditions and nonlinear water content profiles in the soil

Agapetes heana, a new species of A. ser. Longifiles (Ericaceae) from Yunnan, China

Agapetes heana Y. H. Tong & J. D. Ya (Ericaceae), a new species from Lüchun Xian, Yunnan Province, China is described and illustrated. This new species is assigned to Agapetes sect. Agapetes ser. Longifiles Airy Shaw. It is closest to A. inopinata Airy Shaw and A. oblonga Craib, but differs in having bead-like tubers, leaf blade with a wholly serrulate margin, subulate and much longer calyx lobes, much larger corollas that are carmine, green at the apex and maroon on angles, and longer stamens without spurs on the back