Seagoing War Machine: Men, Innovations Decisive For Union Navy

Dennis J. Ringle\u27s Life in Mr. Lincoln\u27s Navy is both a groundbreaking work of naval history and a pleasure to read. Ringle chronicles the Union navy from the antebellum reform movement to the steam-powered Monitor-class ironclad. Moreover, this well-researched book is a compendium of ...

Limits of Identification Using VUV Spectroscopy Applied to C8H18 Isomers Isolated by GC 7GC

13-C-AJFE-UD-026This is an open access article under the terms of the Creative Commons Attribution 4.0 International (CC BY 4.0) license https://creativecommons.org/licenses/by/4.0/. Please cite this article as: Bell DC, Feldhausen J, Spieles AJ, Boehm RC, Heyne JS. Limits of identification using VUV spectroscopy applied to C8H18 isomers isolated by GC 7GC. Talanta. 2023 Jun 1;258:124451. https://doi.org/10.1016/j.talanta.2023.124451The vacuum ultraviolet detector for gas chromatography can be used to identify structural differences between isomers with similar chromatographic elution times, which adds detail to characterization, valuable for prescreening of sustainable aviation fuel candidates. Although this capability has been introduced elsewhere, vacuum ultraviolet spectroscopy for saturated hydrocarbons has been examined minimally, as the similarities between their spectra are much less significant than their aromatic counterparts. The fidelity with which structural differences can be identified has been unclear. In this work, all possible structural isomers of C8H18 are measured and determined to have unambiguously unique vacuum ultraviolet spectra. Using a statistically based residual comparison approach, the concentration limits at which the spectral differences are interpretable are tested in both a controlled study and a real fuel application. The concentration limit at which the spectral differences between C8H18 isomers are unambiguous is below 0.40% by mass and less than 0.20% with human discretion in our experimental configuration

The co-optimization of sustainable aviation fuel: Cost, emissions, and performance

The combustion of petroleum-based fuels contributes to increases in atmospheric CO2, contributing to climate change. As other sectors electrify, current battery technology makes this impractical for the aviation industry. The fastest pathway to reducing the carbon contributions of aviation is to create low or no net carbon-emitting drop-in petroleum alternatives. This research explores 3 potential sorghum derived jet fuel molecules from 4 different production routes, hydro-processed esters and fatty acids (HEFA), and Jet A, to identify how blends including these fuels could offer improved performance (MJ/kg, MJ/L) and improved emissions (gCO2/MJ) while minimizing costs. Different applications will value each target metric differently. This research utilizes the Jet Fuel Blend Optimizer (JudO) to create a 4-dimensional Pareto front across potential solutions. The molecules considered will not offer reduced cost compared to conventional jet fuel (Jet A), but they can be utilized to create blends with higher specific energy, greater energy density, and reduced greenhouse gas emissions. Considerations including carbon credits, the sale of byproducts, and the valuation of improved performance will make the proposed molecules more commercially viable. At the lowest region of GHG solutions, coupled with equivalent LCFS approximations, JudO determined blends that could achieve as high as 69% overall carbon reductions at a premium of $0.34/L

The co-optimization of sustainable aviation fuel: Cost, emissions, and performance

The combustion of petroleum-based fuels contributes to increases in atmospheric CO2, contributing to climate change. As other sectors electrify, current battery technology makes this impractical for the aviation industry. The fastest pathway to reducing the carbon contributions of aviation is to create low or no net carbon-emitting drop-in petroleum alternatives. This research explores 3 potential sorghum derived jet fuel molecules from 4 different production routes, hydro-processed esters and fatty acids (HEFA), and Jet A, to identify how blends including these fuels could offer improved performance (MJ/kg, MJ/L) and improved emissions (gCO2/MJ) while minimizing costs. Different applications will value each target metric differently. This research utilizes the Jet Fuel Blend Optimizer (JudO) to create a 4-dimensional Pareto front across potential solutions. The molecules considered will not offer reduced cost compared to conventional jet fuel (Jet A), but they can be utilized to create blends with higher specific energy, greater energy density, and reduced greenhouse gas emissions. Considerations including carbon credits, the sale of byproducts, and the valuation of improved performance will make the proposed molecules more commercially viable. At the lowest region of GHG solutions, coupled with equivalent LCFS approximations, JudO determined blends that could achieve as high as 69% overall carbon reductions at a premium of $0.34/L

Limits of identification using VUV spectroscopy applied to C8H18 isomers isolated by GC×GC

The vacuum ultraviolet detector for gas chromatography can be used to identify structural differences between isomers with similar chromatographic elution times, which adds detail to characterization, valuable for prescreening of sustainable aviation fuel candidates. Although this capability has been introduced elsewhere, vacuum ultraviolet spectroscopy for saturated hydrocarbons has been examined minimally, as the similarities between their spectra are much less significant than their aromatic counterparts. The fidelity with which structural differences can be identified has been unclear. In this work, all possible structural isomers of C8H18 are measured and determined to have unambiguously unique vacuum ultraviolet spectra. Using a statistically based residual comparison approach, the concentration limits at which the spectral differences are interpretable are tested in both a controlled study and a real fuel application. The concentration limit at which the spectral differences between C8H18 isomers are unambiguous is below 0.40% by mass and less than 0.20% with human discretion in our experimental configuration.[Display omitted]•Ultraviolet spectra of all 18 constitutional isomers of octane are reported.•The spectra of each isomer of octane is shown to be unique and unambiguously distinguishable.•Limits of identification are determined to be <0.20%m for the isomers of octane.•Identification of an 0.16%m iso-alkane peak in Jet A was positively identified as 3-methylheptane

Integrated Hardfacing of Stellite-6 Using Hybrid Manufacturing Process

Hybrid manufacturing systems provide a platform for integrated additive, subtractive and inspection methods on a single machine setup. The present work explores use of hybrid manufacturing for hardfacing of performance components for improving wear resistance. In this work, Stellite-6 was applied to a 410 stainless steel substrate using a hybrid manufacturing system incorporating multi-axis directed energy deposition and machining. Experimental testing was conducted to determine the effects of hybrid manufacturing parameters on internal porosity, surface porosity and microstructure in the cladded material, as well as on the roughness of the final machined surface. Correlation between porosity measurements made by x-ray tomography and surface inspection is presented and determination of ideal process parameters for hardfacing of components using hybrid manufacturing systems is briefly discussed. A deposition process is presented and implemented on a large industrial component. The component is inspected using dye-penetrant testing and metallographic techniques.Mechanical Engineerin