Inhibition effect of 2-amino-5-ethyl-1, 3, 4-thiadiazole on corrosion behaviour of austenitic stainless steel type 304 in dilute HCl solution

The corrosion inhibition of type 304 austenitic stainless steel by 2-amino-5-ethyl-1, 3, 4-thiadiazole (TTD) compound and the electrochemical behaviour in dilute HCl solution were investigated through potentiodynamic polarization test, mass loss techniques and potential measurements. The results show that the organic derivative is highly effective with a maximum inhibition efficiency of 70.22% from mass loss analysis, while 74.2% is obtained from polarization tests. Observation of the scanning electron micrographs shows the absence of corrosion products due to electrochemical influence of TTD on the surface morphology of the steel. X-ray diffractometry reveals the absence of phase compounds and complexes on the steel samples after exposure. TTD adsorption on the steel surface obeys the Langmuir, Frumkin and Freundlich adsorption isotherms. Corrosion thermodynamic calculations reveal the inhibition mechanism occurs through chemisorption process and results from statistical analysis depict the strong influence of inhibitor concentration on the electrochemical performance of the TTD

Inhibition Effect of 2-Amino, 5-Ethyl- 1, 3, 4 Thiadiazole on the Corrosion of Austenitic Stainless Steel Type 304 in Dilute Sulphuric Acid

The inhibition effect of 2- amino, 5- ethyl- 1, 3, 4 thiadiazole (TTD) compound on the corrosion of type 304 stainless steel in 3 M H2SO4 test solution was investigated using potentiodynamic polarization, weight loss techniques and open circuit potential measurements. Results showed TTD to be very effective with an average inhibition efficiency of 98% from weight loss analysis and 87% from polarization test. Data from open circuit potential measurement are well within passivation potentials at specific concentrations of TTD. Scanning electron microscopy showed the effect of the inhibiting compound on the surface topography of the steel, while X - ray diffractometry determined the phase compounds formed on the surface due to inhibitor adhesion. Adsorption of the compound was determined to obey the Langmuir isotherm model. Thermodynamic calculations showed the inhibition process occurred through chemisorption mechanism and results from statistical analysis revealed the overwhelming influence of inhibitor concentration over exposure time on the inhibition performance of the compound

Inhibition effect of butan-1-ol on the corrosion behavior of austenitic stainless steel (Type 304) in dilute sulfuric acid

The electrochemical behavior of austenitic stainless steel (Type 304) in 3 M sulfuric acid with 3.5% recrystallized sodium chloride at specific concentrations of butan-1-ol was investigated with the aid of potentiodynamic polarization, open circuit measurement and weight loss technique. Butan-1-ol effectively inhibited the steel corrosion with a maximum inhibition efficiency of 78.7% from weight-loss analysis and 80.9% from potentiodynamic polarization test at highest concentration studied. Adsorption of the compound obeyed the Freundlich isotherm. Thermodynamic calculations reveal physiochemical interactions and spontaneous adsorption mechanism. Surface characterizations showed the absence of corrosion products and topographic modifications of the steel. Statistical analysis depicts the overwhelming influence and statistical significance of inhibitor concentration on the inhibition performanc

Volume One (Birgit Krohn Albums)

The first of Birgit Krohn\u27s three albums containing printed and manuscrip] music, much of which was likely collected during her time at Nikka Vonen\u27s school for girls in Dale, Norway.https://scholarexchange.furman.edu/krohn-album1/1000/thumbnail.jp

Inhibition Effect of N, N'-Dimethylaminoethanol on the Pitting Corrosion Austenitic Stainless Steel Type 304

The electrochemical influence and corrosion inhibition of N, N'-dimethylaminoethanol on the pitting corrosion resistance of austenitic stainless steel (type 304) in dilute sulphuric acid solution with sodium chloride addition was investigated using potentiodynamic polarization technique. Corrosion potential, pitting potential, passivation potential, nucleation resistance, passivation range and repassivation capacity measurements and potentiodynamic analysis were used to evaluate the steel’s pitting resistance characteristics. The potentiodynamic experiments revealed that pitting potential increased with increase in concentration of the inhibiting compound coupled with an increase in the passivation range hence increased resistance to pittinggcorrosion

Sustainable development of the Russian market of organic agro-industrial complex

Organic agriculture is a dynamically developing area of the global agro-industrial complex. Global climate problems and the depletion of natural resources across the planet dictate the need to review the food production technologies used. Excessive intensification of agricultural production through soil mineralization and fertilization, hormonal stimulation of animal and plant growth has led to the deterioration of water, soil, air quality and overall health. Therefore, the problem of reducing the anthropogenic impact on the environment is the main trend of implementing the principles of organic production. The paper developed recommendations for the strategic development of the Russian market of organic production within the framework of the current EAEU agreement. Conclusions were made on the expansion of instruments of state incentives for the development of organic agricultural production in a changing world economic relations and integration. © The Authors, published by EDP Sciences, 2023

Gigantic Magnetoresistive Effect in n-SiSiO2Ni Nanostructures Fabricated by the Template-Assisted Electrochemical Deposition

The study of the carrier transport and magnetotransport in n-Si/SiO2/Ni nanostructures with granular Ni nanorods embedded into the pores in SiO2 was performed over the temperature range 2 – 300 K and at the magnetic field induction up to 8 T. In n-Si/SiO2/Ni nanostructures at temperatures of about 25 K a huge positive MR effect is observed. Possible mechanisms of the effect is discussed

Magnetotransport in Nanostructured Ni Films Electrodeposited on Si Substrate

The study of electrical resistivity  and magnetoresistance MR in nanogranular Ni films was performed over the temperature range 2 - 300 K and at the magnetic field induction B up to 8 T. The Ni layers having a thickness of about 500 nm were prepared by electrodeposition on n-Si wafers. According to an X-ray diffraction study, a strongly textured face-centered cubic structure was formed in the as-deposited films with an average grain sizes of about 10 - 70 nm. Experiments have demonstrated that the magnetic field and temperature dependences of the MR effect in Ni films shown two main peculiarities: (1) dependencies on the mutual orientations of vectors B, current and the film plane; (2) two contributions to the MR - negative anisotropic magnetoresistance and positive Lorentz-like MR

Lecture-Conversation in Methodological Instrumentation of Russian as a Foreign Language Teacher

The article justifies the urgency of development of lectures-conversations when presenting the theoretical material of the training courses to foreigners. Attention is drawn to the difficulties of foreign students in listening the lecture in its traditional understanding as a monologue of the teacher. The importance of a methodical understanding of the theoretical presentation of the material in question-answer form is emphasised. Scientific novelty and practical significance of research results is seen in the fact that the issues are described from the point of view of the purpose of their performance to the students, the positive effect of the issue, the shortcomings of the question. It is assumed that within this form of classes the teacher can introduce new material, systematize theoretical information studied by students, consolidate students’ knowledge in the subject area, take into account communicative and personal aspects of adaptation of foreign students in Russian educational environment. On the original author’s material of lecture-conversation on theoretical grammar the kinds of questions are demonstrated that are appropriate to use in dialogue with foreign students. Methodological training for teachers in the formulation of various types of questions is proposed. It is concluded that the systematic use of lecture-conversation in teaching practice will contribute to overcoming the communicative and psychological difficulties of foreign students listening to lectures in a foreign language (Russian) that meets the modern trends of multicultural education