306 research outputs found
Field Induced Magnetic Ordering and Single-ion Anisotropy in the Quasi-1D Haldane Chain Compound SrNi2V2O8: A Single Crystal investigation
Field-induced magnetic ordering in the Haldane chain compound
SrNiVO and effect of anisotropy have been investigated using
single crystals. Static susceptibility, inelastic neutron scattering,
high-field magnetization, and low temperature heat-capacity studies confirm a
non-magnetic spin-singlet ground state and a gap between the singlet ground
state and triplet excited states. The intra-chain exchange interaction is
estimated to be 0.1 meV. Splitting of the dispersions into two
modes with minimum energies 1.57 and 2.58 meV confirms the existence of
single-ion anisotropy . The value of {\it D} is estimated to be
meV and the easy axis is found to be along the
crystallographic {\it c}-axis. Field-induced magnetic ordering has been found
with two critical fields [0.2 T and
0.5 T at 4.2 K]. Field-induced
three-dimensional magnetic ordering above the critical fields is evident from
the heat-capacity, susceptibility, and high-field magnetization study. The
Phase diagram in the {\it H-T} plane has been obtained from the high-field
magnetization. The observed results are discussed in the light of theoretical
predictions as well as earlier experimental reports on Haldane chain compounds
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Photofragment Coincidence Imaging of Small I- (H2O)n Clusters Excited to the Charge-transfer-to-solvent State
The photodissociation dynamics of small I{sup -}(H{sub 2}O){sub n} (n = 2-5) clusters excited to their charge-transfer-to-solvent (CTTS) states have been studied using photofragment coincidence imaging. Upon excitation to the CTTS state, two photodissociation channels were observed. The major channel ({approx}90%) is a 2-body process forming neutral I + (H{sub 2}O){sub n} photofragments, and the minor channel is a 3-body process forming I + (H{sub 2}O){sub n-1} + H{sub 2}O fragments. Both process display translational energy (P(E{sub T})) distributions peaking at E{sub T} = 0 with little available energy partitioned into translation. Clusters excited to the detachment continuum rather than to the CTTS state display the same two channels with similar P(E{sub T}) distributions. The observation of similar P(E{sub T}) distributions from the two sets of experiments suggests that in the CTTS experiments, I atom loss occurs after autodetachment of the excited (I(H{sub 2}O){sub n}{sup -})* cluster, or, less probably, that the presence of the excess electron has little effect on the departing I atom
Spin-Wave and Electromagnon Dispersions in Multiferroic MnWO4 as Observed by Neutron Spectroscopy: Isotropic Heisenberg Exchange versus Anisotropic Dzyaloshinskii-Moriya Interaction
High resolution inelastic neutron scattering reveals that the elementary
magnetic excitations in multiferroic MnWO4 consist of low energy dispersive
electromagnons in addition to the well-known spin-wave excitations. The latter
can well be modeled by a Heisenberg Hamiltonian with magnetic exchange coupling
extending to the 12th nearest neighbor. They exhibit a spin-wave gap of 0.61(1)
meV. Two electromagnon branches appear at lower energies of 0.07(1) meV and
0.45(1) meV at the zone center. They reflect the dynamic magnetoelectric
coupling and persist in both, the collinear magnetic and paraelectric AF1
phase, and the spin spiral ferroelectric AF2 phase. These excitations are
associated with the Dzyaloshinskii-Moriya exchange interaction, which is
significant due to the rather large spin-orbit coupling.Comment: 8 pages, 6 figures, accepted for publication in Physical Review
Revisiting the ground state of CoAlO: comparison to the conventional antiferromagnet MnAlO
The A-site spinel material, CoAl2O4, is a physical realization of the
frustrated diamond-lattice antiferromagnet, a model in which is predicted to
contain unique incommensurate or `spin-spiral liquid' ground states. Our
previous single-crystal neutron scattering study instead classified it as a
`kinetically-inhibited' antiferromagnet, where the long ranged correlations of
a collinear Neel ground state are blocked by the freezing of domain wall motion
below a first-order phase transition at T* = 6.5 K. The current paper expands
on our original results in several important ways. New elastic and inelastic
neutron measurements are presented that show our initial conclusions are
affected by neither the sample measured nor the instrument resolution, while
measurements to temperatures as low as T = 250 mK limit the possible role being
played by low-lying thermal excitations. Polarized diffuse neutron measurements
confirm reports of short-range antiferromagnetic correlations and diffuse
streaks of scattering, but major diffuse features are explained as signatures
of overlapping critical correlations between neighboring Brillouin zones.
Finally, and critically, this paper presents detailed elastic and inelastic
measurements of magnetic correlations in a single-crystal of MnAl2O4, which
acts as an unfrustrated analogue to CoAl2O4. The unfrustrated material is shown
to have a classical continuous phase transition to Neel order at T_N = 39 K,
with collective spinwave excitations and Lorentzian-like critical correlations
which diverge at the transition. Direct comparison between the two compounds
indicates that CoAl2O4 is unique, not in the nature of high-temperature diffuse
correlations, but rather in the nature of the frozen state below T*. The higher
level of cation inversion in the MnAl2O4 sample indicates that this novel
behavior is primarily an effect of greater next-nearest-neighbor exchange.Comment: 13 pages, 8 figures, acccepted for publication in Physical Review
Competing exchange interactions on the verge of a metal-insulator transition in the two-dimensional spiral magnet SrFeO
We report a neutron scattering study of the magnetic order and dynamics of
the bilayer perovskite SrFeO, which exhibits a temperature-driven
metal-insulator transition at 340 K. We show that the Fe moments adopt
incommensurate spiral order below K and provide a
comprehensive description of the corresponding spin wave excitations. The
observed magnetic order and excitation spectra can be well understood in terms
of an effective spin Hamiltonian with interactions ranging up to third
nearest-neighbor pairs. The results indicate that the helical magnetism in
SrFeO results from competition between ferromagnetic
double-exchange and antiferromagnetic superexchange interactions whose
strengths become comparable near the metal-insulator transition. They thus
confirm a decades-old theoretical prediction and provide a firm experimental
basis for models of magnetic correlations in strongly correlated metals.Comment: PRL, in pres
Role of commensurate and incommensurate low-energy excitations in the paramagnetic to hidden-order transition of URuSi
We report low-energy inelastic neutron scattering data of the paramagnetic
(PM) to hidden-order (HO) phase transition at in
URuSi. While confirming previous results for the HO and PM phases, our
data reveal a pronounced wavevector dependence of low-energy excitations across
the phase transition. To analyze the energy scans we employ a damped harmonic
oscillator model containing a fit parameter which is expected to
diverge at a second-order phase transition. Counter to expectations the
excitations at show an abrupt step-like suppression of
below , whereas excitations at , associated
with large-moment antiferromagnetism (LMAF) under pressure, show an enhancement
and a pronounced peak of at . Therefore, at the critical HO
temperature , LMAF fluctuations become nearly critical as well. This is
the behavior expected of a super-vector order parameter with nearly degenerate
components for the HO and LMAF leading to nearly isotropic fluctuations in the
combined order-parameter space.Comment: 6 pages; v3 accepted journal version; minor modifications compared to
v
Theory of Superconducting of doped fullerenes
We develop the nonadiabatic polaron theory of superconductivity of
taking into account the polaron band narrowing and realistic
electron-phonon and Coulomb interactions. We argue that the crossover from the
BCS weak-coupling superconductivity to the strong-coupling polaronic and
bipolaronic superconductivity occurs at the BCS coupling constant independent of the adiabatic ratio, and there is nothing ``beyond'' Migdal's
theorem except small polarons for any realistic electron-phonon interaction. By
the use of the polaronic-type function and the ``exact'' diagonalization in the
truncated Hilbert space of vibrons (``phonons'') we calculate the ground state
energy and the electron spectral density of the molecule. This
allows us to describe the photoemission spectrum of in a wide
energy region and determine the electron-phonon interaction. The strongest
coupling is found with the high-frequency pinch mode and with the
Frenkel exciton. We clarify the crucial role of high-frequency bosonic
excitations in doped fullerenes which reduce the bare bandwidth and the Coulomb
repulsion allowing the intermediate and low-frequency phonons to couple two
small polarons in a Cooper pair. The Eliashberg-type equations are solved for
low-frequency phonons. The value of the superconducting , its pressure
dependence and the isotope effect are found to be in a remarkable agreement
with the available experimental data.Comment: 20 pages, Latex, 4 figures available upon reques
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