Structural studies of mesoporous ZrO2_{2}-CeO2_{2} and ZrO2_{2}-CeO2_{2}/SiO2_{2} mixed oxides for catalytical applications

In this work the synthesis of ZrO$_{2}$-CeO$_{2}$ and ZrO$_{2}$-CeO$_{2}$/SiO$_{2}$ were developed, based on the process to form ordered mesoporous materials such as SBA-15 silica. The triblock copolymer Pluronic P-123 was used as template, aiming to obtain crystalline single phase walls and larger specific surface area, for future applications in catalysis. SAXS and XRD results showed a relationship between ordered pores and the material crystallization. 90% of CeO$_{2}$ leaded to single phase homogeneous ceria-zirconia solid solution of cubic fluorite structure (Fm$\bar{3}$m). The SiO$_{2}$ addition improved structural and textural properties as well as the reduction behavior at lower temperatures, investigated by XANES measurements under H$_{2}$ atmosphere

Tumor infiltrating regulatory t cells in sporadic and colitis-associated colorectal cancer: The red little riding hood and the wolf

Regulatory T cells represent a class of specialized T lymphocytes that suppress unwanted immune responses and size the activation of the immune system whereby limiting collateral damages in tissues involved by inflammation. In cancer, the accumulation of Tregs is generally associated with poor prognosis. Many lines of evidence indicate that Tregs accumulation in the tumor microenvironment (TME) suppresses the immune response against tumor-associated antigens (TAA), thus promoting tumor progression in non-small cell lung carcinoma (NSLC), breast carcinoma and melanoma. In colorectal cancer (CRC) the effect of Tregs accumulation is debated. Some reports describe the association of high number of Tregs in CRC stroma with a better prognosis while others failed to find any association. These discordant results stem from the heterogeneity of the immune environment generated in CRC in which anticancer immune response may coexists with tumor promoting inflammation. Moreover, different subsets of Tregs have been identified that may exert different effects on cancer progression depending on tumor stage and their location within the tumor mass. Finally, Tregs phenotypic plasticity may be induced by cytokines released in the TME by dysplastic and other tumor-infiltrating cells thus affecting their functional role in the tumor. Here, we reviewed the recent literature about the role of Tregs in CRC and in colitis-associated colorectal cancer (CAC), where inflammation is the main driver of tumor initiation and progression. We tried to explain when and how Tregs can be considered to be the “good” or the “bad” in the colon carcinogenesis process on the basis of the available data concluding that the final effect of Tregs on sporadic CRC and CAC depends on their localization within the tumor, the subtype of Tregs involved and their phenotypic plasticity

Raman excitation spectroscopy of carbon nanotubes: effects of pressure medium and pressure

Raman excitation and emission spectra for the radial breathing mode (RBM) are reported, together with a preliminary analysis. From the position of the peaks on the two-dimensional plot of excitation resonance energy against Raman shift, the chiral indices (m, n) for each peak are identified. Peaks shift from their positions in air when different pressure media are added - water, hexane, sulphuric acid - and when the nanotubes are unbundled in water with surfactant and sonication. The shift is about 2 - 3 cm-1 in RBM frequency, but unexpectedly large in resonance energy, being spread over up to 100meV for a given peak. This contrasts with the effect of pressure. The shift of the peaks of semiconducting nanotubes in water under pressure is orthogonal to the shift from air to water. This permits the separation of the effects of the pressure medium and the pressure, and will enable the true pressure coefficients of the RBM and the other Raman peaks for each (m, n) to be established unambiguously.Comment: 6 pages, 3 Figures, Proceedings of EHPRG 2011 (Paris

A new electric streamer for the characterization of river embankments

River embankments are linear earth structures, worldwide diffused, commonly used for flood protection. Their integrity and stability are fundamental prerequisites for the protection efficiency they can offer to the increasing frequency and magnitude of extreme flood events associated to changes in climate. Proper characterization and monitoring are essential to verify the construction requirements of newly built structures and to evaluate the durability of aged ones. Considering their linear extent, the characterization requires not only local geotechnical investigations but also the application of efficient and economically affordable methods. This is even more essential when the investigations are performed after, or in foresee of, significant flood events, when these structures get stressed and timing of the surveys is crucial. In these conditions, new survey methodologies, with the use of mobile systems, are a main research topic. In this paper the application of a new electric streamer, specifically designed for these aims, is presented. The technical solutions adopted for its construction are described and its application to the characterization of three different river embankments is presented. These case studies were chosen in accordance with the Po River Interregional Agency (AIPO), which is the authority deputed to the safety of flood protection structures in North-West Italy, along the hydrographic network of the Po River. The selected embankments are all earth structures, constructed above the natural alluvial soils, but are characterized by different conditions and challenges. The results obtained with the new system were comparable to standard Electric Resistivity Tomography (ERT) methods. The new system has significant advantages in terms of reducing the survey time, improving the efficiency of the surveys and increasing the data coverage. This resulted in a better definition of potentially dangerous anomalies

Secondary forest succession in the Mata Atlantica, Brazil: floristic and phytosociological trends.

This study aimed at understanding the dynamics of ecological processes and the use of secondary forests in Santa Catarina state (Brazil). The data base for these studies was formed through forest inventories carried out in the three forest types of the state. The results of this study demonstrate that the patterns of diversity are very similar among the three forest types; however, the species compositions among the types are quite different. A total of 343 woody species belonging to 73 families were found in the 24,000 m2 sampling area, revealing the potential role of secondary forest in the conservation of biodiversity at the landscape scale. As expected, a small set of pioneer species dominates young secondary forests with shade-tolerant species becoming structurally important after 30 years. The patterns of forest structure and species diversity observed in study largely conform to the postagricultural secondary succession observed for many tropical forests.Article ID 759893

Signals to their parliaments? Governments’ use of votes and policy statements in the EU Council

Does parliamentary oversight of governments’ decisions in the international arena matter? This article finds that it does: governments with strong parliamentary oversight behave differently when negotiating policies at the EU level compared with governments with less powerful parliaments. Where parliaments have formal powers to oversee and restrict their government's positions we see a significantly higher use of opposing votes and formal policy statements by those governments. This behaviour intensifies depending on the governments' standing vis‐à‐vis other political parties at home. When governments are under pressure in their national parliaments they are more likely to go on record and take a stand against the majority in Brussels. These results make it clear that in EU legislative politics, governments not only consider their policy priorities and negotiation tactics with their European counterparts, but also make use of EU decision records to send signals to domestic audiences, including their national parliaments

Eta photoproduction off the neutron at GRAAL: Evidence for a resonant structure at W=1.67 GeV

New (preliminary) data on eta photoproduction off the neutron are presented. These data reveal a resonant structure at W=1.67 GeV.Comment: 8 pages, 4 figures. Published in Proceedings of Workshop on the Physics of Excited Nucleons NSTAR2004, Grenoble, France, March 24 - 27, pg.19