205 research outputs found
Study of N2O formation over Rh- and Pt-based LNT catalysts
In this paper, mechanistic aspects involved in the formation of N2O over Pt-BaO/Al2O3 and Rh-BaO/Al2O3 model NOx Storage-Reduction (NSR) catalysts are discussed. The reactivity of both gas-phase NO and stored nitrates was investigated by using H2 and NH3 as reductants. It was found that N2O formation involves the presence of gas-phase NO, since no N2O is observed upon the reduction of nitrates stored over both Pt- and Rh-BaO/Al2O3 catalyst samples. In particular, N2O formation involves the coupling of undissociated NO molecules with N-adspecies formed upon NO dissociation onto reduced Platinum-Group-Metal (PGM) sites. Accordingly, N2O formation is observed at low temperatures, when PGM sites start to be reduced, and disappears at high temperatures where PGM sites are fully reduced and complete NO dissociation takes place. Besides, N2O formation is observed at lower temperatures with H2 than with NH3 in view of the higher reactivity of hydrogen in the reduction of the PGM sites and onto Pt-containing catalyst due to the higher reducibility of Pt vs. Rh
On the deactivation of Fe2O3-MoO3/SiO2 catalysts in the oxidation of methanol to formaldehyde
none1Forzatti, PioForzatti, Pi
Temperature-programmed Desorption - Reaction of Ammonia Over V2o5/tio2 De-no(x)ing Catalysts
PREPARATION OF CLAY/CEMENT-BASED MANUFACTURED ARTICLES BY-MEANS OF EXTRUSION
PREPARATION OF CLAY/CEMENT-BASED MANUFACTURED ARTICLES BY-MEANS OF EXTRUSIO
Environmental catalysis - 1st World Conference Environmental Catalysis for a Better World and Life held in Pisa, Italy May 1-5, 1995 - Preface
Reaction-deactivation kinetics of methanol oxidation over a silica-supported Fe2O3-MoO3 catalyst
none2Forzatti, Pio; Buzzi Ferraris, G.Forzatti, Pio; G., Buzzi Ferrari
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