On the development of creep damage constitutive equations: modified hyperbolic sine law for minimum creep strain rate and stress and creep fracture criterion based on cavity area fraction along grain boundaries

Abstract: This paper reports 1) the latest development and application of modified hyperbolic sine law for minimum creep strain rate and stress for both low Cr and high Cr steels, and 2) the development of creep fracture criterion based on cavity area fraction along grain boundary for high Cr steel. This work is part of the fundamental development of creep damage constitutive equations which were identified through a critical literature review. In the former the application of the new law results in an improved fitting; in the latter, a new creep fracture criterion based on cavity area fraction along grain boundary was derived and quantitatively calibrated using the latest detailed cavity nucleation and growth kinetics models for high Cr steel. Furthermore, this paper revealed the trend of nucleation rate coefficient with stress, and the trend of creep life time coefficient with stress, which provide reliable and universal prediction capabilities. This paper contributes to the specific knowledge on the minimum creep strain rate and stress function, the development of a scientific sound and novel creep rupture criterion based on the cavity area fraction along grain boundary for high Cr steel, and the provision of creep damage/life prediction tools

Temperature and pressure behavior of the emission bands from Mn-, Cu-, and Eu-doped ZnS nanocrystals

The Mn-, Cu- and Eu-doped ZnS nanocrystals (NC) were analyzed for temeperature and pressure dependence of photoluminescence. The thermal quenching behavior of characteristic emission bands reflected nature of different transition mechanisms. The energies of Mn-orange and Eu-green emissions were observed to be weakly dependent on temperature. The results show strong interaction between excited state of Eu2+ ions and conduction band of ZnS which was responsible for positive pressure coefficient.published_or_final_versio

Heterogeneous activation of peroxymonosulfate by a biochar-supported Co3O4 composite for efficient degradation of chloramphenicols

Herein, a new peroxymonosulfate (PMS) activation system was established using a biochar (BC)-supported Co3O4 composite (Co3O4-BC) as a catalyst to enhance chloramphenicols degradation. The effects of the amount of Co3O4 load on the BC, Co3O4-BC amount, PMS dose and solution pH on the degradation of chloramphenicol (CAP) were investigated. The results showed that the BC support could well disperse Co3O4 particles. The degradation of CAP (30 mg/L) was enhanced in the Co3O4-BC/PMS system with the apparent degradation rate constant increased to 5.1, 19.4 and 7.2 times of that in the Co3O4/PMS, BC/PMS and PMS-alone control systems, respectively. Nearly complete removal of CAP was achieved in the Co3O4-BC/PMS system under the optimum conditions of 10 wt% Co3O4 loading on BC, 0.2 g/L. Co3O4-BC, 10 mM PMS and pH 7 within 10 min. The Co3O4/BC composites had a synergistic effect on the catalytic activity possibly because the conducting BC promoted electron transfer between the Co species and HSO5- and thus accelerated the Co3+/Co(2+)redox cycle. Additionally, over 85.0 +/- 1.5% of CAP was still removed in the 10th run. Although both SO4 center dot- and OH center dot were identified as the main active species, SO4 center dot- played a dominant role in CAP degradation. In addition, two other chloramphenicols, i.e., florfenicol (FF) and thiamphenicol (TAP), were also effectively degraded with percentages of 86.4 +/- 13% and 71.8 +/- 1.0%, respectively. This study provides a promising catalyst Co3O4-BC to activate PMS for efficient and persistent antibiotics degradation. (C) 2019 Elsevier Ltd. All rights reserved

Why some causative ‘give’ constructions develop beyond the passive to also form the unaccusative : evidence from Southern Min dialects

The conference was organized by Linguistic Society of Hong Kong.2011-2012 > Academic research: refereed > Refereed conference paperOther Versio

Wodegongjieite, ideally KCa3(Al7Si9)O-32, a new sheet silicate isostructural with the feldspar polymorph kokchetavite, KAlSi3O8

Wodegongjieite occurs in the Cr-11 chromitite orebody of the Luobusa ophiolite in the Kangjinla district, Tibet, China. It is found in two inclusions in corundum: (1) as a partial overgrowth (holotype) up to 1.5 mu m thick around a spheroid 20 mu m across of wenjiite (Ti-10(Si,P,square)(7)), kangjinlaite (Ti-11(Si,P)(10)), zhiqinite (TiSi2) and badengzhuite (TiP), and (2) as pools up to 0.25 mu m wide filling interstices between wenjiite, jingsuiite (TiB2), osbornite-khamrabaevite (Ti[N,C]) and corundum. Energy dispersive analyses gave Al2O3 34.09, SiO2 49.11, K2O 2.56, CaO 11.71, SrO 2.53, total 100.0 wt.%, corresponding to K0.58Sr0.26Ca2.25Al7.20Si8.80O31.20, ideally KCa3(Al7Si9)O-32, for Si + Al = 16 cations.Single-crystal studies were carried out with three-dimensional electron diffraction providing data for an ab initio structure solution in the hexagonal space group P6/mcc (#192) with a = 10.2(2) angstrom, c = 14.9(3) angstrom, V = 1340(50) angstrom(3) and Z = 2. Density (calc.) = 2.694 g.cm(-3). The refinement, which assumes complete Si-Al disorder, gives average T1-O and T2-O bond lengths both as 1.65 angstrom. It was not practical to use unconstrained refinement for the occupancies of the large cation sites 6f and 2a. The ab initio model shows clearly that the two cation sites have different sizes and coordination. Consequently, we imposed the condition (1) that all the K occupies the 2a site as the average K-O bond length of 3.07 angstrom is close to the average K-O bond lengths reported in kokchetavite and (2) that all the Ca occupies the 6f site as the average Ca-O bond length of 2.60 angstrom (2.36 angstrom and 2.84 angstrom for Ca-O1 and Ca-O3, respectively) is reasonable for Ca-O. Assuming that all K and all Ca are located at the 2a site and 6f site, respectively, Sr occupancies of these sites could be refined. Thermal parameters are positive and in a reasonable range. The structure is a sheet silicate isostructural with the K-feldspar polymorph kokchetavite, with two crystallographically distinct sites for K, but not with the topologically identical anorthite polymorph dmisteinbergite (CaAl2Si2O8) with only a single site for Ca. Substitution of K by Ca at the 6f site is associated with marked rotation of the Si,Al tetrahedra and a collapse of the structure to accommodate the smaller Ca ion.The spheroid of intermetallic phases is believed to have formed from the interaction of mantle-derived CH4 + H-2 fluids with basaltic magmas at depths of similar to 30-100 km, resulting in precipitation of corundum that entrapped intermetallic melts. Associated immiscible silicate melt of granodioritic composition crystallised metastably to wodegongjieite instead of a mixture of anorthite and K-feldspar

Experimental procedure for the characterization of turbocharger s waste-gate discharge coefficient

[EN] Nowadays, the turbocharger has become one of the key components for automotive spark-ignition engine improvements (fed with both liquid and gaseous fuels), as a support for the boosting and downsizing concept to reduce fuel consumption and exhaust emission. In gasoline engines, the usage of the waste-gate valve typically regulates the maximum boost pressure in the turbocharger system, to protect the engine and the turbocharger at high engine speeds. To improve the transient response at low engine speeds two-stage turbocharger is widely used. Two-stage systems are composed of several valves to regulate the flow to control the boosting of the system. Like, a by-pass valve between the turbines, a check valve between the compressor and a waste-gate valve for the low-pressure turbines. This paper deals with a methodology for characterizing the discharge coefficient of an electronic waste-gate valve in the turbocharger. To estimate the gas flow over the same in one-dimensional models, an empirical model is correlated and validated. For this, a constant stream experimental work has been carried out on a test rig at different valve position openings, with high turbine inlet temperatures. Finally, an optimal MAP of discharge coefficient has been drawn out through interpolation method, which can integrate into the full one-dimensional turbocharged engine model system, to calculate the actual mass flow through the waste-gate valve.The author(s) disclosed receipt of the following financial support for the research, authorship, and/or publication of this article: This work was partially funded by FEDER and Government of Spain through Project TRA2016-79185-R.Serrano, J.; Arnau Martínez, FJ.; Tiseira ., AO.; Samala, V. (2017). Experimental procedure for the characterization of turbocharger s waste-gate discharge coefficient. Advances in Mechanical Engineering. 9(10):1-9. https://doi.org/10.1177/1687814017728242S1991

Enumeration of distinct mechanically stable disk packings in small systems

We create mechanically stable (MS) packings of bidisperse disks using an algorithm in which we successively grow or shrink soft repulsive disks followed by energy minimization until the overlaps are vanishingly small. We focus on small systems because this enables us to enumerate nearly all distinct MS packings. We measure the probability to obtain a MS packing at packing fraction $\phi$ and find several notable results. First, the probability is highly nonuniform. When averaged over narrow packing fraction intervals, the most probable MS packing occurs at the highest $\phi$ and the probability decays exponentially with decreasing $\phi$. Even more striking, within each packing-fraction interval, the probability can vary by many orders of magnitude. By using two different packing-generation protocols, we show that these results are robust and the packing frequencies do not change qualitatively with different protocols.Comment: 4 pages, 3 figures, Conference Proceedings for X International Workshop on Disordered System

Folate cycle enzyme MTHFD1L confers metabolic advantages in hepatocellular carcinoma

published_or_final_versio

On the General Ericksen-Leslie System: Parodi's Relation, Well-posedness and Stability

In this paper we investigate the role of Parodi's relation in the well-posedness and stability of the general Ericksen-Leslie system modeling nematic liquid crystal flows. First, we give a formal physical derivation of the Ericksen-Leslie system through an appropriate energy variational approach under Parodi's relation, in which we can distinguish the conservative/dissipative parts of the induced elastic stress. Next, we prove global well-posedness and long-time behavior of the Ericksen-Leslie system under the assumption that the viscosity $\mu_4$ is sufficiently large. Finally, under Parodi's relation, we show the global well-posedness and Lyapunov stability for the Ericksen-Leslie system near local energy minimizers. The connection between Parodi's relation and linear stability of the Ericksen-Leslie system is also discussed