2,150 research outputs found
Bond Length - Bond Valence Relationships for Carbon - Carbon and Carbon - Oxygen Bonds
In the present study, relationships are developed for determining bond orders (also referred to as bond valences or bond numbers) from published bond lengths for carbon-carbon (C-C) and carbon-oxygen (C-O) bonds. The relationships are based on Paulingâs empirical formula s = exp((Ro-R)/b)), where s is the bond order, R is the corresponding bond length, Ro is the unit valence bond length, and b is a fitting parameter. We use a recently derived relationship for the b parameter in terms of the bonding atomsâ published atomic orbital exponents. The resulting equations were checked against published x-ray diffraction (XRD) data for 176 carbon systems with 540 published C-C bond lengths, and 50 oxygen systems having 72 published C-O bond lengths. The C-C and C-O bond length-valence relationships are shown to have sufficient applicability and accuracy for use in any bonding environment, regardless of physical state or oxidation number
Theoretical Justification for Bond Valence -- Bond Length Empirical Correlations
Bond valence â bond length empirical correlations are of great interest in chemistry, biology, geology and materials science because they offer a quick and convenient way of checking and evaluating molecular structures. Linus Paulingâs relationship is the most commonly used, but is a two-parameter fit where R0 and b must be optimized. In this study, a simplified quantum-mechanical approach was used to derive Paulingâs empirical bond valence â bond length relationship. A covalency factor was also introduced to account for the difference in âsoftnessâ between cation and anion (resulting in increased orbital overlap). An expression for the b parameter was determined that yields values that are in agreement with experimental data. The derived relationship for the b parameter allows an independent determination of b using orbital exponents and electronegativity values for the cation and anion
Titanium-Oxygen Bond Length -Bond Valence Relationship
A bond lengthâbond valence correlation is a simple method of checking and evaluating molecular structures and is of great interest in chemistry, biology, geology, and material science. Recently, we used quantum-mechanical arguments to derive Paulingâs bond length-valence relationship and to define the adjustable fitting parameter b in terms of atomic-orbital exponents. Improved orbital exponents were generated for elements 1-103 using published atomic radii and single-bond covalent radii as well as a continuous function for effective principal quantum number. In this study, we use orbital exponents for titanium (Ti) and oxygen (O) to generate a bond length-valence relationship for Ti-O bonds. Recent crystallographic Ti-O bond lengths from 32 environments were collected and converted to Ti-O bond valences to check the reliability of the bond length-valence relationship where Ro was found (bond length of unit valence). This relationship is expected to apply to any Ti-O bond regardless of environment, physical state, or oxidation number
Valence-Length Correlations for Chemical Bonds from Atomic Orbital Exponents
Paulingâs empirical bond valence-length correlation has proven valuable because it offers a quick and convenient way of checking and evaluating molecular structures and determining oxidation states from measured bond lengths. In this study, a simplified quantum-mechanical approach was used to derive Paulingâs empirical bond valence-length relationship by considering overlap of hydrogen-like orbitals. An expression for the b âempiricalâ fitting parameter was derived in terms of atomic-orbital exponents. A new set of orbital exponents is presented using published atomic/covalent radii and a continuous function for the effective principal quantum. The b parameters calculated from the orbital exponents are consistent with bond valence-length data from crystallographic data. In general, atomic-orbital exponents may be used to determine bond valence- length relationships for any chemical bond regardless of state, oxidation number, or environment
Raman Spectroscopy of Titania (TiO\u3csub\u3e2\u3c/sub\u3e) Nanotubular Water-Splitting Catalysts
The phase composition of nanotubular TiO2 films was correlated with photoelectrochemical activity as a function of O2-annealing temperature. TiO2 nanotubes have been shown to be more efficient than polycrystalline TiO2 for the photocatalytic splitting of water. Raman spectroscopy was used to identify and quantify the amorphous and crystalline TiO2 phases. The amorphous TiO2 nanotubular array was found to consist of TiO6 8- octahedra having the same average structure as those present in the anatase and rutile phases of TiO2. Results show that the anatase-to-rutile transformation on Ti metal initiates at much lower temperatures compared to polycrystalline TiO2 and this is attributed to oxygen vacancies located at the metal/oxide interface and is likely responsible for increasing the photocurrent density
Focusing on the extended X-ray emission in 3C 459 with a Chandra follow-up observation
6 pages, 4 figures. Reproduced with permission from Astronomy & Astrophysics. © 2019 ESO.Aims. We investigated the X-ray emission properties of the powerful radio galaxy 3C 459 revealed by a recent Chandra follow-up observation carried out in October 2014 with a 62 ks exposure. Methods. We performed an X-ray spectral analysis from a few selected regions on an image obtained from this observation and also compared the X-ray image with a 4.9 GHz VLA radio map available in the literature. Results. The dominant contribution comes from the radio core but significant X-ray emission is detected at larger angular separations from it, surrounding both radio jets and lobes. According to a scenario in which the extended X-ray emission is due to a plasma collisionally heated by jet-driven shocks and not magnetically dominated, we estimated its temperature to be âŒ0.8 keV. This hot gas cocoon could be responsible for the radio depolarization observed in 3C 459, as recently proposed also for 3C 171 and 3C 305. On the other hand, our spectral analysis and the presence of an oxygen K edge, blueshifted at 1.23 keV, cannot exclude the possibility that the X-ray radiation originating from the inner regions of the radio galaxy could be intercepted by some outflow of absorbing material intervening along the line of sight, as already found in some BAL quasars.Peer reviewe
A Chandra study of particle acceleration in the multiple hotspots of nearby radio galaxies
We present Chandra observations of a small sample of nearby classical double
radio galaxies which have more than one radio hotspot in at least one of their
lobes. The X-ray emission from the hotspots of these comparatively low-power
objects is expected to be synchrotron in origin, and therefore to provide
information about the locations of high-energy particle acceleration. In some
models of the relationship between the jet and hotspot the hotspots that are
not the current jet termination point should be detached from the energy supply
from the active nucleus and therefore not capable of accelerating particles to
high energies. We find that in fact some secondary hotspots are X-ray sources,
and thus probably locations for high-energy particle acceleration after the
initial jet termination shock. In detail, though, we show that the spatial
structures seen in X-ray are not consistent with naive expectations from a
simple shock model: the current locations of the acceleration of the
highest-energy observable particles in powerful radio galaxies need not be
coincident with the peaks of radio or even optical emission.Comment: Accepted for ApJ. 33 pages, 8 figures inc. 2 in colo
Extreme Ultraviolet Emission in the Fornax Cluster of Galaxies
We present studies of the Extreme Ultraviolet (EUV) emission in the Fornax
cluster of galaxies; a relatively nearby well-studied cluster with X-ray
emitting cluster gas and a very large radio source. We examine both the
large-scale (~size of the X-ray emitting cluster gas), and the small-scale
(<arcmin) emission.
We find that this cluster has large-scale diffuse EUV emission. However, at
the sensitivity level of the existing EUVE data, this emission is due entirely
to the low energy tail of the X-ray emitting gas. We have also examined
small-scale structures in raw EUVE images of this cluster. We find that
small-scale irregularities are present in all raw Deep Survey images as a
result of small-scale detector effects. These effects can be removed by
appropriate flat-fielding. After flat-fielding, the Fornax cluster still shows
a few significant regions of small-scale EUV enhancement. We find that these
are emission from stars and galaxies in the field. We find that at existing
levels of sensitivity, there is no excess EUV emission in the cluster on either
large or small scales.Comment: 6 pages, 3 eps figures, aastex5, Accepted to ApJ
A Bond Length â Bond Valence Relationship for Carbon â Nitrogen Bonds
In a recent study, Paulingâs relationship between bond length and valence was derived along with a definition for his fitting parameter b that incorporates the orbital exponents for each atom contributing to the bond of interest. The values of b for various bonds, including C-N bonds, were calculated using the orbital exponent data. In this study, Paulingâs correlation between bond length and bond valence, as well as his valence sum rule, were used with the recently-derived definition for b in order to produce a relationship specifically applicable to C-N bonds. The resulting equation was checked against published x-ray diffraction data for 430 C-N bonds. It is expected, and shown by the data presented in this study, that these equations relating the bond length and bond valence of C-N bonds have sufficient applicability and accuracy for use in any bonding environment, regardless of physical state or oxidation number
Bond Length and Bond Valence for Tungsten-Oxygen and Tungsten-Sulfur Bonds
In 1947, Linus Pauling presented an âempiricalâ dependence of bond valence (s, also referred to as bond order) and bond length R: s = exp[(R0-R)/b], where R0 is bond length of unit valence and âbâ is a fitting parameter. Recently, an expression was derived for relating the b fitting parameter to theoretically derived atomic orbital exponents. With a method to calculate b, both R0 and atomic orbital exponents can be experimentally determined through optimized fitting for W-O and W-S bonds. In the present study, bond length â valence relationships are found for W-O and W-S chemical bonds using published crystallographic data. The atomic orbital exponent for tungsten was found to be zW = 1.534. Unit valence (single bond) bond lengths were found to be Ro(W-O) = 1.901 Ă
and Ro(W-S) = 2.307 Ă
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