688 research outputs found

    Steady Combustion Waves Driven by a Recombination Reaction in a Gas Mixture

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    Is the solar neutrino deficit energy-dependent?

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    All existing measurements of the solar neutrino flux are compared with the predictions of the most recent solar model by Bahcall and Pinsonneault, modified by introducing the hypothesis of neutrino oscillations with mass differences large enough to render energy-independent any quantity observable on earth. It is concluded that the data are consistent with this hypothesis and that, at least for the time being, any energy-dependence of the solar neutrino deficit must be regarded as just an attractive theoretical possibility, but not as a compelling reality.Comment: 6 pages, 1 figure, contributed paper to the XVIII Int. Symposium on Lepton-Photon Interactions, Hamburgh, Germany, 28 July - 1 August 199

    Pfaffian representations of cubic surfaces

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    Let K be a field of characteristic zero. We describe an algorithm which requires a homogeneous polynomial F of degree three in K[x_0,x_1,x_2,x_3] and a zero A of F in P^3_K and ensures a linear pfaffian representation of V(F) with entries in K[x_0,x_1,x_2,x_3], under mild assumptions on F and A. We use this result to give an explicit construction of (and to prove the existence of) a linear pfaffian representation of V(F), with entries in K'[x_0,x_1,x_2,x_3], being K' an algebraic extension of K of degree at most six. An explicit example of such a construction is given.Comment: 17 pages. Expanded with some remarks. Published with minor corrections in Geom. Dedicat

    Equilibrium and stability properties of detonation waves in the hydrodynamic limit of a kinetic model

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    A shock wave structure problem, like the one which can be formulated for the planar detonation wave, is analyzed here for a binary mixture of ideal gases undergoing the symmetric reaction A1+A1=A2+A2 . The problem is studied at the hydrodynamic Euler limit of a kinetic model of the reactive Boltzmann equation. The chemical rate law is deduced in this frame with a second-order reaction rate, in a hemical regime such that the gas flow is not far away from the chemical equilibrium. The caloric and the thermal equations of state for the specific internal energy and temperature are employed to close the system of balance laws. With respect to other approaches known in the kinetic literature for detonation problems with a reversible reaction, this paper aims to improve some aspects of the wave solution. Within the mathematical analysis of the detonation model, the equation of the equilibrium Hugoniot curve of the final states is explicitly derived for the first time and used to define the correct location of the equilibrium Chapman–Jouguet point in the Hugoniot diagram. The parametric space is widened to investigate the response of the detonation solution to the activation energy of the chemical reaction. Finally, the mathematical formulation of the linear stability problem is given for the wave detonation structure via a normal-mode approach, when bidimensional disturbances perturb the steady solution. The stability equations with their boundary conditions and the radiation condition of the considered model are explicitly derived for small transversal deviations of the shock wave location. The paper shows how a second-order chemical kinetics description, derived at the microscopic level, and an analytic deduction of the equilibrium Hugoniot curve, lead to an accurate picture of the steady detonation with reversible reaction, as well as to a proper bidimensional linear stability analysis.Brazilian Research Council (CNPq), by Italian Research Council GNFM-INdAM, and by the Research Centre of Mathematics of the University of Minho with the Portuguese Funds of FCT, project PEstOE/MAT/UI0013/2014

    Hydrodynamic bidimensional stability of detonation wave solutions for reactive mixtures

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    The structure of a planar detonation wave is analyzed for an Eulerian mixture of ideal gases undergoing the symmetric reversible explosive reaction A1 + A1 = A2 + A2. The chemical rate law is derived from the reactive Boltzmann equation, showing a detailed chemical kinetics in terms of a second-order reaction rate. The hydrodynamic bidimensional stability of the detonation wave is also investigated using a normal mode approach, when small time-space transverse disturbances affect the shock wave location. A suitable numerical technique is here proposed in order to solve the stability problem and numerical results are provided illustrating the detonation wave structure and its instability spectrum.The paper is partially supported by Brazilian Research Council (CNPq), by Italian Research Council GNFM-INdAM, and by Portuguese Funds of FCT, CMAT project UID/MAT/00013/2013

    Lanthanide-Induced Photoluminescence in Lead-Free Cs2AgBiBr6Bulk Perovskite: Insights from Optical and Theoretical Investigations

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    Emphasis was recently placed on the Cs2AgBiBr6 double perovskite as a possible candidate to substitute toxic lead in metal halide perovskites. However, its poor light-emissive features currently make it unsuitable for solid-state lighting. Lanthanide doping is an established strategy to implement luminescence in poorly emissive materials, with the additional advantage of fine-tuning the emission wavelength. We discuss here the impact of Eu and Yb doping on the optical properties of Cs2AgBiBr6 thin films, obtained from the solution processing of hydrothermally synthesized bulk crystalline powders, by combining experiments and density functional theory calculations. Eu(III) incorporation does not lead to the characteristic 5D0 → 7F2 emission feature at 2 eV, while only a weak trap-assisted sub-band gap radiative emission is reported. Oppositely, we demonstrate that incorporated Yb(III) leads to an intense and exclusive photoluminescence emission in the near-infrared as a result of the efficient sensitization of the lanthanide 2F5/2 → 2F7/2 transition

    Lanthanide Induced Photoluminescence in Lead-Free Cs₂AgBiBr₆ Bulk Perovskite: Insights From Optical and Theoretical Investigations

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    The search for materials substituting toxic lead in metal halide perovskites has recently placed emphasis on the Cs2AgBiBr6 double perovskite as a possible candidate. The poor light-emissive features of this species, mainly associated to the indirect nature of the band gap and the strongly bound exciton, however, currently make it unsuitable for solid-state lighting applications. Doping with lanthanides is an established strategy to implement luminescence in poorly emissive materials, with the additional advantage of tuning the wavelength of emission independently from the host band structure. We discuss here the impact of Eu- and Yb-doping on the absorption and emission properties of Cs2AgBiBr6 polycrystalline thin films, obtained from solution-processing of hydrothermally synthesized bulk crystalline powders, by combining experiments and density functional theory calculations. Eu(III) incorporation does not lead to the characteristic 5D0→7F2 emission feature at 2 eV, while only a weak sub band-gap radiative emission ascribed to a trap-assisted recombination process is reported. On the other hand, we demonstrate that Yb(III) incorporated in the bulk double perovskite leads to an intense and exclusive photoluminescence emission in the near-infrared (NIR) from thin films, as a result of the efficient sensitization of the lanthanide centered 2F5/2→2F7/2 transition, with favorable mid-gap energetic position. Yb-doping may be thus exploited for the future development of stable and sustainable perovskite NIR-light emitters

    A complete solution to neutrino mixing

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    Deviations from expectations have been claimed for solar, atmospheric and high energy prompt neutrinos from charm decay. This information, supplemented only by the existing very good upper limits for oscillations of the νμ\nu_{\mu} at accelerator energies, is used as input to a phenomenological three-flavour analysis of neutrino mixing. The solution found is unique and completely determines the mass eigenstates as well as the mixing matrix relating mass and flavour eigenstates. Assuming the mass eigenstates to follow the hierarchy m1m2m3m_{1} \ll m_{2} \ll m_{3}, their values are found to be m1102m_{1} \ll 10^{-2} eV, m2=(0.18±0.06)m_{2} = (0.18 \pm 0.06) eV, m3=(19.4±0.7)m_{3} = (19.4 \pm 0.7) eV. These masses are in agreement with the leptonic quadratic hierarchy of the see-saw model and large enough to render energy-independent any oscillation-induced phenomenon in solar neutrino physics observable on Earth. This possibility is not excluded by the present knowledge of solar neutrino physics. The mixing angles are determined to be θ12=0.55±0.08\theta_{12} = 0.55 \pm 0.08, θ13=0.38±0.06\theta_{13} = 0.38 \pm 0.06, θ23<0.03\theta_{23} < 0.03. Small values of θ23\theta_{23} are typical of any solution in which m3m_{3} lies in the cosmological interesting region. The solution found is not in serious contradiction with any of the present limits to the existence of neutrino oscillations. The most relevant implications in particle physics, astrophysics and cosmology are discussed.Comment: 17 pages, 3 figures, to be published in Astroparticle Physic

    Testing the performance of a blind burst statistic

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    In this work we estimate the performance of a method for the detection of burst events in the data produced by interferometric gravitational wave detectors. We compute the receiver operating characteristics in the specific case of a simulated noise having the spectral density expected for Virgo, using test signals taken from a library of possible waveforms emitted during the collapse of the core of Type II Supernovae.Comment: 8 pages, 6 figures, Talk given at the GWDAW2002 worksho
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