Molecular Dynamics in grafted layers of poly(dimethylsiloxane) (PDMS)

Dielectric relaxation spectroscopy 10^-1 Hz to 10^6 Hz) is employed to study the molecular dynamics of poly(dimethylsiloxane) (PDMS, Mw=1.7 10^5 g/mol and Mw=9.6 10^4 g/mol as grafted films with thicknesses d below and above the radius of gyration Rg. For d smaller than Rg the molecular dynamics becomes faster by up to three orders of magnitude with respect to the bulk resulting in a pronounced decrease of the Vogel temperature T0 and hence the calorimetric glass transition temperature Tg. For d larger than Rg the molecular dynamics is comparable to that of the bulk melt. The results are interpreted in terms of a chain confinement effect and compared with the findings for low molecular eight glass forming liquids contained in nanoporous glasses and zeolites. Crystallization effects - well known for PDMS - are observed for films of thicknesses above and below Rg.Comment: 20 pages, 4 figure

Normal origamis of Mumford curves

An origami (also known as square-tiled surface) is a Riemann surface covering a torus with at most one branch point. Lifting two generators of the fundamental group of the punctured torus decomposes the surface into finitely many unit squares. By varying the complex structure of the torus one obtains easily accessible examples of Teichm\"uller curves in the moduli space of Riemann surfaces. The p-adic analogues of Riemann surfaces are Mumford curves. A p-adic origami is defined as a covering of Mumford curves with at most one branch point, where the bottom curve has genus one. A classification of all normal non-trivial p-adic origamis is presented and used to calculate some invariants. These can be used to describe p-adic origamis in terms of glueing squares.Comment: 21 pages, to appear in manuscripta mathematica (Springer

Adaptive Resolution Molecular Dynamics Simulation: Changing the Degrees of Freedom on the Fly

We present a new adaptive resolution technique for efficient particle-based multiscale molecular dynamics (MD) simulations. The presented approach is tailor-made for molecular systems where atomistic resolution is required only in spatially localized domains whereas a lower mesoscopic level of detail is sufficient for the rest of the system. Our method allows an on-the-fly interchange between a given molecule's atomic and coarse-grained level of description, enabling us to reach large length and time scales while spatially retaining atomistic details of the system. The new approach is tested on a model system of a liquid of tetrahedral molecules. The simulation box is divided into two regions: one containing only atomistically resolved tetrahedral molecules, the other containing only one particle coarse-grained spherical molecules. The molecules can freely move between the two regions while changing their level of resolution accordingly. The coarse-grained and the atomistically resolved systems have the same statistical properties at the same physical conditions.Comment: 17 pages, 11 figures, 5 table

Accelerated expansion in bosonic and fermionic 2D cosmologies with quantum effects

In this work we analyze the effects produced by bosonic and fermionic constituents, including quantum corrections, in two-dimensional (2D) cosmological models. We focus on a gravitational theory related to the Callan-Giddings-Harvey-Strominger model, to simulate the dynamics of a young, spatially-lineal, universe. The cosmic substratum is formed by an {\it inflaton} field plus a matter component, sources of the 2D gravitational field; the degrees of freedom also include the presence of a dilaton field. We show that this combination permits, among other scenarios, the simulation of a period of inflation, that would be followed by a (bosonic/fermionic) matter dominated era. We also analyse how quantum effects contribute to the destiny of the expansion, given the fact that in 2D we have a consistent (renormalizable) quantum theory of gravity. The dynamical behavior of the system follows from the solution of the gravitational field equations, the (Klein-Gordon and Dirac) equations for the sources and the dilaton field equation. Consistent (accelerated) regimes are present among the solutions of the 2D equations; the results depend strongly on the initial conditions used for the dilaton field. In the particular case where fermions are included as matter fields a transition to a decelerated expansion is possible, something that does not happen in the exclusively bosonic case.Comment: 6 pages, 5 figures, to appear in EP

Specific Heat of the Ca-Intercalated Graphite Superconductor CaC6_6

The superconducting state of Ca-intercalated graphite CaC6 has been investigated by specific heat measurements. The characteristic anomaly at the superconducting transition (Tc = 11.4 K) indicates clearly the bulk nature of the superconductivity. The temperature and magnetic field dependence of the electronic specific heat are consistent with a fully-gapped superconducting order parameter. The estimated electron-phonon coupling constant is lambda = 0.60 - 0.74 suggesting that the relatively high Tc of CaC6 can be explained within the weak-coupling BCS approach.Comment: 4 pages, 4 figs, submitted to Phys. Rev. Let