Kinetic modelling of epitaxial film growth with up- and downward step barriers

The formation of three-dimensional structures during the epitaxial growth of films is associated to the reflection of diffusing particles in descending terraces due to the presence of the so-called Ehrlich-Schwoebel (ES) barrier. We generalize this concept in a solid-on-solid growth model, in which a barrier dependent on the particle coordination (number of lateral bonds) exists whenever the particle performs an interlayer diffusion. The rules do not distinguish explicitly if the particle is executing a descending or an ascending interlayer diffusion. We show that the usual model, with a step barrier in descending steps, produces spurious, columnar, and highly unstable morphologies if the growth temperature is varied in a usual range of mound formation experiments. Our model generates well-behaved mounded morphologies for the same ES barriers that produce anomalous morphologies in the standard model. Moreover, mounds are also obtained when the step barrier has an equal value for all particles independently if they are free or bonded. Kinetic roughening is observed at long times, when the surface roughness w and the characteristic length $\xi$ scale as $w ~ t^\beta$ and $\xi ~ t^\zeta$ where $\beta \approx 0.31$ and $\zeta \approx 0.22$, independently of the growth temperature.Comment: 15 pages, 7 figure

Faceted anomalous scaling in the epitaxial growth of semiconductor films

We apply the generic dynamical scaling theory (GDST) to the surfaces of CdTe polycrystalline films grown in glass substrates. The analysed data were obtained with a stylus profiler with an estimated resolution lateral resolution of $l_c=0.3 \mu$m. Both real two-point correlation function and power spectrum analyses were done. We found that the GDST applied to the surface power spectra foresees faceted morphology in contrast with the self-affine surface indicated by the local roughness exponent found via the height-height correlation function. This inconsistency is explained in terms of convolution effects resulting from the finite size of the probe tip used to scan the surfaces. High resolution AFM images corroborates the predictions of GDST.Comment: to appear in Europhysics Letter

Three Essays on Network Dynamics and Liminality

This dissertation focuses on the emergence and evolution of social networks by paying particular attention to the spanning of cultural boundaries that segregate actors in the context of specific societies. In particular, I use systems science methods to study the bridging of cultural holes in small and relatively dense artificial societies, as well as in an American high school. I also study the significance of local triadic configurations in giving rise to the highly hierarchical system of aggregate-level migration flows in place in the Americas during the late 20th century. I use the concept of liminality as a way to analyze these disparate social systems. More precisely, I focus on the role of cultural brokers seen as actors at the limen – i.e. at the border – of symbolic boundaries, actors that can act as bridges between culturally disconnected worlds. In this context, this dissertation explains key network dynamics behind two emergent phenomena that are the direct result of liminal agents’ behaviors: the diffusion of innovations (Chapters 1 and 2) and a system of international migration flows (Chapter 3). Finally, I also put forward a critical view on brokerage based on different cases mentioned in the literature (e.g. 1.5 generation migrants or multiracial individuals) that show how the spanning of cultural holes can put brokers at an increased risk of being socially and/or psychologically harmed

Modelling of epitaxial film growth with a Ehrlich-Schwoebel barrier dependent on the step height

The formation of mounded surfaces in epitaxial growth is attributed to the presence of barriers against interlayer diffusion in the terrace edges, known as Ehrlich-Schwoebel (ES) barriers. We investigate a model for epitaxial growth using a ES barrier explicitly dependent on the step height. Our model has an intrinsic topological step barrier even in the absence of an explicit ES barrier. We show that mounded morphologies can be obtained even for a small barrier while a self-affine growth, consistent with the Villain-Lai-Das Sarma equation, is observed in absence of an explicit step barrier. The mounded surfaces are described by a super-roughness dynamical scaling characterized by locally smooth (faceted) surfaces and a global roughness exponent $\alpha>1$. The thin film limit is featured by surfaces with self-assembled three-dimensional structures having an aspect ratio (height/width) that may increase or decrease with temperature depending on the strength of step barrier.Comment: To appear in J. Phys. Cond. Matter; 3 movies as supplementary materia

Treatment of bimodality in proficiency test of pH in bioethanol matrix

The pH value in bioethanol is a quality control parameter related to its acidity and to the corrosiveness of vehicle engines when it is used as fuel. In order to verify the comparability and reliability of the measurement of pH in bioethanol matrix among some experienced chemical laboratories, reference material (RM) of bioethanol developed by Inmetro - the Brazilian National Metrology Institute - was used in a proficiency testing (PT) scheme. There was a difference of more than one unit in the value of the pH measured due to the type of internal filling electrolytic solutions (potassium chloride, KCl or lithium chloride, LiCl) from the commercial pH combination electrodes used by the participant laboratories. Therefore, bimodal distribution has occurred from the data of this PT scheme. This work aims to present the possibilities that a PT scheme provider can use to overcome the bimodality problem. Data from the PT of pH in bioethanol were treated by two different statistical approaches: kernel density model and the mixture of distributions. Application of these statistical treatments improved the initial diagnoses of PT provider, by solving bimodality problem and contributing for a better performance evaluation in measuring pH of bioethanol.Comment: 20 pages, 6 figures, Accepted for publication in Accreditation and Quality Assurance (ACQUAL