445 research outputs found
Towards electron transport measurements in chemically modified graphene: The effect of a solvent
Chemical functionalization of graphene modifies the local electron density of
the carbon atoms and hence electron transport. Measuring these changes allows
for a closer understanding of the chemical interaction and the influence of
functionalization on the graphene lattice. However, not only chemistry, in this
case diazonium chemistry, has an effect on the electron transport. Latter is
also influenced by defects and dopants resulting from different processing
steps. Here, we show that solvents used in the chemical reaction process change
the transport properties. In more detail, the investigated combination of
isopropanol and heating treatment reduces the doping concentration and
significantly increases the mobility of graphene. Furthermore, the isopropanol
treatment alone increases the concentration of dopants and introduces an
asymmetry between electron and hole transport which might be difficult to
distinguish from the effect of functionalization. The results shown in this
work demand a closer look on the influence of solvents used for chemical
modification in order to understand their influence
Charge Detection in Graphene Quantum Dots
We report measurements on a graphene quantum dot with an integrated graphene
charge detector. The quantum dot device consists of a graphene island (diameter
approx. 200 nm) connected to source and drain contacts via two narrow graphene
constrictions. From Coulomb diamond measurements a charging energy of 4.3 meV
is extracted. The charge detector is based on a 45 nm wide graphene nanoribbon
placed approx. 60 nm from the island. We show that resonances in the nanoribbon
can be used to detect individual charging events on the quantum dot. The
charging induced potential change on the quantum dot causes a step-like change
of the current in the charge detector. The relative change of the current
ranges from 10% up to 60% for detecting individual charging events.Comment: 4 pages, 3 figure
Transport in a three-terminal graphene quantum dot in the multi-level regime
We investigate transport in a three-terminal graphene quantum dot. All nine
elements of the conductance matrix have been independently measured. In the
Coulomb blockade regime accurate measurements of individual conductance
resonances reveal slightly different resonance energies depending on which pair
of leads is used for probing. Rapid changes in the tunneling coupling between
the leads and the dot due to localized states in the constrictions has been
excluded by tuning the difference in resonance energies using in-plane gates
which couple preferentially to individual constrictions. The interpretation of
the different resonance energies is then based on the presence of a number of
levels in the dot with an energy spacing of the order of the measurement
temperature. In this multi-level transport regime the three-terminal device
offers the opportunity to sense if the individual levels couple with different
strengths to the different leads. This in turn gives qualitative insight into
the spatial profile of the corresponding quantum dot wave functions.Comment: 12 pages, 6 figure
Spatially Resolved Raman Spectroscopy of Single- and Few-Layer Graphene
We present Raman spectroscopy measurements on single- and few-layer graphene
flakes. Using a scanning confocal approach we collect spectral data with
spatial resolution, which allows us to directly compare Raman images with
scanning force micrographs. Single-layer graphene can be distinguished from
double- and few-layer by the width of the D' line: the single peak for
single-layer graphene splits into different peaks for the double-layer. These
findings are explained using the double-resonant Raman model based on ab-initio
calculations of the electronic structure and of the phonon dispersion. We
investigate the D line intensity and find no defects within the flake. A finite
D line response originating from the edges can be attributed either to defects
or to the breakdown of translational symmetry
Quantum capacitance and density of states of graphene
We report on measurements of the quantum capacitance in graphene as a
function of charge carrier density. A resonant LC-circuit giving high
sensitivity to small capacitance changes is employed. The density of states,
which is directly proportional to the quantum capacitance, is found to be
significantly larger than zero at and around the charge neutrality point. This
finding is interpreted to be a result of potential fluctuations with amplitudes
of the order of 100 meV in good agreement with scanning single-electron
transistor measurements on bulk graphene and transport studies on nanoribbons
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