72 research outputs found
In-plane orientation effects on the electronic structure, stability and Raman scattering of monolayer graphene on Ir(111)
We employ angle-resolved photoemission spectroscopy (ARPES) to investigate
the electronic structures of two rotational variants of epitaxial, single-layer
graphene on Ir(111). As grown, the more-abundant R0 variant is nearly
charge-neutral, with strong hybridization between graphene and Ir bands near
the Fermi level. The graphene Fermi surface and its replicas exactly coincide
with Van Hove singularities in the Ir Fermi surface. Sublattice symmetry
breaking introduces a small gap-inducing potential at the Dirac crossing, which
is revealed by n-doping the graphene using K atoms. The energy gaps between
main and replica bands (originating from the moir\'e interference pattern
between graphene and Ir lattices) is shown to be non-uniform along the mini-
zone boundary due to hybridization with Ir bands. An electronically mediated
interaction is proposed to account for the stability of the R0 variant. The
variant rotated 30{\deg} in-plane, R30, is p-doped as grown and K doping
reveals no band gap at the Dirac crossing. No replica bands are found in ARPES
measurements. Raman spectra from the R30 variant exhibit the characteristic
phonon modes of graphene, while R0 spectra are featureless. These results show
that the film/substrate interaction changes from chemisorption (R0) to
physisorption (R30) with in-plane orientation. Finally, graphene-covered Ir has
a work function lower than the clean substrate but higher than graphite.Comment: Manuscript plus 7 figure
Three-Fold Diffraction Symmetry in Epitaxial Graphene and the SiC Substrate
The crystallographic symmetries and spatial distribution of stacking domains
in graphene films on SiC have been studied by low energy electron diffraction
(LEED) and dark field imaging in a low energy electron microscope (LEEM). We
find that the graphene diffraction spots from 2 and 3 atomic layers of graphene
have 3-fold symmetry consistent with AB (Bernal) stacking of the layers. On the
contrary, graphene diffraction spots from the buffer layer and monolayer
graphene have apparent 6-fold symmetry, although the 3-fold nature of the
satellite spots indicates a more complex periodicity in the graphene sheets.Comment: An addendum has been added for the arXiv version only, including one
figure with five panels. Published paper can be found at
http://link.aps.org/doi/10.1103/PhysRevB.80.24140
Determining the structure of Ru(0001) from low-energy electron diffraction of a single terrace
While a perfect hcp (0001) surface has three-fold symmetry, the diffraction
patterns commonly obtained are six-fold symmetric. This apparent change in
symmetry occurs because on a stepped surface, the atomic layers on adjacent
terraces are rotated by 180 degrees. Here we use a Low-Energy Electron
Microscope to acquire the three-fold diffraction pattern from a single hcp Ru
terrace and measure the intensity-vs-energy curves for several diffracted
beams. By means of multiple scattering calculations fitted to the experimental
data with a Pendry R-factor of 0.077, we find that the surface is contracted by
3.5(+-0.9) at 456 K.Comment: 10 pages, 4 figures. Corrected some typos, added more details.
Accepted for publication in Surface Science (Letters
Labyrinthine Island Growth during Pd/Ru(0001) Heteroepitaxy
Using low energy electron microscopy we observe that Pd deposited on Ru only
attaches to small sections of the atomic step edges surrounding Pd islands.
This causes a novel epitaxial growth mode in which islands advance in a
snakelike motion, giving rise to labyrinthine patterns. Based on density
functional theory together with scanning tunneling microscopy and low energy
electron microscopy we propose that this growth mode is caused by a surface
alloy forming around growing islands. This alloy gradually reduces step
attachment rates, resulting in an instability that favors adatom attachment at
fast advancing step sections
Highly Enhanced Concentration and Stability of Reactive Ce^3+ on Doped CeO_2 Surface Revealed In Operando
Trivalent cerium ions in CeO_2 are the key active species in a wide range of catalytic and electro-catalytic reactions. We employed ambient pressure X-ray photoelectron spectroscopy and electrochemical impedance spectroscopy to quantify simultaneously the concentration of the reactive Ce^3+ species on the surface and in the bulk of Sm-doped CeO_2(100) in hundreds of millitorr of H2–H2O gas mixtures. Under relatively oxidizing conditions, when the bulk cerium is almost entirely in the 4+ oxidation state, the surface concentration of the reduced Ce^3+ species can be over 180 times the bulk concentration. Furthermore, in stark contrast to the bulk, the surface’s 3+ oxidation state is also highly stable, with concentration almost independent of temperature and oxygen partial pressure. Our thermodynamic measurements reveal that the difference between the bulk and surface partial molar entropies plays a key role in this stabilization. The high concentration and stability of reactive surface Ce^3+ over wide ranges of temperature and oxygen partial pressure may be responsible for the high activity of doped ceria in many pollution-control and energy-conversion reactions, under conditions at which Ce^3+ is not abundant in the bulk
A high-efficiency spin-resolved phototemission spectrometer combining time-of-flight spectroscopy with exchange-scattering polarimetry
We describe a spin-resolved electron spectrometer capable of uniquely
efficient and high energy resolution measurements. Spin analysis is obtained
through polarimetry based on low-energy exchange scattering from a
ferromagnetic thin-film target. This approach can achieve a similar analyzing
power (Sherman function) as state-of-the-art Mott scattering polarimeters, but
with as much as 100 times improved efficiency due to increased reflectivity.
Performance is further enhanced by integrating the polarimeter into a
time-of-flight (TOF) based energy analysis scheme with a precise and flexible
electrostatic lens system. The parallel acquisition of a range of electron
kinetic energies afforded by the TOF approach results in an order of magnitude
(or more) increase in efficiency compared to hemispherical analyzers. The lens
system additionally features a 90{\deg} bandpass filter, which by removing
unwanted parts of the photoelectron distribution allows the TOF technique to be
performed at low electron drift energy and high energy resolution within a wide
range of experimental parameters. The spectrometer is ideally suited for
high-resolution spin- and angle-resolved photoemission spectroscopy
(spin-ARPES), and initial results are shown. The TOF approach makes the
spectrometer especially ideal for time-resolved spin-ARPES experiments.Comment: 16 pages, 11 figure
Imaging Spin Reorientation Transitions in Consecutive Atomic Co layers
By means of spin-polarized low-energy electron microscopy (SPLEEM) we show
that the magnetic easy-axis of one to three atomic-layer thick cobalt films on
ruthenium crystals changes its orientation twice during deposition:
one-monolayer and three-monolayer thick films are magnetized in-plane, while
two-monolayer films are magnetized out-of-plane, with a Curie temperature well
above room temperature. Fully-relativistic calculations based on the Screened
Korringa-Kohn-Rostoker (SKKR) method demonstrate that only for two-monolayer
cobalt films the interplay between strain, surface and interface effects leads
to perpendicular magnetization.Comment: 5 pages, 4 figures. Presented at the 2005 ECOSS conference in Berlin,
and at the 2005 Fall meeting of the MRS. Accepted for publication at Phys.
Rev. Lett., after minor change
Self-doping effects in epitaxially grown graphene
Self-doping in graphene has been studied by examining single-layer
epitaxially grown graphene samples with differing characteristic lateral
terrace widths. Low energy electron microscopy was used to gain real-space
information about the graphene surface morphology, which was compared with data
obtained by angle-resolved photoemission spectroscopy to study the effect of
the monolayer graphene terrace width on the low energy dispersions. By altering
the graphene terrace width, we report significant changes in the electronic
structure and quasiparticle relaxation time of the material, in addition to a
terrace width-dependent doping effect.Comment: Published in Applied Physics Letters 93, 243119 (2008
Structure and magnetism in ultrathin iron oxides characterized by low energy electron microscopy
We have grown epitaxial films a few atomic layers thick of iron oxides on
ruthenium. We characterize the growth by low energy electron microscopy. Using
selected area diffraction and intensity vs. voltage spectroscopy, we detect two
distinct phases which are assigned to wustite and magnetite. Spin polarized low
energy electron microscopy shows magnetic domain patterns in the magnetite
phase at room temperature.Comment: 21 pages, 10 figures, for J. Phys Cond Matt special LEEM/PEEM issue
in honor of E. Baue
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