Velocity map imaging of the dynamics of the CH3 + HCl -> CH4 + Cl reaction using a dual molecular beam method

International audienceThe reactions CH3 + HCl → CH4 + Cl(²P_3/2) and CD₃ + HCl → CD₃H + Cl(²P_3/2) have been studied by photo-initiation (by CH₃I or CD₃I photolysis at 266 nm) in a dual molecular beam apparatus. Product Cl(²P</sub>3/2</sub>) atoms were detected using resonance enhanced multi-photon ionisation and velocity map imaging, revealing product translational energy and angular scattering distributions in the centre-of-mass frame. Image analysis is complicated by the bimodal speed distribution of CH₃ (and CD₃) radicals formed in coincidence with I(²P_3/2) and I(²P_1/2) atoms from CH₃I (CD₃I) photodissociation, giving overlapping Newton diagrams with displaced centre of mass velocities. The relative reactivities to form Cl atoms are greater for the slower CH₃ speed group than the faster group by factors of ~1.5 for the reaction of CH₃ and ~2.5 for the reaction of CD₃, consistent with the greater propensity of the faster methyl radicals to undergo electronically adiabatic reactions to form Cl(²P_1/2). The average fraction of the available energy becoming product translational energy is = 0.48 ± 0.05 and 0.50 ± 0.03 for reaction of the faster and slower sets of CH₃ radicals, respectively. The Cl atoms are deduced to be preferentially forward scattered with respect to the HCl reagents, but the angular distributions from the dual beam imaging experiments require correction for under-detection of forward scattered Cl products

Some measurements of the directional wave spectrum

A sequence of ten records of the directional wave spectrum has been obtained from the motions of a floating buoy located at 56° 45\u27N, 18° 57\u27W. The records were taken to check the results derived from a numerical scheme for forecasting ocean waves in the North Atlantic...

Brayton-cycle radioisotope heat-source design study. Phase II /preliminary design/ report

Brayton cycle radioisotope heat source desig

Bio-economic evaluation of pasture-cropping, a novel system of integrating perennial pastures and crops on crop-livestock farms

Pasture-cropping is a novel approach to increase the area of perennial crops in mixed sheep and cropping systems. It involves planting annual cereals directly into a living perennial pasture. There is interest in subtropical grasses as they are winter dormant and their growth profile is potentially well suited to pasture-cropping. However, a wide range of factors can affect the uptake of such systems. This paper assesses the relative importance of factors that can influence decisions to introduce pasture-cropping. In this paper the research question is: what factors predispose a farm to take up a new technology such as (1) subtropical grass and (2) subtropical grass that is pasture-cropped. The analysis uses the MIDAS model of a central wheatbelt farm in Western Australia. The results suggest the adoption of subtropical grasses is likely to be strongly influenced by soil mix; feed quality; and whether the farm is predominantly grazing or cropping and by the presence of meat versus wool producing animals. The same factors are relevant for subtropical grass that is pasture-cropped but in addition yield penalties due to competition between the host perennial and the companion cereal become important. The results suggest the level of forage production by subtropical grass is less important but this factor is likely to become more important if feed quality can be improved.Environmental Economics and Policy,