10,250 research outputs found
Defect chemistry and transport properties of BaxCe0.85M0.15O3-d
The site-incorporation mechanism of M3+ dopants into A2+B4+O3 perovskites controls the overall defect chemistry and thus their transport properties. For charge-balance reasons, incorporation onto the A2+-site would require the creation of negatively charged point defects (such as cation vacancies), whereas incorporation onto the B4+-site is accompanied by the generation of positively charged defects, typically oxygen vacancies. Oxygen-vacancy content, in turn, is relevant to proton-conducting oxides in which protons are introduced via the dissolution of hydroxyl ions at vacant oxygen sites. We propose here, on the basis of x-ray powder diffraction studies, electron microscopy, chemical analysis, thermal gravimetric analysis, and alternating current impedance spectroscopy, that nominally B-site doped barium cerate can exhibit dopant partitioning as a consequence of barium evaporation at elevated temperatures. Such partitioning and the presence of significant dopant concentrations on the A-site negatively impact proton conductivity. Specific materials examined are BaxCe0.85M0.15O3-d (x = 0.85 - 1.20; M = Nd, Gd, Yb). The compositional limits for the maximum A-site incorporation are experimentally determined to be: (Ba0.919Nd0.081)(Ce0.919Nd0.081)O3, (Ba0.974Gd0.026)(Ce0.872Gd0.128)O2.875, and Ba(Ce0.85Yb0.15)O2.925. As a consequence of the greater ability of larger cations to exist on the Ba site, the H2O adsorption and proton conductivities of large-cation doped barium cerates are lower than those of small-cation doped analogs
Unveiling interactions between DNA and cytotoxic 2-arylpiperidinyl-1,4-naphthoquinone derivatives: A combined electrochemical and computational study
Indexación: Scopus.Three 2-arylpiperidinyl-1,4-naphthoquinone derivatives were synthesized and evaluated in vitro to determine their cytotoxicity on cancer and normal cell lines. In order to establish their possible action mechanism, the electrochemical behaviour of these quinones was examined using cyclic voltammetry (CV) as technique by using a three-electrode setup: a glassy carbon, Ag/AgCl (in 3 M KCl), and platinum wire as working, reference, and counter electrodes, respectively. Kinetic studies were done to determine the control of the reduction reaction and the number of transferred electrons in the process. Furthermore, the addition of dsDNA to the quinone solutions allowed for the observation of an interaction between each quinone and dsDNA as the current-peaks became lower in presence of dsDNA. Otherwise, motivated to support the aforementioned results, electronic structure calculations at the TPSS-D3/6-31+G(d,p) level of theory were carried out in order to find the most favourable noncovalently bonded complexes between quinones and DNA. Noncovalent complexes formed between DNA and 2-arylpiperidinyl-1,4-naphthoquinones and stabilized by π-stacking interactions along with the well-known hydrogen-bonded complexes were found, with the former being more stable than the latter. These results suggest that the intercalation of these quinone derivatives in DNA is the most likely action mechanism. © 2018 King Saud Universityhttps://www.sciencedirect.com/science/article/pii/S1878535218300893?via%3Dihu
Unraveling public good games
This paper provides experimental evidence on how players predict end-game effects in a linear public good game. Our regression analysis yields a measure of the relative importance of priors and signals on subjects’ beliefs on contributions and allows us to conclude that, first, the weight of the signal is relatively unimportant, while priors have a large weight and, second, priors are the same for all periods. Hence, subjects do not expect end-game effects and there is very little updating of beliefs. We argue that the sustainability of cooperation is related to this pattern of belief formation
Homoerotic Medievalism: Looking at Queer Desire in the Homosocial Relationships of Chaucer’s “The Knight’s Tale” and Fletcher and Shakespeare’s The Two Noble Kinsmen
The purpose of this thesis is to explore queer interiority within the heteronormative social constructions of late medieval England. Queer interiority is not an occurrence of modernity, but rather a response to social constructions that date back to the Middle Ages. It is essential to account for queerness in the Middle Ages because authors like Chaucer promote the successive resurfacing of queer characters within heteronormative social constructions. Writing during the queer reign of Richard II, Chaucer constructs the interior identities of Palamon and Arcite as a reflection of the king and the political norms of England. Inspired by Chaucer, authors in the early modern period, such as Fletcher and Shakespeare, explore the queer propositions of Chaucer and reimagine his stories by extending the characters’ queer potential. This phenomenon is known as medievalism, which encompasses the transformations and retellings of medieval cultural productions in post-medieval periods.
Queerness in medieval and early modern literature occurs through desire, nominally, same-sex relationships; it exists in the mimicked normative relationship constructions of same-sex characters. To access queer desire, Lacanian psychoanalysis explains the signification of language in romantic discourse. His theories do not apply solely to heterosexual relationships, but also the “inversions” (as Freud would name it) that exist when two characters of the same sex desire one another. Through close readings of Geoffrey Chaucer\u27s “The Knight\u27s Tale” and John Fletcher and William Shakespeare\u27s The Two Noble Kinsmen, as well as historical, psychoanalytic, theoretical, and analytical texts, this paper will account for queerness in medievalism
The Cost of Sharing and the Common Law: How to Address the Negative Externalities of Home-Sharing
On the Naturalness of Higgs Inflation
We critically examine the recent claim that the Standard Model Higgs boson
could drive inflation in agreement with observations if has a strong coupling to the Ricci curvature scalar. We
first show that the effective theory approach upon which that claim is based
ceases to be valid beyond a cutoff scale , where is the
reduced Planck mass. We then argue that knowing the Higgs potential profile for
the field values relevant for inflation () requires knowledge of the ultraviolet completion of the SM beyond
. In absence of such microscopic theory, the extrapolation of the pure
SM potential beyond is unwarranted and the scenario is akin to other
ad-hoc inflaton potentials afflicted with significant fine-tuning. The
appealing naturalness of this minimal proposal is therefore lost.Comment: 9 pages. Replaced with published version, plus a footnote clarifying
the use of power counting estimate
The method of Gaussian weighted trajectories. V. On the 1GB procedure for polyatomic processes
In recent years, many chemical reactions have been studied by means of the
quasi-classical trajectory (QCT) method within the Gaussian binning (GB)
procedure. The latter consists in "quantizing" the final vibrational actions in
Bohr spirit by putting strong emphasis on the trajectories reaching the
products with vibrational actions close to integer values. A major drawback of
this procedure is that if N is the number of product vibrational modes, the
amount of trajectories necessary to converge the calculations is ~ 10^N larger
than with the standard QCT method. Applying it to polyatomic processes is thus
problematic. In a recent paper, however, Czako and Bowman propose to quantize
the total vibrational energy instead of the vibrational actions [G. Czako and
J. M. Bowman, J. Chem. Phys., 131, 244302 (2009)], a procedure called 1GB here.
The calculations are then only ~ 10 times more time-consuming than with the
standard QCT method, allowing thereby for considerable numerical saving. In
this paper, we propose some theoretical arguments supporting the 1GB procedure
and check its validity on model test cases as well as the prototype four-atom
reaction OH+D_2 -> HOD+D
Identities among relations for higher-dimensional rewriting systems
We generalize the notion of identities among relations, well known for
presentations of groups, to presentations of n-categories by polygraphs. To
each polygraph, we associate a track n-category, generalizing the notion of
crossed module for groups, in order to define the natural system of identities
among relations. We relate the facts that this natural system is finitely
generated and that the polygraph has finite derivation type.Comment: 16 pages, corrected version after review, to appear in S\'eminaires
et Congr\`e
- …