Important role of alkali atoms in A4C60

We show that hopping via the alkali atoms plays an important role for the t1u band of A4C60 (A=K, Rb), in strong contrast to A3C60. Thus the t1u band is broadened by more than 40 % by the presence of the alkali atoms. The difference between A4C60 and A3C60 is in particular due to the less symmetric location of the alkali atoms in A4C60.Comment: 5 pages, revtex, 2 figures, submitted to Phys. Rev. B more information at http://www.mpi-stuttgart.mpg.de/dokumente/andersen/fullerene

Floppy modes and non-affine deformations in random fiber networks

We study the elasticity of random fiber networks. Starting from a microscopic picture of the non-affine deformation fields we calculate the macroscopic elastic moduli both in a scaling theory and a self-consistent effective medium theory. By relating non-affinity to the low-energy excitations of the network (``floppy-modes'') we achieve a detailed characterization of the non-affine deformations present in fibrous networks.Comment: 4 pages, 2 figures, new figure

Shear dispersion along circular pipes is affected by bends, but the torsion of the pipe is negligible

The flow of a viscous fluid along a curving pipe of fixed radius is driven by a pressure gradient. For a generally curving pipe it is the fluid flux which is constant along the pipe and so I correct fluid flow solutions of Dean (1928) and Topakoglu (1967) which assume constant pressure gradient. When the pipe is straight, the fluid adopts the parabolic velocity profile of Poiseuille flow; the spread of any contaminant along the pipe is then described by the shear dispersion model of Taylor (1954) and its refinements by Mercer, Watt et al (1994,1996). However, two conflicting effects occur in a generally curving pipe: viscosity skews the velocity profile which enhances the shear dispersion; whereas in faster flow centrifugal effects establish secondary flows that reduce the shear dispersion. The two opposing effects cancel at a Reynolds number of about 15. Interestingly, the torsion of the pipe seems to have very little effect upon the flow or the dispersion, the curvature is by far the dominant influence. Lastly, curvature and torsion in the fluid flow significantly enhance the upstream tails of concentration profiles in qualitative agreement with observations of dispersion in river flow

Critical issues of double-metal layer coating on FBG for applications at high temperatures

Use of fiber Bragg gratings (FBGs) to monitor high temperature (HT) applications is of great interest to the research community. Standard commercial FBGs can operate up to 600 ∘ C. For applications beyond that value, specific processing of the FBGs must be adopted to allow the grating not to deteriorate. The most common technique used to process FBGs for HT applications is the regeneration procedure (RP), which typically extends their use up to 1000 ∘ C. RP involves a long-term annealing of the FBGs, to be done at a temperature ranging from 550 to 950 ∘ C. As at that temperature, the original coating of the FBGs would burn out, they shall stay uncoated, and their brittleness is a serious concern to deal with. Depositing a metal coating on the FBGs prior to process them for RP offers an effective solution to provide them with the necessary mechanical strengthening. In this paper, a procedure to provide the FBG with a bimetallic coating made by copper and nickel electrodeposition (ED) is proposed, discussing issues related to the coating morphology, adherence to the fiber, and effects on the grating spectral response. To define the processing parameters of the proposed procedure, production tests were performed on dummy samples which were used for destructive SEM-EDS analysis. As a critical step, the proposed procedure was shown to necessitate a heat treatment after the nickel ED, to remove the absorbed hydrogen. The spectral response of the FBG samples was monitored along the various steps of the proposed procedure and, as a final proof test for adherence stability of the bimetallic coating, along a heating/cooling cycle from room temperature to 1010 ∘ C. The results suggest that, given the emergence of Kirkendall voids at the copper-nickel interface, occurring at the highest temperatures (700-1010 ∘ C), the bimetallic layer could be employed as FBG coating up to 700 ∘ C

Neutron diffraction in a model itinerant metal near a quantum critical point

Neutron diffraction measurements on single crystals of Cr1-xVx (x=0, 0.02, 0.037) show that the ordering moment and the Neel temperature are continuously suppressed as x approaches 0.037, a proposed Quantum Critical Point (QCP). The wave vector Q of the spin density wave (SDW) becomes more incommensurate as x increases in accordance with the two band model. At xc=0.037 we have found temperature dependent, resolution limited elastic scattering at 4 incommensurate wave vectors Q=(1+/-delta_1,2, 0, 0)*2pi/a, which correspond to 2 SDWs with Neel temperatures of 19 K and 300 K. Our neutron diffraction measurements indicate that the electronic structure of Cr is robust, and that tuning Cr to its QCP results not in the suppression of antiferromagnetism, but instead enables new spin ordering due to novel nesting of the Fermi surface of Cr.Comment: Submitted as a part of proceedings of LT25 (Amsterdam 2008