Opportunities of Scanning Probe Microscopy for Electrical, Mechanical and Electromechanical Research of Semiconductor Nanowires

In this chapter, three types of phenomena (electrical, mechanical, and electromechanical) that can be investigated in individual III–V semiconductor nanowires with scanning probe microscope are presented. Transport measurements in GaAs nanowires based on stable electric connection provided opportunity to study individual vertical freestanding nanowires under gentle precisely controlled force. Latter approach appears superior to studies of horizontally fixed nanowires because studying vertical as‐grown nanowires avoids charge leakage into the substrate and impact of defects caused by breakage of nanowires. Principles of thermionic emission theory are used to characterize electrical effects in individual as-grown nanowires. Effects of SiO2 protective layer, surface passivation layers, illumination, and influence of sweeping rate of current‐voltage recording are analyzed. Elastic studies are performed for individual InP nanowires affixed at one end. Bending of the tapered nanowires with diameters of a narrow free end either 10 or 20 nm was performed under different loading forces. It allowed calculation of flexibility coefficient profiles along the nanowires’ axes. Improved numerical model for tapered nanowires leads to the finding of Young’s modulus of wurtzite InP material in nanowires. Piezoelectric measurements permitting registration of reverse piezo effect with opportunities of direct piezo response recording for individual wurtzite GaAs nanowires are briefly described

Composition of Ni2+ cation solvation shell in NiCl2–methanol solution by multinuclear NMR

1H-, 2H- and 13C-NMR spectra have been used to test the Ni2+ solvation shell composition in the 1.1 molal methanol solution of NiCl2. It has been confirmed that Cl− anion takes part in the nearest environment of Ni2+ cation at all the temperatures investigated. Using 2H-NMR allowed us to detect for the first time OD-signal of methanol in the primary solvation shell of Ni2+ cation. Both 2H- and 13C-NMR spectra show that the composition of the cation solvation shell becomes more complicated at temperatures lower than 220 K

Dispersion Characteristics of Spin-Electromagnetic Waves in Planar Multiferroic Structures with Coplanar Transmission Line

Introduction. The distinctive feature of a coplanar transmission line with thin ferrite and ferroelectric films is the absence of undesirable irregularities in dispersion for relatively low frequencies when the wavelength approaches the thickness of ferroelectric layer, in contrast to the open ferrite-ferroelectric wave-guiding structure without metallization.Aim. The purpose of this paper is twofold: (i) to develop a theory of the wave spectra in the multiferroic structures based on the coplanar lines; (ii) using this theory to find ways to enhance the electric tuning range.Materials and methods. The dispersion relation for spin-electromagnetic waves was derived through analytical solution of the full set of the Maxwell's equations utilizing a method of approximate boundary conditions.Results. A theory of spin-electromagnetic wave spectrum has been developed for the thin-film ferrite-ferroelectric structure based on a coplanar transmission line. According to this theory, dispersion characteristics of the spin-electromagnetic waves were described and analyzed for different parameters of the structure. The obtained results show that the investigated structure demonstrates a dual electric and magnetic field tunability of wave spectra. Its efficiency increases with an increase in the thicknesses of the ferrite and ferroelectric films and with a decrease in the width of the central metal strip.Conclusion. The distinctive features of the proposed coplanar waveguides are the thin-film planar topology and dual tunability of the wave spectra. All these advantages make the proposed structures perspective for development of new microwave devices.Introduction. The distinctive feature of a coplanar transmission line with thin ferrite and ferroelectric films is the absence of undesirable irregularities in dispersion for relatively low frequencies when the wavelength approaches the thickness of ferroelectric layer, in contrast to the open ferrite-ferroelectric wave-guiding structure without metallization.Aim. The purpose of this paper is twofold: (i) to develop a theory of the wave spectra in the multiferroic structures based on the coplanar lines; (ii) using this theory to find ways to enhance the electric tuning range.Materials and methods. The dispersion relation for spin-electromagnetic waves was derived through analytical solution of the full set of the Maxwell's equations utilizing a method of approximate boundary conditions.Results. A theory of spin-electromagnetic wave spectrum has been developed for the thin-film ferrite-ferroelectric structure based on a coplanar transmission line. According to this theory, dispersion characteristics of the spin-electromagnetic waves were described and analyzed for different parameters of the structure. The obtained results show that the investigated structure demonstrates a dual electric and magnetic field tunability of wave spectra. Its efficiency increases with an increase in the thicknesses of the ferrite and ferroelectric films and with a decrease in the width of the central metal strip.Conclusion. The distinctive features of the proposed coplanar waveguides are the thin-film planar topology and dual tunability of the wave spectra. All these advantages make the proposed structures perspective for development of new microwave devices

Magnetic field dependence of the martensitic transition and magnetocaloric effects in Ni49BiMn35In15

The structural, magnetic, and magnetocaloric properties of the Bi-doped Heusler alloy Ni49BiMn35In15 have been investigated using room temperature X-ray diffraction (XRD) and magnetization measurements in a temperature interval of 5-400 K. The alloy at room temperature was found to be in a mixture of a high temperature austenite phase (AP) and a low temperature martensite phase (MP). A drastic shift in the martensitic transition temperature at the rate of 16 K/T from 197 K to lower temperatures was observed. A kinetic arrest phenomenon of the AP was observed in the magnetization and electrical resistivity measurements during field-cooled (FC) measurements at 5T. A metamagnetic behavior characterized by a jump in magnetization in the isothermal M(H) curves near TM was observed. The maximum value of the magnetic entropy change and refrigerant capacity at Curie temperature were found to be 5.5 Jkg-1K-1 and 312 Jkg-1 for μoΔH = 5T, respectively. A large magnetoresistance value of -56% was found near the martensitic transition

Relaxation phenomena in adiabatic temperature changes near magnetostructural transitions in Heusler alloys

The relaxation processes of the adiabatic temperature changes (ΔTad) at the phase transitions in Ni45Mn43CoSn11, Ni50Mn36.5In13.5, and Ni50Mn35In14.25B0.75 Heusler alloys with different magnetic structures have been studied using a direct extraction method in magnetic fields up to 14 T. It has been found that ΔTad exhibits short relaxation times (less than 10−1 (s)) in the vicinity of the second order phase transitions at the Curie temperatures. The relaxation times of the first order martensitic transitions strongly depend on the latent heat of the transition and can be characterized by a logarithmic law

Effects of magnetic and structural phase transitions on the normal and anomalous Hall effects in Ni-Mn-In-B Heusler alloys

Magnetization, electrical resistivity, magnetoresistance, and Hall resistivity of Ni50Mn35In14.25B0.75 and Ni50Mn35In14.5B0.5 Heusler alloys were studied in a temperature range T=80-400K in magnetic fields up to 20 kOe. Both alloys exhibit a martensitic transformation from a higherature ferromagnetic austenite phase to a lowerature, low-magnetization martensitic phase. The electrical resistivity nearly doubles as a result of the martensitic transformation, reaching 180 and 100 μ cm in the martensitic states of Ni50Mn35In14.25B0.75 and Ni50Mn35In14.5B0.5, respectively. The temperature dependence of the electrical resistivity does not corresponded with the Mooij correlation. The magnetoresistance is negative with a narrow negative peak at the martensitic transition. Normal and anomalous Hall effect coefficients were determined by fitting the field dependences of the Hall resistivity using magnetization data. The coefficients of the normal Hall effect for both compositions were found to decrease with temperature from positive values in the austenite to negative values in the martensite phase. None of the known correlations between the anomalous Hall effect coefficient and resistivity were satisfied. Significant changes in the values of the anomalous Hall coefficients during the martensitic transformation are explained by the difference in spin-up and spin-down state occupations in the martensite and austenite phases. First-principles calculations of the electronic structures confirm this explanation