569 research outputs found
Anisotropic exchange and effective crystal field parameters for low dimensional systems, EPR data
We review some aspects of the electron paramagnetic resonance (EPR) studies in quasi-onedimensional inorganic compounds with special emphasis on the angular dependencies of g-factors, linewidth and the information they reveal about the physical system. In particular, we employ for the analysis of the data the method of moments and outline the expressions for the second and the fourth moments which is related to different spin-spin interactions
Anisotropy of the paramagnetic susceptibility in LaTiO: The electron-distribution picture in the ground state
The energy-level scheme and wave functions of the titanium ions in
LaTiO are calculated using crystal-field theory and spin-orbit coupling.
The theoretically derived temperature dependence and anisotropy of the magnetic
susceptibility agree well with experimental data obtained in an untwinned
single crystal. The refined fitting procedure reveals an almost isotropic
molecular field and a temperature dependence of the van Vleck susceptibility.
The charge distribution of the 3d--electron on the Ti positions and the
principle values of the quadrupole moments are derived and agree with NMR data
and recent measurements of orbital momentum and crystal-field splitting.
The low value of the ordered moment in the antiferromagnetic phase is
discussed.Comment: 6 pages, 2 figures, 3 table
Anisotropic Exchange in LiCuVO probed by ESR
We investigated the paramagnetic resonance in single crystals of LiCuVO
with special attention to the angular variation of the absorption spectrum. To
explain the large resonance linewidth of the order of 1 kOe, we analyzed the
anisotropic exchange interaction in the chains of edge-sharing CuO
octahedra, taking into account the ring-exchange geometry of the
nearest-neighbor coupling via two symmetric rectangular Cu-O bonds. The
exchange parameters, which can be estimated from theoretical considerations,
nicely agree with the parameters obtained from the angular dependence of the
linewidth. The anisotropy of this magnetic ring exchange is found to be much
larger than it is usually expected from conventional estimations which neglect
the bonding geometry. Hence, the data yield the evidence that in copper oxides
with edge-sharing structures the role of the orbital degrees of freedom is
strongly enhanced. These findings establish LiCuVO as one-dimensional
compound at high temperatures.
PACS: 76.30.-v, 76.30.Fc, 75.30.EtComment: 18 pages, 6 figure
Electron spin resonance and exchange paths in the orthorhombic dimer system Sr2VO4
We report on magnetization and electron spin resonance (ESR) measurements of
SrVO with orthorhombic symmetry. In this dimer system the
ions are in tetrahedral environment and are coupled by an antiferromagnetic
intra-dimer exchange constant 100 K to form a singlet ground
state without any phase transitions between room temperature and 2 K. Based on
an extended-H\"{u}ckel-Tight-Binding analysis we identify the strongest
exchange interaction to occur between two inequivalent vanadium sites via two
intermediate oxygen ions. The ESR absorption spectra can be well described by a
single Lorentzian line with an effective g-factor = 1.89. The temperature
dependence of the ESR intensity is well described by a dimer model in agreement
with the magnetization data. The temperature dependence of the ESR linewidth
can be modeled by a superposition of a linear increase with temperature with a
slope = 1.35 Oe/K and a thermally activated behavior with an
activation energy = 1418 K, both of which point to spin-phonon
coupling as the dominant relaxation mechanism in this compound.Comment: 5 pages, 4 figure
Spin correlations and Dzyaloshinskii-Moriya interaction in CsCuCl
We report on electron spin resonance (ESR) studies of the spin relaxation in
CsCuCl. The main source of the ESR linewidth at temperatures K is attributed to the uniform Dzyaloshinskii-Moriya interaction. The
vector components of the Dzyaloshinskii-Moriya interaction are determined from
the angular dependence of the ESR spectra using a high-temperature
approximation. Both the angular and temperature dependence of the ESR linewidth
have been analyzed using a self-consistent quantum-mechanical approach. In
addition analytical expressions based on a quasi-classical picture for spin
fluctuations are derived, which show good agreement with the quantum-approach
for temperatures K. A small modulation of the
ESR linewidth observed in the -plane is attributed to the anisotropic
Zeeman interaction, which reflects the two magnetically nonequivalent Cu
positions
Detection of Fusobacterium spp in colorectal tissue samples using reverse transcription polymerase chain reaction with minor groove binder probes: an exploratory research
An unhealthy microbiome is intimately correlated with several disease states, including colorectal cancer, wherein bacteria might be the key to neoplastic initiation and progression. Recent studies revealed an enrichment of Fusobacterium in colorectal tumor tissues relative to surrounding normal mucosa. Given the available evidence, we conducted an exploratory study quantifying the relative expression of Fusobacterium spp in 28 tissue samples from patients treated at Centro Hospitalar de São João belonging to 4 different groups: adenomas, paired normal tissue from patients with adenomas, carcinomas, and paired normal tissue from patients with colorectal carcinomas. To increase reverse transcription polymerase chain reaction quantification sensitivity, minor groove binders fluorescent probes were used, having in mind its implementation into routine clinical practice. Differences of Fusobacterium spp relative abundance between paired neoplastic lesions/normal tissue were examined by Wilcoxon signed-rank test and for all the other 2-group comparisons the Mann-Whitney U test was used. Most of the adenomas studied belonged to clinical specimens showing either tubular or villous low-grade dysplasia and an enrichment of Fusobacterium relative to paired normal tissue was not found (P = .180). In the carcinoma group, 57% of samples displayed a positive status for this bacterium with the highest burden of detectable Fusobacterium belonging to a specimen with positive regional lymph node metastasis. This is the first Portuguese study confirming a trend toward an overabundance of Fusobacterium in colorectal carcinomas compared to adenomas and paired samples of normal-looking mucosa, in keeping with the role of this bacterium in colorectal carcinogenesis. Further studies are needed to elucidate the relevance of Fusobacterium detection for the prevention and treatment of colorectal cancer
Structural, thermodynamic, and local probe investigations of a honeycomb material AgLiMnO
The system Ag[LiMn]O belongs to a quaternary
3R-delafossite family and crystallizes in a monoclinic symmetry with space
group and the magnetic Mn() ions form a honeycomb
network in the -plane. An anomaly around 50 K and the presence of
antiferromagnetic (AFM) coupling (Curie-Weiss temperature
K) were inferred from our magnetic susceptibility data. The magnetic specific
heat clearly manifests the onset of magnetic ordering in the vicinity of 48\,K
and the recovered magnetic entropy, above the ordering temperature, falls short
of the expected value, implying the presence of short-range magnetic
correlations. The (ESR) line broadening on approaching the ordering temperature
could be described in terms of a Berezinski-Kosterlitz-Thouless
(BKT) scenario with K. Li NMR line-shift probed as a
function of temperature tracks the static susceptibility (K) of
magnetically coupled Mn ions. The Li spin-lattice relaxation rate
(1/) exhibits a sharp decrease below about 50 K. Combining our bulk
and local probe measurements, we establish the presence of an ordered ground
state for the honeycomb system AgLiMnO.Our ab-initio
electronic structure calculations suggest that in the -plane, the nearest
neighbor (NN) exchange interaction is strong and AFM, while the next NN and the
third NN exchange interactions are FM and AFM respectively. In the absence of
any frustration the system is expected to exhibit long-range, AFM order, in
agreement with experiment.Comment: 11 pages, 13 figures, accepted in Phys Rev
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