581 research outputs found
Charge transfer and weak bonding between molecular oxygen and graphene zigzag edges at low temperatures
Electron paramagnetic resonance (EPR) study of air-physisorbed defective
carbon nano-onions evidences in favor of microwave assisted formation of
weakly-bound paramagnetic complexes comprising negatively-charged O2- ions and
edge carbon atoms carrying pi-electronic spins. These complexes being located
on the graphene edges are stable at low temperatures but irreversibly
dissociate at temperatures above 50-60 K. These EPR findings are justified by
density functional theory (DFT) calculations demonstrating transfer of an
electron from the zigzag edge of graphene-like material to oxygen molecule
physisorbed on the graphene sheet edge. This charge transfer causes changing
the spin state of the adsorbed oxygen molecule from S = 1 to S = 1/2 one. DFT
calculations show significant changes of adsorption energy of oxygen molecule
and robustness of the charge transfer to variations of the graphene-like
substrate morphology (flat and corrugated mono- and bi-layered graphene) as
well as edges passivation. The presence of H- and COOH- terminated edge carbon
sites with such corrugated substrate morphology allows formation of ZE-O2-
paramagnetic complexes characterized by small (<50 meV) binding energies and
also explains their irreversible dissociation as revealed by EPR.Comment: 28 pages, 8 figures, 2 tables, accepted in Carbon journa
Arrival time distributions of electrons in air showers with primary energies above 10 (18)eV observed at 900m above sea level
Detection of air showers with primary energies above 10 to the 19th power eV with sufficient statistics is extremely important in an astrophysical aspect related to the Greisen cut off and the origin of such high energy cosmic rays. Recently, a method is proposed to observe such giant air showers by measuring the arrival time distributions of air-shower particles at large core distances with a mini array. Experiments to measure the arrival time distributions of muons were started in 1981 and those of electrons in early 1983 in the Akeno air-shower array (930 gcm cm squared atmospheric depth, 900m above sea level). During the time of observation, the detection area of the Akeno array was expanded from 1 sq km to sq km in 1982 and to 20 sq km in 1984. Now the arrival time distribution of electrons and muons can be measured for showers with primary energies above 1019eV at large core distances
Longitudinal development of muons in large air showers studies from the arrival time distributions measured at 900m above sea level
The arrival time distributions of muons with energies above 1.0GeV and 0.5GeV have been measured in the Akeno air-shower array to study the longitudinal development of muons in air showers with primary energies in the range 10 to the 17th power to 10 to the 18th power ev. The average rise times of muons with energies above 1.0GeV at large core distances are consistent with those expected from very high multiplicity models and, on the contrary, with those expected from the low multiplicity models at small core distances. This implies that the longitudinal development at atmospheric depth smaller than 500 cm square is very fast and that at larger atmospheric depths is rather slow
Extending the linearity range of eddy-current displacement sensor with magnetoplated wire
This material is presented to ensure timely dissemination of scholarly and technical work. Copyright and all rights therein are retained by authors or by other copyright holders. All persons copying this information are expected to adhere to the terms and constraints invoked by each author's copyright. In most cases, these works may not be reposted without the explicit permission of the copyright holder.ArticleIEEE TRANSACTIONS ON MAGNETICS. 43(2): 543-548 (2007)journal articl
Reduction of eddy current loss in magnetoplated wire
ArticleCOMPEL-THE INTERNATIONAL JOURNAL FOR COMPUTATION AND MATHEMATICS IN ELECTRICAL AND ELECTRONIC ENGINEERING. 28(1):57-66 (2009)journal articl
Spin-stripe density varies linearly with hole content in single-layer Bi2201 cuprate
We have performed inelastic neutron scattering measurements on the
single-layer cuprate Bi2+xSr2-xCuO6+y (Bi2201) with x=0.2, 0.3, 0.4 and 0.5, a
doping range that spans the spin-glass (SG) to superconducting (SC) phase
boundary. The doping evolution of low energy spin fluctuations was found to be
characterized by a change of incommensurate modulation wave vector from the
tetragonal [110] to [100]/[010] directions, while maintaining a linear relation
between the incommensurability and the hole concentration, delta p. In the SC
regime, the spectral weight is strongly suppressed below 4 meV. Similarities
and differences in the spin correlations between Bi2201 and the prototypical
single-layer system La2-xSrxCuO4 are discussed.Comment: 5 page,4 figure
Reduction of proximity effect in coil using magnetoplated wire
This material is presented to ensure timely dissemination of scholarly and technical work. Copyright and all rights therein are retained by authors or by other copyright holders. All persons copying this information are expected to adhere to the terms and constraints invoked by each author's copyright. In most cases, these works may not be reposted without the explicit permission of the copyright holder.ArticleIEEE TRANSACTIONS ON MAGNETICS. 43(6): 2654-2656 (2007)journal articl
Reversible Fluorination of Graphene: towards a Two-Dimensional Wide Bandgap Semiconductor
We report the synthesis and evidence of graphene fluoride, a two-dimensional
wide bandgap semiconductor derived from graphene. Graphene fluoride exhibits
hexagonal crystalline order and strongly insulating behavior with resistance
exceeding 10 G at room temperature. Electron transport in graphene
fluoride is well described by variable-range hopping in two dimensions due to
the presence of localized states in the band gap. Graphene obtained through the
reduction of graphene fluoride is highly conductive, exhibiting a resistivity
of less than 100 k at room temperature. Our approach provides a new
path to reversibly engineer the band structure and conductivity of graphene for
electronic and optical applications.Comment: 7 pages, 5 figures, revtex, to appear in PR
- …