12 research outputs found

    Response surface methodological optimization of batch Cu(II) sorption onto succinic acid functionalized SiO2 nanoparticles

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    Functionalizing nanosilica (n-SiO2) particles with suitable active organic moiety leads to the formation of surfaces with precisely controlled physical and chemical characteristics. In this work, a novel nanosorbent (31±2.4 nm) namely succinic acid functionalized nanosilica (n-SiO2@SA) was synthesized via a simple protocol using microwave irradiation to remove Cu(II) ions from aqueous media. The successful functionalization of n-SiO2 was confirmed by FTIR while the thermal stability of n-SiO2@SA is investigated by TGA study. Other techniques including, HRTEM, DLS and zeta-potential were utilized to investigate the chemical, surface and morphological properties of the fabricated n-SiO2@SA. The response surface methodology (RSM) combined with 3-level, 3-factorial Box–Behnken design (BBD) were applied to optimize the multivariable sorption system using data obtained from 17 batch runs to reach 98.9% of Cu(II) ion removal. The predicted optimal conditions were: contact time = 30 min, pH = 7.1, initial Cu(II) concentration = 317.5 mg L−1 and sorbent dose = 15 mg at which the maximum sorption capacities for n-SiO2 and n-SiO2@SA were 209.3 and 386.4 mg g−1, respectively at 25 oC supporting the validity of functionalization process. Non-linear regression and linear least-squares methods confirm the suitability of Langmuir model to describe the experimental endothermic, feasible and chemisorption data, while the normalized standard deviation Δq% recommends the pseudo second-order kinetic model to represent the kinetic data. Real Cu-contaminated wastewaters were used to examine n-SiO2@SA nanosorbent for removing Cu(II) ions.The accepted manuscript in pdf format is listed with the files at the bottom of this page. The presentation of the authors' names and (or) special characters in the title of the manuscript may differ slightly between what is listed on this page and what is listed in the pdf file of the accepted manuscript; that in the pdf file of the accepted manuscript is what was submitted by the author

    Cationic Surfactant-Modified <i>Tetraselmis</i> sp. for the Removal of Organic Dyes from Aqueous Solution

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    The modification of the Tetraselmis sp. algae material (Tetra-Alg) with surfactant Cethyltrimethylammonium Bromide (CTAB) yielded adsorbent Tetra-Alg-CTAB as an adsorbent of methyl orange (MO) and methylene blue (MB) solutions. The characterization of the adsorbent used an infrared (IR) spectrometer to identify functional groups and Scanning Electron Microscopy with Energy Dispersive X-ray (SEM-EDX FEI Inspect-S50, Midland, ON, Canada) to determine the surface morphology and elemental composition. Methyl orange and methylene blue adsorption on the adsorbent Tetra-Alg, Tetraselmis sp. algae-modified Na+ ions (Tetra-Alg-Na), and Tetra-Alg-CTAB were studied, including variations in pH, contact time, concentration, and reuse of adsorbents. The adsorption of MO and MB by Tetra-Alg-CTAB at pH 10, during a contact time of 90 min, and at a concentration of 250 mg L−1 resulted in MO and MB being absorbed in the amounts of 128.369 and 51.013 mg g−1, respectively. The adsorption kinetics and adsorption isotherms of MO and MB and Tetra-Alg, Tetra-Alg-Na, and Tetra-Alg-CTAB tend to follow pseudo-second-order kinetics models and Freundlich adsorption isotherms with each correlation coefficient value (R2) approaching 1. Due to the modification with the cationic surfactant CTAB, anionic dyes can be strongly sorbed in alkaline pH due to strong electrostatic attraction, while MB is more likely to involve cation exchange and hydrogen bonding. The reuse of Tetra-Alg-CTAB was carried out four times with adsorption percent > 70%, and the adsorbent was very effective in the adsorption of anionic dyes such as MO

    Recovery of Heavy Metal Ions Using Magnetic Glycine-Modified Chitosan—Application to Aqueous Solutions and Tailing Leachate

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    The necessity of decontaminating effluents for the dual purpose of environmental beneficiation and valorization of low-grade resources is driving the development of new sorbents. The functionalization of biopolymers is a promising strategy for improving sorption performance. Incorporating magnetic micro-particles offers an opportunity for the facilitated recovery of spent micron-size sorbent. Combining magnetic facilities and biopolymer functionalization represents a winning strategy. Magnetic glycine-grafted chitosan (G@MChs) was synthesized for the sorption of Ni(II), Zn(II), and Hg(II) before being applied to the removal of hazardous and strategic metals from tailing leachates. The sorbent was characterized using Fourier transform infrared spectroscopy and scanning electron microscopy, before and after metal sorption. The acid–base properties of functionalized sorbent were also determined (pHPZC). Uptake kinetics were studied in mono- and multi-component solutions using different equations for kinetic modeling at optimized pH (i.e., pH0: 5.5). Langmuir and Sips equations were applied to model sorption isotherms in single-component solutions. In addition, sorption isotherms in multi-component solutions were used to evaluate the preference for selected metals. Maximum sorption capacities were 0.35 mmol Hg g−1, 0.47 mmol Zn g−1, and 0.50 mmol Ni g−1. Acidified urea solution (pH 2.7) successfully desorbs metal ions from G@MChs (desorption &gt; 90%). The sorbent was tested for the recovery of hazardous and strategic metal ions from acidic leachates of tailings. This study demonstrates the promising performance of G@MChs for the treatment of complex metal-bearing solutions

    The synergistic effect of ultrasound power and magnetite incorporation on the sorption/desorption behavior of Cr(VI) and As(V) oxoanions in an aqueous system

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    Though abundant studies have targeted the sorption of Cr(VI) and As(V) anions by organic polymers or magnetic metal oxides, there is no research literature on the sorption characteristics of Cr(VI) and As(V) by thiourea-formaldehyde resin (TF) and its magnetic derivative (MTF). TF resin is a strong chelating agent, which has several practical applications. This paper reports on the removal of Cr(VI) and As(V) oxoanions by TF and MTF sorbents. The sorbents were characterized by Fourier transform infrared (FTIR), nuclear magnetic resonance (NMR) spectroscopy, elemental analysis, zetametry, Brunauer-Emmett-Teller (BET) analysis, and differential light scattering (DLS). The synergistic influence of magnetite incorporation and ultrasonic power on sorption kinetics, isotherms, and oxoanion desorption were investigated, including the analysis of the uncertainty in the study results. The relationship between kinetic and equilibrium constants of the two sorbents under normal shaking and ultrasound shaking was analysed. Ultrasound power improved the mass transfer and makes the sorption ultra-fast while magnetite enhanced the sorption capacity. The MTF particles sorbed 4.28 and 1.97 mmol g−1 of Cr(VI) and As(V), respectively, under optimum conditions. Further, desorption kinetics and efficiency of Cr(VI) and As(V) were estimated using normal shaking and ultrasonic agitation. Ultrasound power reduced the time and the concentration of NaCl required for the stabilization of desorption efficiency.</p

    Magnetic alginate beads with high basic dye removal potential and excellent regeneration ability

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    The adsorption of crystal violet dye (CV) onto magnetic alginate composite (MAlg) from aqueous solutions was studied. Experiments were carried out as function of contact time, dosage, temperature, pH and CV concentration in the solutions. Optimum CV uptake was observed at equilibrium pH 7 and most of the CV was sorbed within 30 min. The equilibrium adsorption data were analyzed using two common adsorption models: Langmuir and Freundlich. The results revealed that Langmuir isotherm fit the experimental results well. The maximum adsorption capacity obtained from Langmuir isotherm equation was 0.113 mmol g−1 at 298±1 K. The kinetics adsorption of CV onto MAlg composite was investigated using the pseudo ïŹrst order and pseudo second order kinetic models. The results showed that the adsorption of CV onto MAlg composite followed pseudo second order kinetic model. Thermodynamic data indicated that adsorption process is endothermic and spontaneous reaction. Due to their outstanding adsorption capacities, MAlg composite is an excellent adsorbent for the removal of CV. The Composite regeneration was greater than 98.6% with 0.01 M HCl, and MAlg composite could be repeatedly utilized for CV removal with negligible loss in sorption capacity.The accepted manuscript in pdf format is listed with the files at the bottom of this page. The presentation of the authors' names and (or) special characters in the title of the manuscript may differ slightly between what is listed on this page and what is listed in the pdf file of the accepted manuscript; that in the pdf file of the accepted manuscript is what was submitted by the author

    Efficient Recovery of Rare Earth Elements (Pr(III) and Tm(III)) From Mining Residues Using a New Phosphorylated Hydrogel (Algal Biomass/PEI)

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    International audienceWith the target of recovering rare earth elements (REEs) from acidic leachates, a new functionalized hydrogel was designed, based on the phosphorylation of algal/polyethyleneimine beads. The functionalization strongly increased the sorption efficiency of the raw material for Pr(III) and Tm(III). Diverse techniques were used for characterizing this new material and correlating the sorption performances and mechanisms to the physicochemical structure of the sorbent. First, the work characterized the sorption properties from synthetic solutions with the usual procedures (study of pH effect, uptake kinetics, sorption isotherms, metal desorption and sorbent recycling, and selectivity from multi-element solutions). Optimum pH was found close to 5; sorption isotherms were fitted by the Langmuir equation (maximum sorption capacities close to 2.14 mmol Pr g−1 and 1.57 mmol Tm g−1). Fast uptake kinetics were modeled by the pseudo-second order rate equation. The sorbent was highly selective for REEs against alkali-earth and base metals. The sorbent was remarkably stable for sorption and desorption operation (using 0.2 M HCl/0.5 M CaCl2 solutions). The sorbent was successfully applied to the leachates of Egyptian ore (pug leaching) after a series of pre-treatments (precipitation steps), sorption, and elution. The selective precipitation of REEs using oxalic acid allows for the recovery of a pure REE precipitate
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