113 research outputs found

    Suelos volcanicos endurecidos

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    The tepetates of Mexico Highlands are indurated horizons with fragipan pr0perties. Tepetates appear among pyroclastic deposits (T1, T2, T3). A soil profile located near Texcoco, Mexico, including tepetate layers was studied. Mineralogical and microscopical features of this profile were studied using a series of methods. This report the main results of the study. Tepetates were characterized by several features: first, the nature of their parent material; second, a close matrix microstructure and third, their colloidal fraction. The latter is conformed mainly by laminated 1:1 to 2:1 mixed layer minerals made of flaky layers. These features can explain the fragipan properties of tepetates and most of their mechanical behaviour. (Résumé d'auteur)

    Temporal and spatial monitoring of mobile nanoparticles in a vineyard soil: Evidence of nanoaggregate formation

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    Mechanisms of formation, stabilization, liberation, transport and deposition of nanoparticles and their relationship to contaminant transport remain scarcely investigated in natural porous media. This study investigated nanoparticles mobilized in the pore space of a French vineyard soil by observing mobile soil-derived organic matter (SOM) and minerals in pore fluids over an 8-month monitoring period. Samples were collected in situ and investigated by transmission electron microscopy coupled to electron-dispersive spectroscopy. The main types of nanoparticles transported within the soil were clay, bacteria, SOM and nanoaggregates. Nanometric clay particles were enriched in various metals (Fe, Zn, As and Pb) and organically-derived constituents. Analyses of bacteria showed enrichments in Pb. SOM consisted of small carbon-based particles (\u3c200 nm) with slight enrichments in various metals. The fourth dominant particle type consisted of the association of particles forming organo-mineral nanoaggregates. Based on the study of more than 22 500 individual particles, we propose a schematic interpretation of the evolution of the distribution of particles with depth in a soil profile. The increase of nanoaggregates with depth in the soil seemed to be largely controlled by the ionic strength of soil water and soil hydrodynamics. Seasonal variations in temperature also appear to affect nanoaggregation. Based on the architecture of the nanoaggregates, we propose an improvement of pre-existing models of microaggregation by focusing on early aggregation stages suggesting the importance of bacteria and electrostatic interactions. The process of nanoaggregation can enhance the net reactivity of soil with respect to transported suspended matter, including heavy metals, and can initiate the process of C sequestration. © 2010 The Authors. Journal compilation © 2010 British Society of Soil Science

    Microscopie Ă©lectronique analytique

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    Vectorial dissipative solitons in vertical-cavity surface-emitting Lasers with delays

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    We show that the nonlinear polarization dynamics of a vertical-cavity surface-emitting laser placed into an external cavity leads to the formation of temporal vectorial dissipative solitons. These solitons arise as cycles in the polarization orientation, leaving the total intensity constant. When the cavity round-trip is much longer than their duration, several independent solitons as well as bound states (molecules) may be hosted in the cavity. All these solutions coexist together and with the background solution, i.e. the solution with zero soliton. The theoretical proof of localization is given by the analysis of the Floquet exponents. Finally, we reduce the dynamics to a single delayed equation for the polarization orientation allowing interpreting the vectorial solitons as polarization kinks.Comment: quasi final resubmission version, 12 pages, 9 figure

    CRY2 Is Associated with Rapid Cycling in Bipolar Disorder Patients

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    Bipolar disorder patients often display abnormalities in circadian rhythm, and they are sensitive to irregular diurnal rhythms. CRY2 participates in the core clock that generates circadian rhythms. CRY2 mRNA expression in blood mononuclear cells was recently shown to display a marked diurnal variation and to respond to total sleep deprivation in healthy human volunteers. It was also shown that bipolar patients in a depressive state had lower CRY2 mRNA levels, nonresponsive to total sleep deprivation, compared to healthy controls, and that CRY2 gene variation was associated with winter depression in both Swedish and Finnish cohorts.Four CRY2 SNPs spanning from intron 2 to downstream 3'UTR were analyzed for association to bipolar disorder type 1 (n = 497), bipolar disorder type 2 (n = 60) and bipolar disorder with the feature rapid cycling (n = 155) versus blood donors (n = 1044) in Sweden. Also, the rapid cycling cases were compared with bipolar disorder cases without rapid cycling (n = 422). The haplotype GGAC was underrepresented among rapid cycling cases versus controls and versus bipolar disorder cases without rapid cycling (OR = 0.7, P = 0.006-0.02), whereas overrepresentation among rapid cycling cases was seen for AAAC (OR = 1.3-1.4, P = 0.03-0.04) and AGGA (OR = 1.5, P = 0.05). The risk and protective CRY2 haplotypes and their effect sizes were similar to those recently suggested to be associated with winter depression in Swedes.We propose that the circadian gene CRY2 is associated with rapid cycling in bipolar disorder. This is the first time a clock gene is implicated in rapid cycling, and one of few findings showing a molecular discrimination between rapid cycling and other forms of bipolar disorder

    Transmission Electron Microscopy

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    Illite-Smectite Alteration and Accompanying Reactions in a Pennsylvanian Underclay Studied by TEM

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