8,212 research outputs found
Revealing the pure confinement effect in glass-forming liquids by dynamic mechanical analysis
Many molecular glass forming liquids show a shift of the glass transition Tg
to lower temperatures when the liquid is confined into mesoporous host
matrices. Two contrary explanations for this effect are given in literature:
First, confinement induced acceleration of the dynamics of the molecules leads
to an effective downshift of Tg increasing with decreasing pore size. Secondly,
due to thermal mismatch between the liquid and the surrounding host matrix,
negative pressure develops inside the pores with decreasing temperature, which
also shifts Tg to lower temperatures. Here we present novel dynamic mechanical
analysis measurements of the glass forming liquid salol in Vycor and Gelsil
with pore sizes of d = 2.6, 5.0 and 7.5 nm. The dynamic complex elastic
susceptibility data can be consistently described with the assumption of two
relaxation processes inside the pores: A surface induced slowed down relaxation
due to interaction with rough pore interfaces and a second relaxation within
the core of the pores. This core relaxation time is reduced with decreasing
pore size d, leading to a downshift of Tg in perfect agreement with recent DSC
measurements
Amplitude equations near pattern forming instabilities for strongly driven ferromagnets
A transversally driven isotropic ferromagnet being under the influence of a
static external and an uniaxial internal anisotropy field is studied. We
consider the dissipative Landau-Lifshitz equation as the fundamental equation
of motion and treat it in ~dimensions. The stability of the spatially
homogeneous magnetizations against inhomogeneous perturbations is analyzed.
Subsequently the dynamics above threshold is described via amplitude equations
and the dependence of their coefficients on the physical parameters of the
system is determined explicitly. We find soft- and hard-mode instabilities,
transitions between sub- and supercritical behaviour, various bifurcations of
higher codimension, and present a series of explicit bifurcation diagrams. The
analysis of the codimension-2 point where the soft- and hard-mode instabilities
coincide leads to a system of two coupled Ginzburg-Landau equations.Comment: LATeX, 25 pages, submitted to Z.Phys.B figures available via
[email protected] in /pub/publications/frank/zpb_95
(postscript, plain or gziped
Direct Hopf Bifurcation in Parametric Resonance of Hybridized Waves
We study parametric resonance of interacting waves having the same wave
vector and frequency. In addition to the well-known period-doubling instability
we show that under certain conditions the instability is caused by a Hopf
bifurcation leading to quasiperiodic traveling waves. It occurs, for example,
if the group velocities of both waves have different signs and the damping is
weak. The dynamics above the threshold is briefly discussed. Examples
concerning ferromagnetic spin waves and surface waves of ferro fluids are
discussed.Comment: Appears in Phys. Rev. Lett., RevTeX file and three postscript
figures. Packaged using the 'uufiles' utility, 33 k
Early embryonic mortality in strain crossed gilts
Digitized 2007 AES.Includes bibliographical references (page [36])
Stick-slip motion of solids with dry friction subject to random vibrations and an external field
We investigate a model for the dynamics of a solid object, which moves over a
randomly vibrating solid surface and is subject to a constant external force.
The dry friction between the two solids is modeled phenomenologically as being
proportional to the sign of the object's velocity relative to the surface, and
therefore shows a discontinuity at zero velocity. Using a path integral
approach, we derive analytical expressions for the transition probability of
the object's velocity and the stationary distribution of the work done on the
object due to the external force. From the latter distribution, we also derive
a fluctuation relation for the mechanical work fluctuations, which incorporates
the effect of the dry friction.Comment: v1: 23 pages, 9 figures; v2: Reference list corrected; v3: Published
version, typos corrected, references adde
Charge injection instability in perfect insulators
We show that in a macroscopic perfect insulator, charge injection at a
field-enhancing defect is associated with an instability of the insulating
state or with bistability of the insulating and the charged state. The effect
of a nonlinear carrier mobility is emphasized. The formation of the charged
state is governed by two different processes with clearly separated time
scales. First, due to a fast growth of a charge-injection mode, a localized
charge cloud forms near the injecting defect (or contact). Charge injection
stops when the field enhancement is screened below criticality. Secondly, the
charge slowly redistributes in the bulk. The linear instability mechanism and
the final charged steady state are discussed for a simple model and for
cylindrical and spherical geometries. The theory explains an experimentally
observed increase of the critical electric field with decreasing size of the
injecting contact. Numerical results are presented for dc and ac biased
insulators.Comment: Revtex, 7pages, 4 ps figure
Imbibition in mesoporous silica: rheological concepts and experiments on water and a liquid crystal
We present, along with some fundamental concepts regarding imbibition of
liquids in porous hosts, an experimental, gravimetric study on the
capillarity-driven invasion dynamics of water and of the rod-like liquid
crystal octyloxycyanobiphenyl (8OCB) in networks of pores a few nanometers
across in monolithic silica glass (Vycor). We observe, in agreement with
theoretical predictions, square root of time invasion dynamics and a sticky
velocity boundary condition for both liquids investigated.
Temperature-dependent spontaneous imbibition experiments on 8OCB reveal the
existence of a paranematic phase due to the molecular alignment induced by the
pore walls even at temperatures well beyond the clearing point. The ever
present velocity gradient in the pores is likely to further enhance this
ordering phenomenon and prevent any layering in molecular stacks, eventually
resulting in a suppression of the smectic phase in favor of the nematic phase.Comment: 18 pages, 8 figure
Confinement effects on glass forming liquids probed by DMA
Many molecular glass forming liquids show a shift of the glass transition T-g
to lower temperatures when the liquid is confined into mesoporous host
matrices. Two contrary explanations for this effect are given in literature:
First, confinement induced acceleration of the dynamics of the molecules leads
to an effective downshift of T-g increasing with decreasing pore size. Second,
due to thermal mismatch between the liquid and the surrounding host matrix,
negative pressure develops inside the pores with decreasing temperature, which
also shifts T-g to lower temperatures. Here we present dynamic mechanical
analysis measurements of the glass forming liquid salol in Vycor and Gelsil
with pore sizes of d=2.6, 5.0 and 7.5 nm. The dynamic complex elastic
susceptibility data can be consistently described with the assumption of two
relaxation processes inside the pores: A surface induced slowed down relaxation
due to interaction with rough pore interfaces and a second relaxation within
the core of the pores. This core relaxation time is reduced with decreasing
pore size d, leading to a downshift of T-g proportional to 1/d in perfect
agreement with recent differential scanning calorimetry (DSC) measurements.
Thermal expansion measurements of empty and salol filled mesoporous samples
revealed that the contribution of negative pressure to the downshift of T-g is
small (<30%) and the main effect is due to the suppression of dynamically
correlated regions of size xi when the pore size xi approaches
On the driven Frenkel-Kontorova model: II. Chaotic sliding and nonequilibrium melting and freezing
The dynamical behavior of a weakly damped harmonic chain in a spatially
periodic potential (Frenkel-Kontorova model) under the subject of an external
force is investigated. We show that the chain can be in a spatio-temporally
chaotic state called fluid-sliding state. This is proven by calculating
correlation functions and Lyapunov spectra. An effective temperature is
attributed to the fluid-sliding state. Even though the velocity fluctuations
are Gaussian distributed, the fluid-sliding state is clearly not in equilibrium
because the equipartition theorem is violated. We also study the transition
between frozen states (stationary solutions) and=7F molten states
(fluid-sliding states). The transition is similar to a first-order phase
transition, and it shows hysteresis. The depinning-pinning transition
(freezing) is a nucleation process. The frozen state contains usually two
domains of different particle densities. The pinning-depinning transition
(melting) is caused by saddle-node bifurcations of the stationary states. It
depends on the history. Melting is accompanied by precursors, called
micro-slips, which reconfigurate the chain locally. Even though we investigate
the dynamics at zero temperature, the behavior of the Frenkel-Kontorova model
is qualitatively similar to the behavior of similar models at nonzero
temperature.Comment: Written in RevTeX, 13 figures in PostScript, appears in PR
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