First-principles thermodynamic modeling of lanthanum chromate perovskites

Tendencies toward local atomic ordering in (A,A′)(B,B′)O_(3−δ) mixed composition perovskites are modeled to explore their influence on thermodynamic, transport, and electronic properties. In particular, dopants and defects within lanthanum chromate perovskites are studied under various simulated redox environments. (La_(1−x),Sr_x)(Cr_(1−y),Fe_y)O_(3−δ) (LSCF) and (La_(1−x),Sr_x)(Cr_(1−y),Ru_y)O_(3−δ) (LSCR) are modeled using a cluster expansion statistical thermodynamics method built upon a density functional theory database of structural energies. The cluster expansions are utilized in lattice Monte Carlo simulations to compute the ordering of Sr and Fe(Ru) dopant and oxygen vacancies (Vac). Reduction processes are modeled via the introduction of oxygen vacancies, effectively forcing excess electronic charge onto remaining atoms. LSCR shows increasingly extended Ru-Vac associates and short-range Ru-Ru and Ru-Vac interactions upon reduction; LSCF shows long-range Fe-Fe and Fe-Vac interaction ordering, inhibiting mobility. First principles density functional calculations suggest that Ru-Vac associates significantly decrease the activation energy of Ru-Cr swaps in reduced LSCR. These results are discussed in view of experimentally observed extrusion of metallic Ru from LSCR nanoparticles under reducing conditions at elevated temperature

First-principles thermodynamic modeling of atomic ordering in yttria-stabilized zirconia

Yttria-stabilized zirconia YSZ is modeled using a cluster expansion statistical thermodynamics method built upon a density-functional theory database. The reliability of cluster expansions in predicting atomic ordering is explored by comparing with the extensive experimental database. The cluster expansion of YSZ is utilized in lattice Monte Carlo simulations to compute the ordering of dopant and oxygen vacancies as a function of concentration. Cation dopants show a strong tendency to aggregate and vacate significantly sized domains below 9 mol % Y_2O_3, which is likely important for YSZ aging processes in ionic conductivity. Evolution of vibrational and underlying electronic properties as a function of Y doping is explored

Is simultaneous yy and ξ\xi--scaling in the quasi-elastic region accidental?

We study the $y$ and $\xi$--scaling of the nuclear response at large momentum transfer in order to understand how scaling based on very different descriptions of the elementary interaction can occur simultaneously. We find that the approximate validity of $\xi$-scaling at low energy loss arises from the coincidental behavior of the quasielastic and deep inelastic cross sections.Comment: 4 pages, 3 Postscript figure

Compactification and Supersymmetry Breaking in M-theory

Keeping N=1 supersymmetry in 4-dimension and in the leading order, we disuss the various orbifold compactifications of M-theory suggested by Horava and Witten on $T^6/Z_3$, $T^6/Z_6$, $T^6/Z_{12}$, and the compactification by keeping singlets under $SU(2)\times U(1)$ symmetry, then the compactification on $S^1/Z_2$. We also discuss the next to leading order K\"ahler potential, superpotential, and gauge kinetic function in the $Z_{12}$ case. In addition, we calculate the SUSY breaking soft terms and find out that the universality of the scalar masses will be violated, but the violation might be very small.Comment: 16 pages, latex, no figure

Non-Critical Liouville String Escapes Constraints on Generic Models of Quantum Gravity

It has recently been pointed out that generic models of quantum gravity must contend with severe phenomenological constraints imposed by gravitational Cerenkov radiation, neutrino oscillations and the cosmic microwave background radiation. We show how the non-critical Liouville-string model of quantum gravity we have proposed escapes these constraints. It gives energetic particles subluminal velocities, obviating the danger of gravitational Cerenkov radiation. The effect on neutrino propagation is naturally flavour-independent, obviating any impact on oscillation phenomenology. Deviations from the expected black-body spectrum and the effects of time delays and stochastic fluctuations in the propagation of cosmic microwave background photons are negligible, as are their effects on observable spectral lines from high-redshift astrophysical objects.Comment: 15 pages LaTeX, 2 eps figures include

Gluino Condensation in Strongly Coupled Heterotic String Theory

Strongly coupled heterotic $E_8\times E_8$ string theory, compactified to four dimensions on a large Calabi-Yau manifold ${\bf X}$, may represent a viable candidate for the description of low-energy particle phenomenology. In this regime, heterotic string theory is adequately described by low-energy $M$-theory on ${\bf R}^4\times{\bf S}^1/{\bf Z}_2\times{\bf X}$, with the two $E_8$'s supported at the two boundaries of the world. In this paper we study the effects of gluino condensation, as a mechanism for supersymmetry breaking in this $M$-theory regime. We show that when a gluino condensate forms in $M$-theory, the conditions for unbroken supersymmetry can still be satisfied locally in the orbifold dimension ${\bf S}^1/{\bf Z}_2$. Supersymmetry is then only broken by the global topology of the orbifold dimension, in a mechanism similar to the Casimir effect. This mechanism leads to a natural hierarchy of scales, and elucidates some aspects of heterotic string theory that might be relevant to the stabilization of moduli and the smallness of the cosmological constant.Comment: 22 pages, harvmac, no figure

Stability of attitude control systems acted upon by random perturbations

Mathematical models on stability of attitude control systems acted upon by random perturbation processe

Issues for the Next Generation of Galaxy Surveys

I argue that the weight of the available evidence favours the conclusions that galaxies are unbiased tracers of mass, the mean mass density (excluding a cosmological constant or its equivalent) is less than the critical Einstein-de Sitter value, and an isocurvature model for structure formation offers a viable and arguably attractive model for the early assembly of galaxies. If valid these conclusions complicate our work of adding structure formation to the standard model for cosmology, but it seems sensible to pay attention to evidence.Comment: 14 pages, 3 postscript figures, uses rspublic.st

QCD corrections to stoponium production at hadron colliders

If the lighter top squark has no kinematically allowed two-body decays that conserve flavor, then it will live long enough to form hadronic bound states. The observation of the diphoton decays of stoponium could then provide a uniquely precise measurement of the top squark mass. In this paper, we calculate the cross section for the production of stoponium in a hadron collider at next-to-leading order (NLO) in QCD. We present numerical results for the cross section for production of stoponium at the LHC and study the dependence on beam energy, stoponium mass, and the renormalization and factorization scale. The cross-section is substantially increased by the NLO corrections, counteracting a corresponding decrease found earlier in the NLO diphoton branching ratio.Comment: 24 page