Structural and sorption properties of bio-nanocomposite films based on κ-carrageenan and cellulose nanocrystals

There is an increased interest on changing the synthetic based materials to biodegradable ones, especially with natural polymers, polysaccharides or proteins. In this research we prepared bio-nanocomposite formulations with different component concentrations and investigated their structural features, with focus on the interactions, sorption properties, and how the combination between them influences these properties. By infrared spectroscopy, principal component analysis (PCA) and two-dimensional correlation spectroscopy (2DCOS) was identified that in the blending process are involved the −SO4 and C(4)-O-S groups of β-d-galactose, CO groups, (O=S=O) of carrageenan and –OH and CO groups from CNCs.The water uptake and water sorption properties decrease with increasing the CNCs content in the formulations from about 15% for κ to 10% for κC15 and from about 128% for κ to 115% for κC15, respectively. The increase of the CNCs content induced an increase of the water contact angle from 47° for κ to 90° for κC15, indicating once again the involvement of the free hydroxyl groups in the hydrogen bonded interactions

ORNAMENTAL VEGETABLE GARDEN DESIGN POSSIBILITIES USING MODULAR RAISED BEDS

Ornamental vegetable gardens have many benefits. They are aesthetic, educational, ecological, economical, sanitary, and are a source of fresh food. Small allotments in urban and peri-urban areas do not allow the implementation of utilitarian gardens. Thus, ornamental vegetable gardens are the best choice. Raised beds can be used to enhance the decorative effect of the entire vegetable garden. This type of construction presents, in turn, several advantages both for the user and crop: reduced effort for maintenance work, early heating of the substrate, loose substrate, reduced volume of weeds, efficient use of space for plants, etc. Establishing ornamental vegetable gardens on raised beds is easily achieved using geometric modules, as they can be adapted to various designs. This paper presents several design options for a decorative vegetable garden on private properties. The case studies presented showed different methods of using modular raised beds depending on the property’s area, the owner’s wishes, and the desired area to be planted. Also, depending on the results obtained from the experimental batch, three other variations of modular layouts with different purposes were proposed: focal point, physically closed but visually open space, and relaxation space

Ornamental vegetable garden design possibilities using modular raised beds

Ornamental vegetable gardens have many benefits. They are aesthetic, educational, ecological, economical, sanitary, and are a source of fresh food. Small allotments in urban and peri-urban areas do not allow the implementation of utilitarian gardens. Thus, ornamental vegetable gardens are the best choice. Raised beds can be used to enhance the decorative effect of the entire vegetable garden. This type of construction presents, in turn, several advantages both for the user and crop: reduced effort for maintenance work, early heating of the substrate, loose substrate, reduced volume of weeds, efficient use of space for plants, etc. Establishing ornamental vegetable gardens on raised beds is easily achieved using geometric modules, as they can be adapted to various designs. This paper presents several design options for a decorative vegetable garden on private properties. The case studies presented showed different methods of using modular raised beds depending on the property’s area, the owner’s wishes, and the desired area to be planted. Also, depending on the results obtained from the experimental batch, three other variations of modular layouts with different purposes were proposed: focal point, physically closed but visually open space, and relaxation space

Functional quality of improved tomato genotypes grown in open field and in plastic tunnel under organic farming

In response to urgent demand to raise awareness of the nutritional and health benefits of tomato consumption and to advocate for healthy diets through increased sustainable production and consumption of fruits and vegetables, this study is intended to promote a healthy and balanced lifestyle, sharing the best practices of production and consumption. The aim of this research was to compare the effects of the growing system (field vs. plastic tunnel) and of genotype characteristics for organic improved tomato genotypes. The research was carried out in the 2019 and 2020 years on eight improved tomato genotypes. The results showed that the ascorbic acid content presented higher values for organic tomatoes cultivated in the field for all genotypes studied, with an upper limit of 18.57 mg 100 g1 FW. In contrast, the content in -carotene and lycopene showed higher values for genotypes grown under plastic tunnel conditions. Significant statistical differences were noticed concerning the mean values of all genotypes according to cultivation conditions (field vs. plastic tunnel) for most parameters excepting total soluble solids (TSS), titratable acidity (TA), maturity index (MI) and flavor index (FI). This highlights the major importance of the selection of some genotypes of tomatoes that respond positively to the organic cultivation system in terms of the presence of the antioxidants compounds (vitamin C, lycopene, and carotene) in representative quantities. Genotype 3 is highlighted by the highest content in carotene (7.4 mg 100 g1 F.W.) and lycopene (8.4 mg 100 g1 F.W.) and genotype 5 by the highest content in vitamin C (16.8 mg 100 g1 F.W.). The results of the study suggest that by applying appropriate techniques for growing organic tomatoes in the plastic tunnel system, the antioxidant substrate can be optimized compared to the results obtained for the field system

Influence of the Chitosan and Rosemary Extract on Fungal Biodegradation of Some Plasticized PLA-Based Materials

The fungal degradation of the complex polymeric systems based on poly(lactic acid) (PLA) and natural bioactive compounds (chitosan and powdered rosemary alcoholic extract) was studied. Two fungal strains, Chaetomium globosum and Phanerochaete chrysosporium were tested. Both fungi characteristics and changes in morphology, structure and thermal properties were monitored. Biochemical parameters as superoxide dismutase, catalase, soluble protein and malondialdehyde have been determined at different time periods of fungal degradation. The fungi extracellular enzyme activities are slightly decreased in the case of composites containing bioactive compounds. The presence of natural compounds in the PLA-based polymeric system determines an acceleration of fungal degradation and probably the chemical hydrolysis, which further helps the attachment of fungi on the surface of polymeric samples. Significant decreases in average molecular mass of the polymeric samples were observed by fungi action; accompanied by structural changes, increase in crystallinity and decrease of thermal properties and the loss of the physical integrity and finally to degradation and integration of fungal degradation products into environmental medium. It was found that both fungi tested are efficient for PLA-based materials degradation, the most active from them being Chaetomium globosum fungus

Influence of the Chitosan and Rosemary Extract on Fungal Biodegradation of Some Plasticized PLA-Based Materials

Paslaru, Elena/0000-0003-1409-9913WOS: 000519849800219PubMed: 32085447The fungal degradation of the complex polymeric systems based on poly(lactic acid) (PLA) and natural bioactive compounds (chitosan and powdered rosemary alcoholic extract) was studied. Two fungal strains, Chaetomium globosum and Phanerochaete chrysosporium were tested. Both fungi characteristics and changes in morphology, structure and thermal properties were monitored. Biochemical parameters as superoxide dismutase, catalase, soluble protein and malondialdehyde have been determined at different time periods of fungal degradation. the fungi extracellular enzyme activities are slightly decreased in the case of composites containing bioactive compounds. the presence of natural compounds in the PLA-based polymeric system determines an acceleration of fungal degradation and probably the chemical hydrolysis, which further helps the attachment of fungi on the surface of polymeric samples. Significant decreases in average molecular mass of the polymeric samples were observed by fungi action; accompanied by structural changes, increase in crystallinity and decrease of thermal properties and the loss of the physical integrity and finally to degradation and integration of fungal degradation products into environmental medium. It was found that both fungi tested are efficient for PLA-based materials degradation, the most active from them being Chaetomium globosum fungus.Ministry of Research and InnovationMinistry of Research and Innovation, Ontario [34PFE/19.10.2018]This research was funded through the project Development of the national RD system, Subprogram 1.2-Institutional Performance-RDI excellence funding projects, by the Ministry of Research and Innovation within Program 1. Contract no.34PFE/19.10.2018

Application of Vegetal Oils in Developing Bioactive Paper-Based Materials for Food Packaging

A major disadvantage of conventional food packaging materials is the difficulty in disposal and recycling, due to their high stability to environmental and thermal stress. The trend now is to develop new eco-friendly food packaging that can substitute fossil fuel derived materials. Cellulose, the main constituent of paper-based food packages, is a favorable starting material for such purpose. In this study we present a new method to obtain bioactive paper based materials suitable for food packaging applications. By combining eco-friendly activation processes (cold plasma or gamma irradiation) and bioactive plant oils (clove essential oil and rosehip seeds vegetal oil) for modification of kraft paper, new materials with antioxidant and antibacterial activity were obtained. The oil-loaded bioactive paper based materials presented increased hydrophobicity (from 97° contact angle in the case of kraft paper to 115° for oil-loaded sample) and decreased water adsorption (a one-quarter decrease). Due to various interactions with the functional groups of plant oils, the modified kraft paper presents different antibacterial and antioxidant properties. Essential clove oil imprinted higher antioxidant activity (owing to the high content in eugenol and eugenol acetate phenolic compounds) and was more efficient in reducing the bacterial growth on fresh beef meat and on fresh curd cheese. The cold pressed rosehip seeds oil acted as aslightly better antibacterial agent against Listeria monocytogenes (+), Salmonella enteritidis (−) and Escherichia coli (−) bacterial strains. Thus, the newly developed bioactive paper could be used as effective packaging material that can help preserving food quality for longer time