Pyroelectric effect in lead zirconate titanate/polyurethane composite for thermal energy harvesting

We deal with the thermal energy which is one of the ambient energy sources surely exploitable, but it has not been much interest as the mechanical energy. In the last decades, direct energy conversion devices received particular attention because of the need to develop flexible systems, autonomous and self-powered. The energy harvesting aims to make the systems, autonomous in terms of energy and to contribute to sustainable development by the total respect of the environment. In this paper, our aim is to use thermal energy and show that it's an important source for producing the electrical energy through pyroelectric effect: first, elaborate charged polyurethane (PU) with different proportions (20%, 30% and 40%) of lead zirconate titanate (PZT), then to use those PZT/PU composites as a pyroelectric energy harvesting systems. Secondly, the optimization of energy harvesting and storage. The PZT/PU composite prepared is considered as one of the most promising composites for energy harvesting systems, due its various advantages, such as mechanical flexibility, high temperature sensitivity, low cost as well as its high electro-active functional properties. The current generated by all samples for temperature fluctuations over a period of time in the order of 140 s have been rectified and stored in a charge capacitor of 1μF. The stored energy can reach a maximum value in the order of 14μW for a composite loaded with 40% PZT. Therefore, these composites show an interesting potential to be used in various applications. These results shed light on the thermoelectric energy conversion by a new composite of PZT/PU having the pyroelectric property

Identification of the Physical and Mechanical Properties of Moroccan Sisal Yarns Used as Reinforcements for Composite Materials

This work aims to investigate the physical and mechanical properties of sisal fiber and yarn of Moroccan origin. The cellulosic and non-cellulosic constituents of the Moroccan sisal fiber were identified by FTIR spectroscopy. The thermal properties were studied by thermogravimetric analysis. The hydrophilicity of the fiber was evaluated by the contact angle. The results show that the sisal fiber has a low thermal stability. The mechanical properties of the fiber analyzed by the Impregnated Fiber Bundle Test (IFBT) method show that the porosity of the impregnated yarns and the twist angle of the yarns influence the elastic modulus of the sisal fiber. The physical and mechanical properties of the manufactured sisal yarns were also characterized and analyzed. The obtained results reveal an interesting potential to use the Moroccan sisal fiber in development of bio-sourced composite materials

Piezo-Resistive Properties of Bio-Based Sensor Yarn Made with Sisal Fibre

In this work, a sensor yarn based on a natural sisal yarn containing a non-electro-conductive core impregnated with PVA polymer and coated by PEDOT:PSS polymer as an electro-conductive sheath was investigated. The main objectives include the development of this new sensor yarn as a first step. Then, we look towards the insertion of this sensor yarn into different woven structures followed by the monitoring of the mechanical behaviour of composite materials made with these fibrous reinforcements. The combined effect of the structural geometry and the number of PEDOT:PSS coating layers on the properties of the sensor yarns was investigated. It was found that the number of PEDOT:PSS coating layers could strongly influence the electromechanical behaviours of the sensor yarns. Different methods of characterization were employed on strain-sensor yarns with two and four coating layers of PEDOT:PSS. The piezo-resistive strain-sensor properties of these selected coating layers were evaluated. Cyclic stretching-releasing tests were also performed to investigate the dynamic strain-sensing behavior. The obtained results indicated that gauge factor values can be extracted in three strain regions for two and four coating layers, respectively. Moreover, these strain-sensor yarns showed accurate and stable sensor responses under cyclic conditions. Furthers works are in progress to investigate the mechanism behind these first results of these sisal fibre-based sensors

Identification of the Physical and Mechanical Properties of Moroccan Sisal Yarns Used as Reinforcements for Composite Materials

This work aims to investigate the physical and mechanical properties of sisal fiber and yarn of Moroccan origin. The cellulosic and non-cellulosic constituents of the Moroccan sisal fiber were identified by FTIR spectroscopy. The thermal properties were studied by thermogravimetric analysis. The hydrophilicity of the fiber was evaluated by the contact angle. The results show that the sisal fiber has a low thermal stability. The mechanical properties of the fiber analyzed by the Impregnated Fiber Bundle Test (IFBT) method show that the porosity of the impregnated yarns and the twist angle of the yarns influence the elastic modulus of the sisal fiber. The physical and mechanical properties of the manufactured sisal yarns were also characterized and analyzed. The obtained results reveal an interesting potential to use the Moroccan sisal fiber in development of bio-sourced composite materials

Piezo-Resistive Properties of Bio-Based Sensor Yarn Made with Sisal Fibre

In this work, a sensor yarn based on a natural sisal yarn containing a non-electro-conductive core impregnated with PVA polymer and coated by PEDOT:PSS polymer as an electro-conductive sheath was investigated. The main objectives include the development of this new sensor yarn as a first step. Then, we look towards the insertion of this sensor yarn into different woven structures followed by the monitoring of the mechanical behaviour of composite materials made with these fibrous reinforcements. The combined effect of the structural geometry and the number of PEDOT:PSS coating layers on the properties of the sensor yarns was investigated. It was found that the number of PEDOT:PSS coating layers could strongly influence the electromechanical behaviours of the sensor yarns. Different methods of characterization were employed on strain-sensor yarns with two and four coating layers of PEDOT:PSS. The piezo-resistive strain-sensor properties of these selected coating layers were evaluated. Cyclic stretching-releasing tests were also performed to investigate the dynamic strain-sensing behavior. The obtained results indicated that gauge factor values can be extracted in three strain regions for two and four coating layers, respectively. Moreover, these strain-sensor yarns showed accurate and stable sensor responses under cyclic conditions. Furthers works are in progress to investigate the mechanism behind these first results of these sisal fibre-based sensors

Pyroelectric Generators to Harvest Energy from Disc Brake Pads for Wireless Sensors in Electric Vehicles

There is a large amount of thermal energy wasted during the driving cycle of all kinds of vehicles. In this paper, a pyroelectric harvester system, based on temperature change, is designed for low-powered sensors for a reliable Electronic/Electric architecture development of autonomous vehicles. For this proposed approach, three main elements are required: Pyroelectric energy harvest module, energy conversion module and power storage module. The energy harvest module includes a pyroelectric material, which captures the temperature of the braking system, and harvests the wasted heat energy during the contact process. In the energy conversion module, the temperature variation through the pyroelectric material generates electricity, given the cooling phenomena with the ambient air. The energy potentially available in the form of heat produced by the friction involved in braking was evaluated using finite element analysis on the Multiphysics software environment. Therefore, we present stimulations of disc heating and cooling during the braking process at different speeds. Moreover, the potential for energy recovery in multiple rolling conditions is discussed, such as the braking cycles and the effect of the material thickness, used in the conversion module. The proposed system has undergone simulation analysis, which shows that the system can generate a voltage of 10.8 V and a power of 7.0 mW for a cycle of one braking process and around 9.5 mW for a cycle containing two successive braking. This result illustrates the feasibility of energy-autonomous applications in low-power sensors for new vehicle generations

An Electronic Measurement Instrumentation of the Impedance of a Loaded Fuel Cell or Battery

In this paper we present an inexpensive electronic measurement instrumentationdeveloped in our laboratory, to measure and plot the impedance of a loaded fuel cell orbattery. Impedance measurements were taken by using the load modulation method. Thisinstrumentation has been developed around a VXI system stand which controls electroniccards. Software under Hpvee® was developed for automatic measurements and the layout ofthe impedance of the fuel cell on load. The measurement environment, like the ambienttemperature, the fuel cell temperature, the level of the hydrogen, etc..., were taken withseveral sensors that enable us to control the measurement. To filter the noise and theinfluence of the 50Hz, we have implemented a synchronous detection which filters in a verynarrow way around the useful signal. The theoretical result obtained by a simulation underPspice® of the method used consolidates the choice of this method and the possibility ofobtaining correct and exploitable results. The experimental results are preliminary results ona 12V vehicle battery, having an inrush current of 330A and a capacity of 40Ah (impedancemeasurements on a fuel cell are in progress, and will be the subject of a forthcoming paper).The results were plotted at various nominal voltages of the battery (12.7V, 10V, 8V and 5V)and with two imposed currents (0.6A and 4A). The Nyquist diagram resulting from theexperimental data enable us to show an influence of the load of the battery on its internalimpedance. The similitude in the graph form and in order of magnitude of the valuesobtained (both theoretical and practical) enables us to validate our electronic measurementinstrumentation. One of the future uses for this instrumentation is to integrate it with several control sensors, on a vehicle as an embedded system to monitor the degradation of fuel cell membranes

Preparation of a novel composite based polyester nonwovens with high mechanical resistance and wash fastness properties

International audienceIn this work, polyester fiber (PET) were functionalized by oxides (Ox) like titanium dioxide (TiO2), zinc oxide (ZnO) and silicon dioxide (SiO2), using polyvinylidene fluoride (PVDF) as binder to obtain a PET-PVDF-Ox material. Chitosan polymer (CT) was further grafted as coating layer to improve the surface compatibility, resulting in the PET-PVDF-Ox-CT composite. The obtained products were thermally pressed and fully characterized. The chemical coatings, physical and thermal properties were investigated. It was found that coated PET nonwoven is highly hydrophobic materials with good diffusion resistance. Incorporation of TiO2, ZnO and SiO2 resulted in the formation of strong cross-linked CT network, producing improved dripping resistance of PET nonwoven. In addition, the modification steps allowed increasing significantly the mechanical resistance. This was explained in terms of improved surface compatibly and interfacial bonding occurred in the matrix. Moreover, soil release tests confirmed the high durability against washing for PET-PVDF-Ox-CT composite. This work allowed developing a facile process for the fabrication of new composite based nonwovens with satisfactory durability and high mechanical resistance