Importance of tetrahedral coordination for high-valent transition metal oxides: YCrO4_4 as a model system

We have investigated the electronic structure of the high oxidation state material YCrO$_4$ within the framework of the Zaanen-Sawatzky-Allen phase diagram. While Cr$^{4+}$-based compounds like SrCrO$_3$/CaCrO$_3$ and CrO$_2$ can be classified as small-gap or metallic negative-charge-transfer systems, we find using photoelectron spectroscopy that YCrO$_4$ is a robust insulator despite the fact that its Cr ions have an even higher formal valence state of 5+. We reveal using band structure calculations that the tetrahedral coordination of the Cr$^{5+}$ ions in YCrO$_4$ plays a decisive role, namely to diminish the bonding of the Cr $3d$ states with the top of the O $2p$ valence band. This finding not only explains why the charge-transfer energy remains effectively positive and the material stable, but also opens up a new route to create doped carriers with symmetries different from those of other transition-metal ions.Comment: 6 pages, 6 figure

Possibility to realize spin-orbit-induced correlated physics in iridium fluorides

Recent theoretical predictions of "unprecedented proximity" of the electronic ground state of iridium fluorides to the SU(2) symmetric $j_{\mathrm{eff}}=1/2$ limit, relevant for superconductivity in iridates, motivated us to investigate their crystal and electronic structure. To this aim, we performed high-resolution x-ray powder diffraction, Ir L$_3$-edge resonant inelastic x-ray scattering, and quantum chemical calculations on Rb$_2$[IrF$_6$] and other iridium fluorides. Our results are consistent with the Mott insulating scenario predicted by Birol and Haule [Phys. Rev. Lett. 114, 096403 (2015)], but we observe a sizable deviation of the $j_{\mathrm{eff}}=1/2$ state from the SU(2) symmetric limit. Interactions beyond the first coordination shell of iridium are negligible, hence the iridium fluorides do not show any magnetic ordering down to at least 20 K. A larger spin-orbit coupling in iridium fluorides compared to oxides is ascribed to a reduction of the degree of covalency, with consequences on the possibility to realize spin-orbit-induced strongly correlated physics in iridium fluorides

Extreme plasma states in laser-governed vacuum breakdown

Triggering vacuum breakdown at the upcoming laser facilities can provide rapid electron-positron pair production for studies in laboratory astrophysics and fundamental physics. However, the density of the emerging plasma should seemingly stop rising at the relativistic critical density, when the plasma becomes opaque. Here we identify the opportunity of breaking this limit using optimal beam configuration of petawatt-class lasers. Tightly focused laser fields allow plasma generation in a small focal volume much less than ${\lambda}^3$, and creating extreme plasma states in terms of density and produced currents. These states can be regarded as a new object of nonlinear plasma physics. Using 3D QED-PIC simulations we demonstrate the possibility of reaching densities of more than $10^{25}$ cm$^{-3}$, which is an order of magnitude higher than previously expected. Controlling the process via the initial target parameters gives the opportunity to reach the discovered plasma states at the upcoming laser facilities

Tien-Shan effect and charmed particles

It is shown that the Tien-Shan effect can be explained as a consequence of charmed particle production with a sufficiently high production cross-section (about 5 mb/nucleon at 100 TeV)