23 research outputs found

    Uncommon intramolecular palladium-catalyzed cyclization of indole derivatives

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    A novel synthetic strategy based on the intramolecular palladium-catalyzed oxidative cyclization reaction, allows the formation of C-C bond and the synthesis of \u3b2-carbolinones. The reaction has been performed in the presence of catalytic amount of PdCl2(CH3CN)2 and benzoquinone as a reoxidant

    Chemo- and Regioselective Palladium(II)-Catalyzed Aminoarylation of N-Allylureas Providing 4-Arylmethyl Imidazolidinones

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    The aminoarylation reaction of N -allylureas under oxidative palladium catalysis, in the absence of ligands and by using inexpensive H 2 O 2 as the sole oxidant, occurs in a chemo- and regioselective fashion. This intramolecular process takes place via a 5- exo -trig cyclization, and represents an easy approach to 4-arylmethyl imidazolidinones
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