14-Bromo-12-chloro-2,16-dioxapentacyclohenicosa-3(8),10,12,14-tetraene-7,20-dione

In the title compound, C19H16BrClO4, both the fused xanthene rings and one of the cyclohexane rings adopt envelope conformations, while the other cyclohexane ring is in a chair conformation. In the crystal, molecules are linked by C-H...O hydrogen bonds, forming infinite chains running along [10-1] incorporating R22(16) ring motifs. In addition, C-H...[pi] interactions and weak [pi]-[pi] stacking interactions [centroid-centroid distance = 3.768 (3) Å] help to consolidate the packing

BACH ARRAY LINEAR GENERATOR FOR WAVE ENERGY CONVERTERS

linear generators have been proposed as a proper power takeoff system for direct-drive wave energy conversion. Coupled directly to a reciprocating wave energy device, it was declared that linear generators could be a valuable replacement for hydraulic and pneumatic systems. In this paper, the design and performance evaluation of permanent magnet linear generator that implements Halbach array arrangement is established. The designed generator is suitable for direct energy extraction from sea waves at small wave amplitude. The electromagnetic design is performed using finite element method and space harmonic analysis. A comparative study is performed between Halbach array and conventional air-cored linear generators to show the effectiveness of the proposed design. The equivalent circuit based model is utilized to investigate the dynamic performance of the Halbach array generator. The simulated dynamic performance of the designed generator clarifies that the implementation of Halbach array arrangement would improve energy extraction and voltage waveform

Can deficit irrigations be an optimum solution for increasing water productivity under arid conditions? A case study on wheat plants

Water scarcity is of growing concern in many countries around the world, especially within the arid and semi-arid zones. Accordingly, rationalizing irrigation water has become an obligation to achieve the sustainable developmental goals of these countries. This may take place via using deficit irrigation which is long thought to be an effective strategy to save and improve water productivity. The current study is a trial to evaluate the pros and cons of using 50 and 75 % of the irrigation requirements (IR) of wheat (deficit irrigations) versus 100 %IR, while precisely charting changes in wheat growth parameters, antioxidant enzymes in plant shoots and the overall nutritional status of plants (NPK contents). Accordingly, a field experiment was conducted for two successive seasons, followed a split-plot design in which deficit irrigations (two irrigations to achieve 50 % of the irrigations requirements (IR), three irrigations to attain 75 % IR, and four irrigations to fulfill 100 % IR) were placed in main plots while four different studied wheat cultivars were in subplots. Results obtained herein indicate that deficit irrigations led to significant reductions in growth parameters and productivity of all wheat cultivars, especially when using 50 % IR. It also decreased NPK contents within plant shoots while elevated their contents of proline, peroxidase, and catalase enzymes. On the other hand, this type of irrigation decreased virtual water content (VWC, the amount of water used in production on ton of wheat grains). Stress tolerance index (STI), and financial revenues per unit area were also assessed. The obtained values of grain productivity, STI, VWC and financial revenues were weighted via PCA analyses, and then introduced in a novel model to estimate the efficiency of deficit irrigations (ODEI) whose results specified that the overall efficiency decreased as follows: 50 %IR < 75 %IR < 100 %IR. In conclusion, deficit irrigation is not deemed appropriate for rationalizing irrigation water while growing wheat on arid soils

Activity Study of Absorbent Prepared from CaO/CaSO4/Coal Fly Ash for SO2 Removal at Low Temperatures.

This study presents findings from an experimental investigation of the influences of several factors on the desulfurization capacity of absorbent prepared from coal fly ash, CaO, and CaSO4. The absorbent was synthesized using hydrothermal reaction while the sulfation experiments were performed in a fixed-bed reactor under isothermal conditions at low temperature

Optimal Sizing of Standalone PV-Wind Hybrid Energy System in Rural Area North Egypt

This paper studies the sizing of stand-alone renewable energy system applied in rural areas in the north of Egypt. The available renewable energy sources in these areas are investigated to be integrated to supply the different types of electrical loads. The quality and quantity of these sources over various weather and climate changes are studied to construct a robust energy system. The load demand in such areas is determined according to all activities require electrical energy. This study considers the different economic levels and technologies which affect the load demand value. The technique and economical indices required to obtain the optimal are investigated and applied in the various estimated cases. The genetic algorithm (GA) technique is applied to determine the size and number of photovoltaic panels and wind turbines. The obtained solution takes into account the loss of power supply probability and the minimization of system cost. This study presents an essential phase in the sustainable development of such rural areas

Thermodynamics and magnetic field profiles in low-kappa type-II superconductors

Two-dimensional low-kappa type-II superconductors are studied numerically within the Eilenberger equations of superconductivity. Depending on the Ginzburg-Landau parameter \kappa=\lambda/\xi vortex-vortex interaction can be attractive or purely repulsive. The sign of interaction is manifested as a first (second) order phase transition from Meissner to the mixed state. Temperature and field dependence of the magnetic field distribution in low-kappa type-II superconductors with attractive intervortex interaction is calculated. Theoretical results are compared to the experiment.Comment: 4 pages, 3 figure

Toll-Like Receptors: The Key of Immunotherapy in MSCs

Human mesenchymal stem cells (MSCs) are potential candidates for various applications in the fields of immunotherapy. Their multilineage differentiation capability and immune modulatory features allow their prospective application for the management of different immunological circumstances. However, the local microenvironment, in addition to the source of the MSCs can control diverse biological features of the cells. Indeed, throughout their therapeutic application, MSCs may interact with their microenvironment through their expressed toll-like-receptors (TLRs), producing immune modulating reactions. Stimulation of MSCs before or within the potential treatment procedures with distinct TLR ligands may assist as an effective step controlling the biological function of the MSCs as needed in different therapeutic stages of the disease

Electrical and Magnetic Properties of Mn-Bi-Sb Alloys

MnBi1-xSbx alloys were prepared by the conventional melt technique. The Seebeck coefficient (S), electrical resistivity (ρ), and magnetic susceptibility (c) were measured at various temperatures ranging from ~100 to 400 K. The electrical resistivity of x £ 0.15 shows both semiconducting and metallic behavior depending on temperature and Sb content, whereas samples x 3 0.2 have only semiconductor behavior in all the temperature range. The negative sign of the Seebeck coefficient increases, i.e., the positivity decreases with the increasing Sb content. The magnetic susceptibility (χ) shows that alloys undergo ferro-paramagnetic transition at a certain temperature (TC) and the TC values decrease with increasing Sb content. From thermoelectric measurements and electronic thermal conductivity calculated, it was observed that Sb doping increases the power factor (PF) and the figure of merit (ZT). Thus, Sb content plays an essential role in making these alloys applicable in the thermoelectric industry