Correlations in two-component log-gas systems

A systematic study of the properties of particle and charge correlation functions in the two-dimensional Coulomb gas confined to a one-dimensional domain is undertaken. Two versions of this system are considered: one in which the positive and negative charges are constrained to alternate in sign along the line, and the other where there is no charge ordering constraint. Both systems undergo a zero-density Kosterlitz-Thouless type transition as the dimensionless coupling $\Gamma := q^2 / kT$ is varied through $\Gamma = 2$. In the charge ordered system we use a perturbation technique to establish an $O(1/r^4)$ decay of the two-body correlations in the high temperature limit. For $\Gamma \rightarrow 2^+$, the low-fugacity expansion of the asymptotic charge-charge correlation can be resummed to all orders in the fugacity. The resummation leads to the Kosterlitz renormalization equations.Comment: 39 pages, 5 figures not included, Latex, to appear J. Stat. Phys. Shortened version of abstract belo

Metastable liquid-liquid phase transition in a single-component system with only one crystal phase and no density anomaly

We investigate the phase behavior of a single-component system in 3 dimensions with spherically-symmetric, pairwise-additive, soft-core interactions with an attractive well at a long distance, a repulsive soft-core shoulder at an intermediate distance, and a hard-core repulsion at a short distance, similar to potentials used to describe liquid systems such as colloids, protein solutions, or liquid metals. We showed [Nature {\bf 409}, 692 (2001)] that, even with no evidences of the density anomaly, the phase diagram has two first-order fluid-fluid phase transitions, one ending in a gas--low-density liquid (LDL) critical point, and the other in a gas--high-density liquid (HDL) critical point, with a LDL-HDL phase transition at low temperatures. Here we use integral equation calculations to explore the 3-parameter space of the soft-core potential and we perform molecular dynamics simulations in the interesting region of parameters. For the equilibrium phase diagram we analyze the structure of the crystal phase and find that, within the considered range of densities, the structure is independent of the density. Then, we analyze in detail the fluid metastable phases and, by explicit thermodynamic calculation in the supercooled phase, we show the absence of the density anomaly. We suggest that this absence is related to the presence of only one stable crystal structure.Comment: 15 pages, 21 figure